| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| S106745-100ml | 100ml | In stock | $55.90 | |
| S106745-500ml | 500ml | In stock | $211.90 |
| Specifications & Purity | 2.0 M in THF(40%) |
|---|---|
| Storage Temp | Argon charged |
| Shipped In | Normal |
| Product Description | Significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis； · Sodium bis(trimethylsilyl)amide, also known as NaHMDS, is a metal dialkylamide reagent that combines both high basicity and nucleophilicity. It is a general reagent used for the enolization of carbonyl compounds. · It can be used to prepare phosphonium ylides in Wittig reaction. · NaHMDS solution can also be used as a source of nitrogen in aminomethylation and in the synthesis of primary amines from the corresponding alkyl halides. |
| UN Number | 2056 |
|---|---|
| Packing Group | II |
| Molecular Weight | 183.37 |
Enter Lot Number to search for COA:
Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
 G23201074 | Certificate of Analysis | Jun 16, 2023 | S106745 |
| G23201076 | Certificate of Analysis | Jun 16, 2023 | S106745 |
| G23201083 | Certificate of Analysis | Jun 16, 2023 | S106745 |
| G23201085 | Certificate of Analysis | Jun 16, 2023 | S106745 |
| G23201086 | Certificate of Analysis | Jun 16, 2023 | S106745 |
| H2416036 | Certificate of Analysis | Jun 16, 2023 | S106745 |
| I2101082 | Certificate of Analysis | Jun 06, 2023 | S106745 |
| I2101079 | Certificate of Analysis | Jun 06, 2023 | S106745 |
| L2009153 | Certificate of Analysis | Sep 21, 2022 | S106745 |
| A2220047 | Certificate of Analysis | Sep 14, 2021 | S106745 |
| I2101085 | Certificate of Analysis | Sep 14, 2021 | S106745 |
| Solubility | Miscible with benzene and toluene |
|---|---|
| Sensitivity | Air & Moisture Sensitive |
| Pictogram(s) | GHS08, GHS07, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H351:Suspected of causing cancer H302:Harmful if swallowed H225:Highly Flammable liquid and vapor H372:Causes damage to organs through prolonged or repeated exposure H371:May cause damage to organs |
| Precautionary Statements | P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P337+P313:IF eye irritation persists: Get medical advice/attention. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P308+P311:IF exposed or concerned: Call a POISON CENTER/doctor/... P330:Rinse mouth. P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. |
| Class | 3 |
| 1. Xinyan Yu, Yong Wang, Yutong Dong, Ning Zhao, Lifeng Zhang, Sunting Xuan, Zhengbiao Zhang. (2023) Efficient Synthesis of N-Methyl Polypeptides by Organic Acid Promoted Controlled Ring-Opening Polymerization of N-Methyl-α-Amino Acids N-Carboxyanhydrides. MACROMOLECULES, 56 (21): (8899–8911). [PMID:27438768] [10.1021/acs.macromol.3c01102] |
| 1. Xinyan Yu, Yong Wang, Yutong Dong, Ning Zhao, Lifeng Zhang, Sunting Xuan, Zhengbiao Zhang. (2023) Efficient Synthesis of N-Methyl Polypeptides by Organic Acid Promoted Controlled Ring-Opening Polymerization of N-Methyl-α-Amino Acids N-Carboxyanhydrides. MACROMOLECULES, 56 (21): (8899–8911). [PMID:27438768] [10.1021/acs.macromol.3c01102] |
