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Basic Description
| Synonyms | SODIUM AMIDE|7782-92-5|Sodamide|Sodium amide (Na(NH2))|sodium;azanide|5DB3G6PX9D|sodiumamide|sodium azanide|UNII-5DB3G6PX9D|Natriumamid|Sodoamide|HSDB 692|Sodium amide, 50 wt. % suspension in toluene|EINECS 231-971-0|MFCD00011117|NaNH2|Sodium amide, 95%|S |
|---|---|
| Specifications & Purity | 50 wt. % suspension in toluene |
| Product Description | Sodium amide, an inorganic compound used in organic synthesis, is generally prepared by heating sodium metal in gaseous ammonia. It is used in some organic reactions like dehalogenation, deprotonation, anionic polymerization of ionic chains, and in cleavage of ketones. Application Reagent for: Synthesis of allylic amines and amides Synthesis of antibacterials Aggregative activation and heterocyclic chemistry Phenylation with diphenyliodonium chloride |
Names and Identifiers
Certificates
Certificate of Analysis(COA)
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Chemical and Physical Properties
| Boil Point(°C) | 400°C |
|---|---|
| Melt Point(°C) | 210°C |
Safety and Hazards(GHS)
| Pictogram(s) | GHS09, GHS05, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H314:Causes severe skin burns and eye damage H318:Causes serious eye damage H400:Very toxic to aquatic life H261:In contact with water releases flammable gas |
| Precautionary Statements | P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas/... Protect from moisture. P370+P378:In case of fire: Use ... to extinguish. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P391:Collect spillage. P402+P404:Store in a dry place. Store in a closed container. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. |
| WGK Germany | 2 |
| Class | 4.3 |
Related Documents
References
| 1. Christian Bukovec,Uli Kazmaier. (2011-03-08) Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.. Organic & biomolecular chemistry, 9 ((8)): (2743-2750). [PMID:21380466] |
| 2. André M Bienfait,Christoph Schädle,Cäcilia Maichle-Mössmer,Karl W Törnroos,Reiner Anwander. (2014-10-17) Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.. Dalton transactions (Cambridge, England : 2003), 43 ((46)): (17324-17332). [PMID:25318830] |