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S195897-5g

Available within 8-12 weeks(?)

$20.90

S195897-10g

10g

Available within 8-12 weeks(?)

$37.90

S195897-25g

25g

Available within 4-8 weeks(?)

$74.90

S195897-100g

100g

Available within 4-8 weeks(?)

$266.90

Basic Description

Synonyms	Benzenethiol sodium salt \| BP-30118 \| Sodium thiophenolate, purum, >=96.5% (RT) \| SODIUM BENZENETHIOLATE [HSDB] \| MFCD00066460 \| Thiophenol sodium salt \| HSDB 5771 \| SODIUM BENZENETHIOLATE \| Sodium thiophenolate \| Sodium phenylmercaptide \| DTXSID1027342 \|
Specifications & Purity	≥90%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether. Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies: · As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS). · Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes. · Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene. · Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.

Names and Identifiers

IUPAC Name	sodium;benzenethiolate
INCHI	InChI=1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChi Key	RZWQDAUIUBVCDD-UHFFFAOYSA-M
Canonical SMILES	C1=CC=C(C=C1)[S-].[Na+]
Isomeric SMILES	C1=CC=C(C=C1)[S-].[Na+]
WGK Germany	3
PubChem CID	4110039
Molecular Weight	132.16

Certificates

Certificate of Analysis(COA)

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5 results found

Lot Number	Certificate Type	Date	Item
A2211581	Certificate of Analysis	Oct 11, 2024	S195897
A2211609	Certificate of Analysis	Oct 11, 2024	S195897
L2402586	Certificate of Analysis	Jul 08, 2024	S195897
A2422192	Certificate of Analysis	Dec 07, 2021	S195897
E2408023	Certificate of Analysis	Dec 07, 2021	S195897

Chemical and Physical Properties

Sensitivity	Air and moisture sensitive
Melt Point(°C)	>300 °C

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3

FAQs and Articles

FAQ

DIBAL-H, Diisobutylaluminium hydride

Categories: Technical articles

Tags:

Chemical synthesis Reducing agent Diisobutylaluminium hydride DIBAL-H Hydrogenation reaction

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Zheng Wang,De-Man Han,Wen-Ping Jia,Qi-Zhong Zhou,Wei-Ping Deng. (2012-04-28) Reaction-based fluorescent probe for selective discrimination of thiophenols over aliphaticthiols and its application in water samples.. Analytical chemistry, 84 ((11)): (4915-4920). [PMID:22536992]
2. Yumiao Dong, Qinhui Xie, Shuo Wu, Junbo Li, Lei Sun, Wei Ji. (2023) Revealing Adsorption Mechanism of p-Mercaptobenzoic Acid with TiO2 Surfaces Using Electric Field-Enhanced Semiconductor SERS. Journal of Physical Chemistry C, 127 (19): (9418–9424). [PMID:] [10.1021/acs.jpcc.3c02113]
3. Zhuoyao Li, Chengyu Zhang, Huixiang Sheng, Jin Wang, Yameng Zhu, Liuyingzi Yu, Junjie Wang, Qiming Peng, Gang Lu. (2022) Molecular Cocatalyst of p-Mercaptophenylboronic Acid Boosts the Plasmon-Mediated Reduction of p-Nitrothiophenol. ACS Applied Materials & Interfaces, 14 (33): (38302–38310). [PMID:35943401] [10.1021/acsami.2c08327]
4. Qilong Li, Na Li, Xiangqiang Pan, Jian Zhu. (2021) Photo masking via breaking alkyl CSe bond of selenium-containing maleimide polymers by ultraviolet light. EUROPEAN POLYMER JOURNAL, 159 (110764). [PMID:] [10.1016/j.eurpolymj.2021.110764]
5. Yu Ji, Qiang Yao, Weihong Cao, Yueying Zhao. (2021) A Probable Origin of Dibenzothiophenes in Coals and Oils. Energies, 14 (1): (234). [PMID:] [10.3390/en14010234]

References

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30. Zhuoyao Li, Chengyu Zhang, Huixiang Sheng, Jin Wang, Yameng Zhu, Liuyingzi Yu, Junjie Wang, Qiming Peng, Gang Lu. (2022) Molecular Cocatalyst of p-Mercaptophenylboronic Acid Boosts the Plasmon-Mediated Reduction of p-Nitrothiophenol. ACS Applied Materials & Interfaces, 14 (33): (38302–38310). [PMID:35943401] [10.1021/acsami.2c08327]
31. Qilong Li, Na Li, Xiangqiang Pan, Jian Zhu. (2021) Photo masking via breaking alkyl CSe bond of selenium-containing maleimide polymers by ultraviolet light. EUROPEAN POLYMER JOURNAL, 159 (110764). [PMID:] [10.1016/j.eurpolymj.2021.110764]
32. Yu Ji, Qiang Yao, Weihong Cao, Yueying Zhao. (2021) A Probable Origin of Dibenzothiophenes in Coals and Oils. Energies, 14 (1): (234). [PMID:] [10.3390/en14010234]

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Sodium thiophenolate - 90%, high purity , CAS No.930-69-8