Sodium hexanitrocobaltate(III) - puriss. p.a., for the determination of K, ACS reagent, high purity , CAS No.13600-98-1

Item Number
S431989
Grouped product items
SKUSizeAvailabilityPrice Qty
S431989-25g
25g
Available within 8-12 weeks(?)
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$119.90

Basic Description

SynonymsSodium hexanitritocobaltate(III), Sodium cobaltnitrite
Specifications & Puritypuriss. p.a., for the determination of K, ACS reagent
GradeACS, puriss. p.a.
Product Description

Application

Sodium hexanitrocobaltate(III) (Na 3 Co(NO 2 ) 6 ) may be employed as a nitrosation reagent for various amino group containing organic compounds (aliphatic and aromatic).

Names and Identifiers

IUPAC Name trisodium;cobalt;hexanitrite
INCHI InChI=1S/Co.6HNO2.3Na/c;6*2-1-3;;;/h;6*(H,2,3);;;/q;;;;;;;3*+1/p-6
InChi Key MUTOTFDDGIZNIK-UHFFFAOYSA-H
Canonical SMILES N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].[Na+].[Na+].[Na+].[Co]
Isomeric SMILES N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].[Na+].[Na+].[Na+].[Co]
WGK Germany 3
RTECS GF9480000
PubChem CID 22836338
UN Number 1479
Molecular Weight 403.94

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Melt Point(°C)220°C

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS07,   GHS03
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H351:Suspected of causing cancer

H317:May cause an allergic skin reaction

H334:May cause allergy or asthma symptoms or breathing difficulties if inhaled

H272:May intensify fire; oxidizer

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P220:Keep away from clothing and other combustible materials.

P284:[In case of inadequate ventilation] Wear respiratory protection.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P203:Obtain, read and follow all safety instructions before use.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P318:if exposed or concerned, get medical advice.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

P342+P316:If experiencing respiratory symptoms: Get emergence medical help immediately.

WGK Germany 3
RTECS GF9480000

Related Documents

References

1. A A Korolev.  (1980-10-01)  [Hygienic standard basis for potassium hexanitrocobaltate in the water of reservoirs]..  Gigiena i sanitariia,    ((10)(10)): (72-73).  [PMID:7429188]
2. S Khalil,N Borham.  (2000-03-17)  Indirect atomic absorption spectrometric determination of pindolol, propranolol and levamisole hydrochlorides based on formation of ion-associates with ammonium reineckate and sodium cobaltinitrite..  Journal of pharmaceutical and biomedical analysis,  22  ((2)): (235-240).  [PMID:10719905]
3. Bogdan Stefane,Marijan Kocevar,Slovenko Polanc.  (2001-10-24)  Nitrosation with Sodium Hexanitrocobaltate(III)..  The Journal of organic chemistry,  62  ((21)): (7165-7169).  [PMID:11671821]
4. Man-Song Li,Elizabeth A Cowley,Paul Linsdell.  (2012-05-23)  Pseudohalide anions reveal a novel extracellular site for potentiators to increase CFTR function..  British journal of pharmacology,  167  ((5)): (1062-1075).  [PMID:22612315]
5. D B Green,S M Dodge,J R Lee,G Tallman.  (1990-01-01)  Effect of sodium hexanitrocobaltate (III) decomposition on its staining of intracellular potassium ions..  Stain technology,  65  ((1)): (15-24).  [PMID:1694311]

Solution Calculators