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Sodium bis(trimethylsilyl)amide - 95%, high purity , CAS No.1070-89-9

  • ≥95%
Item Number
S106743
Grouped product items
SKUSizeAvailabilityPrice Qty
S106743-1g
1g
In stock
$14.90
S106743-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$56.90
S106743-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$127.90

Discover Sodium bis(trimethylsilyl)amide by Aladdin Scientific in 95% for only $14.90. Available - in Ligands at Aladdin Scientific. Tags: Organic base, Silicon compound.

View related series
Organic base Silicon compound

Basic Description

SynonymsSodium bis(trimethylsilyl)amide|1070-89-9|NaHMDS|N-Sodiohexamethyldisilazane|Sodium Hexamethyldisilazide|Hexamethyldisilazane sodium salt|sodium;bis(trimethylsilyl)azanide|MFCD00009835|Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt|sodium he
Specifications & Purity95%
Storage TempArgon charged
Shipped InNormal
Product Description

Product Describtion:

Significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis


Product Application:

Sodium bis(trimethylsilyl)amide is used as a base in organic synthesis as well as to deprotonate other compounds containing weakly acidic O-H, S-H, and N-H bonds. It is used to prepare amines by reacting with alkyl halides. It finds application in certain organic reactions viz. generation of carbenes by dehydrohalogenation of halocarbons and Wittig reagents by deprotonation of phosphonium salts. It accelerates the polymerization of pheneylacetylene in conjunction with rhodium(I) catalysis. Furthermore, it is used for the preparation of lanthanide complexes.

Names and Identifiers

IUPAC Name sodium;bis(trimethylsilyl)azanide
INCHI InChI=1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChi Key WRIKHQLVHPKCJU-UHFFFAOYSA-N
Canonical SMILES C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
Isomeric SMILES C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
WGK Germany 3
PubChem CID 2724254
UN Number 3263
Packing Group II
Molecular Weight 183.37
Beilstein 3629917
Reaxy-Rn 3629917

Certificates

Certificate of Analysis(COA)

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13 results found

Lot NumberCertificate TypeDateItem
H2427135Certificate of AnalysisJun 28, 2024 S106743
H2427136Certificate of AnalysisJun 28, 2024 S106743
H2427133Certificate of AnalysisJun 28, 2024 S106743
H2427134Certificate of AnalysisJun 28, 2024 S106743
D2429377Certificate of AnalysisApr 18, 2024 S106743
D2429378Certificate of AnalysisApr 18, 2024 S106743
I2301645Certificate of AnalysisAug 15, 2023 S106743
I2301750Certificate of AnalysisAug 15, 2023 S106743
F23301021Certificate of AnalysisJun 09, 2023 S106743
F23301036Certificate of AnalysisJun 09, 2023 S106743
F2330641Certificate of AnalysisJun 09, 2023 S106743
B1927001Certificate of AnalysisSep 21, 2022 S106743
I1820262Certificate of AnalysisMay 11, 2022 S106743

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Chemical and Physical Properties

SolubilitySoluble in hexane, toluene, ether,terahydrofuran, benzene and toluene.
SensitivityHygroscopic.
Flash Point(°F)1 °F
Flash Point(°C)-17 °C
Melt Point(°C)171-175°C

Safety and Hazards(GHS)

Pictogram(s) GHS05
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H412:Harmful to aquatic life with long lasting effects

H302+H312+H332:Harmful if swallowed, in contact with skin or if inhaled

Precautionary Statements

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P362+P364:Take off contaminated clothing and wash it before reuse.

P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.

WGK Germany 3
Reaxy-Rn 3629917
Class 8(3)

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Solution Calculators