Sodium tert-butoxide solution - 2 M in THF, high purity , CAS No.865-48-5

7 Citations
  • 2 M in THF
Item Number
S140748
Grouped product items
SKUSizeAvailabilityPrice Qty
S140748-100ml
100ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$86.90

Basic Description

Synonyms2-Propanol, 2-methyl-, sodium salt (1:1) | EC 212-741-9 | t-butoxysodium | (tert-butoxy)sodium | tertiary butoxy sodium | SH-003 | sodium tbutoxide | sodium t-butoxide | Sodium tert-butoxide, 97% | tert-butyl 4-formylpiperidine-1-carboxylate;N-BOC-PIPERID
Specifications & Purity2 M in THF
Storage TempArgon charged
Shipped InNormal

Names and Identifiers

IUPAC Name sodium;2-methylpropan-2-olate
INCHI InChI=1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChi Key MFRIHAYPQRLWNB-UHFFFAOYSA-N
Canonical SMILES CC(C)(C)[O-].[Na+]
Isomeric SMILES CC(C)(C)[O-].[Na+]
WGK Germany 3
PubChem CID 23676156
Molecular Weight 96.1

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Chemical and Physical Properties

SensitivityMoisture sensitive
Refractive Index1.413
Flash Point(°F)57.2 °F
Flash Point(°C)14 °C
Melt Point(°C)270 °C

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS07,   GHS02
Signal Danger
Hazard Statements

H335:May cause respiratory irritation

H314:Causes severe skin burns and eye damage

H318:Causes serious eye damage

H228:Flammable solid

H251:Self-heating; may catch fire

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P410:Protect from sunlight.

P420:Store separately.

P235:Keep cool.

P407:Maintain air gap between stacks or pallets.

P413:Store bulk masses greater than ... kg/...lbs at temperatures not exceeding ... °C/...°F.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P317:Get emergency medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

P319:Get medical help if you feel unwell.

WGK Germany 3

Related Documents

Citations of This Product

1. Yuying Li, Junle Zhang, Yaxuan Shi, Yuancheng Zhang, Ge Shi, Xiaomeng Zhang, Zhe Cui, Peng Fu, Minying Liu, Xiaoguang Qiao, Yanjie He, Yudong Wang, Haitao Zhao, Wenjie Zhang, Xinchang Pang.  (2023)  Robust Strategy to Improve the Compatibility between Incorporated Upconversion Nanoparticles and the Bulk Transparent Polymer Matrix.  ACS Omega,  (35): (32159–32167).  [PMID:37692212]
2. Duanlian Tang, Minlei Yin, Xiaowei Du, Yuxin Duan, Jie Chen, Ting Qiu.  (2023)  Wettability tunable conjugated microporous poly(aniline)s for long-term, rapid and ppb level sequestration of Hg(II).  CHEMICAL ENGINEERING JOURNAL,  474  (145527).  [PMID:]
3. Duanlian Tang, Xiaoying Lyu, Zhixian Huang, Renwei Xu, Jie Chen, Ting Qiu.  (2023)  Nitrogen-doped microporous carbons as highly efficient adsorbents for CO2 and Hg(II) capture.  POWDER TECHNOLOGY,  427  (118769).  [PMID:]
4. Xiaoyu Lou, Xiaoyan Chen, Duanlian Tang, Qiong Wang, Yukun Tian, Menghan Tu, Yupeng Wang, Changshen Ye, Jie Chen, Ting Qiu.  (2022)  Conjugated Microporous Poly(aniline) Enabled Hierarchical Porous Carbons for Hg(II) Adsorption.  LANGMUIR,  38  (43): (13238–13247).  [PMID:36260748]
5. Hang Yu, Dewang Li, Huayu Bao, Zhenhu Zhang, Hongli Liu, Fei Zhang, Shirong Wang.  (2022)  Multifunctional Cross-Linked Hole Transporting Interfacial Layer for Efficient and Stable Perovskite Solar Cells.  ACS Applied Energy Materials,  (9): (10742–10750).  [PMID:]
6. Tao Huang, Rongrong Zheng, Haiyang Chang, Di Ma, Haijun Niu.  (2022)  Sodium tert-butoxide as stable electrode material in aprotic electrolyte for high cycle stability organic sodium-ion batteries.  JOURNAL OF POWER SOURCES,  532  (231361).  [PMID:]
7. Xianqi Zhu, Lin Li, Jin Tang, Chunyu Yang, Hao Yu, Kunpeng Liu, Ziyan Zheng, Xinggui Gu, Qingsong Yu, Fu-Jian Xu, Zhihua Gan.  (2022)  Cascade-responsive nano-assembly for efficient photothermal-chemo synergistic inhibition of tumor metastasis by targeting cancer stem cells.  BIOMATERIALS,  280  (121305).  [PMID:34890970]
8. Yan-Xiong LIU, Long-Chun BIAN, Jie-Ren XIA, Qiu-E CAO.  (2021)  A Novel Ion-imprinted Polymer Based on Multi-walled Carbon Nanotubes for Solid Phase Extraction of Pd(II).  CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,  49  (e21170).  [PMID:]
9. Jian Chen, Kai Chen, Baichuan Han, Yunting Xue, Wanjuan Chen, Zhenzhong Gao, Xianfeng Hou.  (2020)  A novel single-fluorophore-based ratiometric fluorescent probe for detection of formaldehyde in air.  TETRAHEDRON,  76  (131681).  [PMID:]
10. Yue Yu, Lei Shi, Jianjun Guo, Xin Li, Wenbing Yang, Zhigang Zhang, Guangwen Xu.  (2021)  In-depth understanding of soluble base deactivation during the carbonate transesterification process.  FUEL,  285  (119201).  [PMID:]
11. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang.  (2020)  Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate.  ACS Sustainable Chemistry & Engineering,  (27): (9968–9979).  [PMID:]
12. Xinming Wu, Bin Huang, Qiguan Wang, Yan Wang.  (2019)  Thermally chargeable supercapacitor using a conjugated conducting polymer: Insight into the mechanism of charge-discharge cycle.  CHEMICAL ENGINEERING JOURNAL,  373  (493).  [PMID:]

