Determine the necessary mass, volume, or concentration for preparing a solution.
Basic Description
| Synonyms | EC 231-971-0 | EINECS 231-971-0 | FT-0689068 | HSDB 692 | Q188260 | SODIUM AMIDE | SODIUM AMIDE [MI] | AKOS015960454 | 5DB3G6PX9D | SODIUM AMIDE [HSDB] | Sodium amide (Na(NH2)) | Sodium amide, 50 wt. % suspension in toluene | Sodium amide, hydrogen-storag |
|---|---|
| Specifications & Purity | 50 wt. % suspension in toluene |
| Product Description | Sodium amide, an inorganic compound used in organic synthesis, is generally prepared by heating sodium metal in gaseous ammonia. It is used in some organic reactions like dehalogenation, deprotonation, anionic polymerization of ionic chains, and in cleavage of ketones. Application Reagent for: Synthesis of allylic amines and amides Synthesis of antibacterials Aggregative activation and heterocyclic chemistry Phenylation with diphenyliodonium chloride |
Names and Identifiers
Certificates
Certificate of Analysis(COA)
Enter Lot Number to search for COA:
Chemical and Physical Properties
| Boil Point(°C) | 400°C |
|---|---|
| Melt Point(°C) | 210°C |
Safety and Hazards(GHS)
| Pictogram(s) | GHS09, GHS05, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H314:Causes severe skin burns and eye damage H318:Causes serious eye damage H400:Very toxic to aquatic life H261:In contact with water releases flammable gas |
| Precautionary Statements | P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas/... Protect from moisture. P370+P378:In case of fire: Use ... to extinguish. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P391:Collect spillage. P402+P404:Store in a dry place. Store in a closed container. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. |
| WGK Germany | 2 |
| Class | 4.3 |
Related Documents
Citations of This Product
| 1. Xiaoxu Zhao, Yueqin Liu, Jianfeng Guo, Na Chang, Haitao Wang. (2022) NCQDs active sites as effective collectors of charge carriers towards enhanced photocatalytic activity of porous Co3O4. ENVIRONMENTAL TECHNOLOGY, [PMID:36379221] [10.1080/09593330.2022.2143292] |
| 2. Weijun Ying, Shuo Tian, Huan Liu, Zenan Zhou, Grantson Kapeso, Jinhuan Zhong, Wenbiao Zhang. (2022) In Situ Dry Chemical Synthesis of Nitrogen-Doped Activated Carbon from Bamboo Charcoal for Carbon Dioxide Adsorption. Materials, 15 (3): (763). [PMID:35160708] [10.3390/ma15030763] |
| 3. Zhixiu Yang, Xiaofei Guo, Guojie Zhang, Ying Xu. (2020) One-pot synthesis of high N-doped porous carbons derived from a N-rich oil palm biomass residue in low temperature for CO2 capture. INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 44 (6): (4875-4887). [PMID:] [10.1002/er.5287] |
| 4. Zhixiu Yang, Guojie Zhang, Ying Xu, Peiyu Zhao. (2019) One step N-doping and activation of biomass carbon at low temperature through NaNH2: An effective approach to CO2 adsorbents. Journal of CO2 Utilization, 33 (320). [PMID:] [10.1016/j.jcou.2019.06.021] |
| 5. Yan Zhang, Lu Liu, Peixin Zhang, Jun Wang, Mai Xu, Qiang Deng, Zheling Zeng, Shuguang Deng. (2019) Ultra-high surface area and nitrogen-rich porous carbons prepared by a low-temperature activation method with superior gas selective adsorption and outstanding supercapacitance performance. CHEMICAL ENGINEERING JOURNAL, 355 (309). [PMID:] [10.1016/j.cej.2018.08.169] |
| 6. Zuo Yong, Liu Yu, He Qiong-Ping, Song Ji-Ming, Niu He-Lin, Mao Chang-Jie. (2018) CuAgSe nanocrystals: colloidal synthesis, characterization and their thermoelectric performance. JOURNAL OF MATERIALS SCIENCE, 53 (21): (14998-15008). [PMID:] [10.1007/s10853-018-2676-7] |
| 7. Mei Guo, Yu Li, Kewen Du, Chaochao Qiu, Gang Dou, Guoxin Zhang. (2018) Fabricating hierarchically porous carbon with well-defined open pores via polymer dehalogenation for high-performance supercapacitor. APPLIED SURFACE SCIENCE, 440 (606). [PMID:] [10.1016/j.apsusc.2018.01.215] |
| 8. Zhen Hu, Qing Shao, Xirong Xu, Dayu Zhang, Yudong Huang. (2017) Surface initiated grafting of polymer chains on carbon nanotubes via one-step cycloaddition of diarylcarbene. COMPOSITES SCIENCE AND TECHNOLOGY, 142 (294). [PMID:] [10.1016/j.compscitech.2017.02.027] |
| 9. Zhen Hu, Qing Shao, Mark G. Moloney, Xirong Xu, Dayu Zhang, Jun Li, Chunhua Zhang, Yudong Huang. (2017) Nondestructive Functionalization of Graphene by Surface-Initiated Atom Transfer Radical Polymerization: An Ideal Nanofiller for Poly(p-phenylene benzobisoxazole) Fibers. MACROMOLECULES, 50 (4): (1422–1429). [PMID:] [10.1021/acs.macromol.6b02694] |
