(S)-RuCl[(p-cymene(BINAP)]Cl - 99.95% metals basis, high purity , CAS No.130004-33-0

Item Number

S294487

• Synonyms: 130004-33-0|145926-28-9|(R)-RuCl[(p-cymene)(BINAP)]Cl|(S)-RuCl[(p-cymene(BINAP)]Cl|Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride|(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM
• Specifications & Purity: 99.95% metals basis
• Legal Information: Product of Umicore
• Storage Temp: Store at 2-8°C,Argon charged
• Shipped In: Wet ice

Product Description

Product class
M-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - Chiral

Reaction type
Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C54H46Cl2P2Ru

Empirical formula

[RuCl(p-cymene)(S)-BINAP)]Cl

Molecular weight

928.88

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color
Metal purity

red orange

99.95

Applications & references

Synthesis of (R)- or (S)-4-halo-3-hydroxybuyrate ester by asymmetric hydrogenation of 4-halo-3-oxobutanoate ester; this reaction can be applied in the Producteion of L-carnitine.

Reference: EP2386536

Enantioselective hydrogenation of functionalized ketones.

Reference: EP0366390

Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.

Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721)

Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.

Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018)

Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.

Reference: J. Mol. Cat. A: Chem. 2006, 259, 103 (DOI: 10.1016/j.molcata.2006.05.066)