References

1. Yuying Li, Junle Zhang, Yaxuan Shi, Yuancheng Zhang, Ge Shi, Xiaomeng Zhang, Zhe Cui, Peng Fu, Minying Liu, Xiaoguang Qiao, Yanjie He, Yudong Wang, Haitao Zhao, Wenjie Zhang, Xinchang Pang.  (2023)  Robust Strategy to Improve the Compatibility between Incorporated Upconversion Nanoparticles and the Bulk Transparent Polymer Matrix.  ACS Omega,  (35): (32159–32167).  [PMID:37692212]
2. Duanlian Tang, Minlei Yin, Xiaowei Du, Yuxin Duan, Jie Chen, Ting Qiu.  (2023)  Wettability tunable conjugated microporous poly(aniline)s for long-term, rapid and ppb level sequestration of Hg(II).  CHEMICAL ENGINEERING JOURNAL,  474  (145527).  [PMID:]
3. Duanlian Tang, Xiaoying Lyu, Zhixian Huang, Renwei Xu, Jie Chen, Ting Qiu.  (2023)  Nitrogen-doped microporous carbons as highly efficient adsorbents for CO2 and Hg(II) capture.  POWDER TECHNOLOGY,  427  (118769).  [PMID:]
4. Xiaoyu Lou, Xiaoyan Chen, Duanlian Tang, Qiong Wang, Yukun Tian, Menghan Tu, Yupeng Wang, Changshen Ye, Jie Chen, Ting Qiu.  (2022)  Conjugated Microporous Poly(aniline) Enabled Hierarchical Porous Carbons for Hg(II) Adsorption.  LANGMUIR,  38  (43): (13238–13247).  [PMID:36260748]
5. Hang Yu, Dewang Li, Huayu Bao, Zhenhu Zhang, Hongli Liu, Fei Zhang, Shirong Wang.  (2022)  Multifunctional Cross-Linked Hole Transporting Interfacial Layer for Efficient and Stable Perovskite Solar Cells.  ACS Applied Energy Materials,  (9): (10742–10750).  [PMID:]
6. Tao Huang, Rongrong Zheng, Haiyang Chang, Di Ma, Haijun Niu.  (2022)  Sodium tert-butoxide as stable electrode material in aprotic electrolyte for high cycle stability organic sodium-ion batteries.  JOURNAL OF POWER SOURCES,  532  (231361).  [PMID:]
7. Xianqi Zhu, Lin Li, Jin Tang, Chunyu Yang, Hao Yu, Kunpeng Liu, Ziyan Zheng, Xinggui Gu, Qingsong Yu, Fu-Jian Xu, Zhihua Gan.  (2022)  Cascade-responsive nano-assembly for efficient photothermal-chemo synergistic inhibition of tumor metastasis by targeting cancer stem cells.  BIOMATERIALS,  280  (121305).  [PMID:34890970]
8. Yan-Xiong LIU, Long-Chun BIAN, Jie-Ren XIA, Qiu-E CAO.  (2021)  A Novel Ion-imprinted Polymer Based on Multi-walled Carbon Nanotubes for Solid Phase Extraction of Pd(II).  CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,  49  (e21170).  [PMID:]
9. Jian Chen, Kai Chen, Baichuan Han, Yunting Xue, Wanjuan Chen, Zhenzhong Gao, Xianfeng Hou.  (2020)  A novel single-fluorophore-based ratiometric fluorescent probe for detection of formaldehyde in air.  TETRAHEDRON,  76  (131681).  [PMID:]
10. Yue Yu, Lei Shi, Jianjun Guo, Xin Li, Wenbing Yang, Zhigang Zhang, Guangwen Xu.  (2021)  In-depth understanding of soluble base deactivation during the carbonate transesterification process.  FUEL,  285  (119201).  [PMID:]
11. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang.  (2020)  Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate.  ACS Sustainable Chemistry & Engineering,  (27): (9968–9979).  [PMID:]
12. Xinming Wu, Bin Huang, Qiguan Wang, Yan Wang.  (2019)  Thermally chargeable supercapacitor using a conjugated conducting polymer: Insight into the mechanism of charge-discharge cycle.  CHEMICAL ENGINEERING JOURNAL,  373  (493).  [PMID:]

Solution Calculators