| 10. Zhen Hu, Chenhao Song, Qing Shao, Jun Li, Yudong Huang. (2016) One-step functionalization of graphene by cycloaddition of diarylcarbene and its application as reinforcement in epoxy composites. COMPOSITES SCIENCE AND TECHNOLOGY, 135 (21). [PMID:] [10.1016/j.compscitech.2016.09.008] |
| 11. Guoxin Zhang, Kang Zhou, Ruoyu Xu, Hekai Chen, Xiaoke Ma, Biao Zhang, Zheng Chang, Xiaoming Sun. (2016) An alternative pathway to water soluble functionalized graphene from the defluorination of graphite fluoride. CARBON, 96 (1022). [PMID:] [10.1016/j.carbon.2015.10.020] |
References
| 1. Christian Bukovec,Uli Kazmaier. (2011-03-08) Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.. Organic & biomolecular chemistry, 9 ((8)): (2743-2750). [PMID:21380466] |
| 2. André M Bienfait,Christoph Schädle,Cäcilia Maichle-Mössmer,Karl W Törnroos,Reiner Anwander. (2014-10-17) Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.. Dalton transactions (Cambridge, England : 2003), 43 ((46)): (17324-17332). [PMID:25318830] |
| 3. Xiaoxu Zhao, Yueqin Liu, Jianfeng Guo, Na Chang, Haitao Wang. (2022) NCQDs active sites as effective collectors of charge carriers towards enhanced photocatalytic activity of porous Co3O4. ENVIRONMENTAL TECHNOLOGY, [PMID:36379221] [10.1080/09593330.2022.2143292] |
| 4. Weijun Ying, Shuo Tian, Huan Liu, Zenan Zhou, Grantson Kapeso, Jinhuan Zhong, Wenbiao Zhang. (2022) In Situ Dry Chemical Synthesis of Nitrogen-Doped Activated Carbon from Bamboo Charcoal for Carbon Dioxide Adsorption. Materials, 15 (3): (763). [PMID:35160708] [10.3390/ma15030763] |
| 5. Zhixiu Yang, Xiaofei Guo, Guojie Zhang, Ying Xu. (2020) One-pot synthesis of high N-doped porous carbons derived from a N-rich oil palm biomass residue in low temperature for CO2 capture. INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 44 (6): (4875-4887). [PMID:] [10.1002/er.5287] |
| 6. Zhixiu Yang, Guojie Zhang, Ying Xu, Peiyu Zhao. (2019) One step N-doping and activation of biomass carbon at low temperature through NaNH2: An effective approach to CO2 adsorbents. Journal of CO2 Utilization, 33 (320). [PMID:] [10.1016/j.jcou.2019.06.021] |
| 7. Yan Zhang, Lu Liu, Peixin Zhang, Jun Wang, Mai Xu, Qiang Deng, Zheling Zeng, Shuguang Deng. (2019) Ultra-high surface area and nitrogen-rich porous carbons prepared by a low-temperature activation method with superior gas selective adsorption and outstanding supercapacitance performance. CHEMICAL ENGINEERING JOURNAL, 355 (309). [PMID:] [10.1016/j.cej.2018.08.169] |
| 8. Zuo Yong, Liu Yu, He Qiong-Ping, Song Ji-Ming, Niu He-Lin, Mao Chang-Jie. (2018) CuAgSe nanocrystals: colloidal synthesis, characterization and their thermoelectric performance. JOURNAL OF MATERIALS SCIENCE, 53 (21): (14998-15008). [PMID:] [10.1007/s10853-018-2676-7] |
| 9. Mei Guo, Yu Li, Kewen Du, Chaochao Qiu, Gang Dou, Guoxin Zhang. (2018) Fabricating hierarchically porous carbon with well-defined open pores via polymer dehalogenation for high-performance supercapacitor. APPLIED SURFACE SCIENCE, 440 (606). [PMID:] [10.1016/j.apsusc.2018.01.215] |
| 10. Zhen Hu, Qing Shao, Xirong Xu, Dayu Zhang, Yudong Huang. (2017) Surface initiated grafting of polymer chains on carbon nanotubes via one-step cycloaddition of diarylcarbene. COMPOSITES SCIENCE AND TECHNOLOGY, 142 (294). [PMID:] [10.1016/j.compscitech.2017.02.027] |
| 11. Zhen Hu, Qing Shao, Mark G. Moloney, Xirong Xu, Dayu Zhang, Jun Li, Chunhua Zhang, Yudong Huang. (2017) Nondestructive Functionalization of Graphene by Surface-Initiated Atom Transfer Radical Polymerization: An Ideal Nanofiller for Poly(p-phenylene benzobisoxazole) Fibers. MACROMOLECULES, 50 (4): (1422–1429). [PMID:] [10.1021/acs.macromol.6b02694] |
| 12. Zhen Hu, Chenhao Song, Qing Shao, Jun Li, Yudong Huang. (2016) One-step functionalization of graphene by cycloaddition of diarylcarbene and its application as reinforcement in epoxy composites. COMPOSITES SCIENCE AND TECHNOLOGY, 135 (21). [PMID:] [10.1016/j.compscitech.2016.09.008] |
| 13. Guoxin Zhang, Kang Zhou, Ruoyu Xu, Hekai Chen, Xiaoke Ma, Biao Zhang, Zheng Chang, Xiaoming Sun. (2016) An alternative pathway to water soluble functionalized graphene from the defluorination of graphite fluoride. CARBON, 96 (1022). [PMID:] [10.1016/j.carbon.2015.10.020] |