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(S)-(-)-1-Amino-2-(methoxymethyl)pyrrolidine - >98.0%(T), high purity , CAS No.59983-39-0
Discover (S)-(-)-1-Amino-2-(methoxymethyl)pyrrolidine by Aladdin Scientific in >98.0%(T) for only $31.90. Available - in Ligands at Aladdin Scientific. Tags: asymmetric synthesis, Chiral heterocyclic block.
Basic Description Synonyms 59983-39-0|(S)-(-)-1-Amino-2-(methoxymethyl)pyrrolidine|(S)-2-(Methoxymethyl)pyrrolidin-1-amine|SAMP|(2S)-2-(methoxymethyl)pyrrolidin-1-amine|1-Pyrrolidinamine, 2-(methoxymethyl)-, (2S)-|[S]-(-)-1-amino-2-(methoxymethyl)pyrrolidine|(S)-1-Amino-2-(methoxym Specifications & Purity >98.0%(T) Storage Temp Argon charged Shipped In Normal Product Description Product Application：
(S)-(-)-1-Amino-2-(methoxymethyl)pyrrolidine may be used as a chiral auxiliary in the asymmetric synthesis of (S)-2-ethylhexanoic acid and (S)-2-n-propyl-4-pentenoic acid. It can undergo 1,4-addition to (E)-alkenyl-cyclohexyl sulfonates in the presence of zinc bromide to form β-hydrazino-cyclohexyl sulfonates.
Names and Identifiers IUPAC Name (2S)-2-(methoxymethyl)pyrrolidin-1-amine INCHI InChI=1S/C6H14N2O/c1-9-5-6-3-2-4-8(6)7/h6H,2-5,7H2,1H3/t6-/m0/s1 InChi Key BWSIKGOGLDNQBZ-LURJTMIESA-N Canonical SMILES COCC1CCCN1N Isomeric SMILES COC[C@@H]1CCCN1N WGK Germany 3 PubChem CID 7156993 Molecular Weight 130.19 Beilstein 1523790 Reaxy-Rn 4857560
Chemical and Physical Properties Sensitivity Air sensitive Specific Rotation[α] -80° Flash Point(°F) 161.6 °F Flash Point(°C) 72 °C Boil Point(°C) 64 °C
Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
Precautionary Statements P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P264: Wash hands [and …] thoroughly after handling.
P362+P364: Take off contaminated clothing and wash it before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P337+P317: If eye irritation persists: Get medical help.
P332+P317: If skin irritation occurs: Get medical help.
WGK Germany 3 Reaxy-Rn 4857560
References 1. Loris R Lopetuso,Ruo Jia,Xiao-Ming Wang,Li-Guo Jia,Valentina Petito,Wendy A Goodman,Jon B Meddings,Fabio Cominelli,Brian K Reuter,Theresa T Pizarro. (2017-02-02) Epithelial-specific Toll-like Receptor (TLR)5 Activation Mediates Barrier Dysfunction in Experimental Ileitis.. Inflammatory bowel diseases, 23 ((3)): (392-403). [PMID:28146004 ] 2. Yuanxia Qin,Jie Wang,Fenglong Wang,Lili Shen,Haixiang Zhou,Hangjun Sun,Kaiqiang Hao,Liyun Song,Zhicheng Zhou,Chaoqun Zhang,Yuanhua Wu,Jinguang Yang. (2019-02-26) Purification and Characterization of a Secretory Alkaline Metalloprotease with Highly Potent Antiviral Activity from Serratia marcescens Strain S3.. Journal of agricultural and food chemistry, 67 ((11)): (3168-3178). [PMID:30799619 ]
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