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tert-Butyllithium solution - 1.7 M in pentane, high purity , CAS No.594-19-4

  • 1.7 M in pentane
Item Number
T433023
Grouped product items
SKUSizeAvailabilityPrice Qty
T433023-25ml
25ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$39.90
T433023-4×25ml
4×25ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$115.90
T433023-100ml
100ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$119.90
T433023-500ml
500ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$546.90
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Organic lithium

Basic Description

Synonymstertbutyllithium | tert-Butyllithium | t-Butyllitium | ter-Butyllithium | t-butyllithiurn | tBuLi | t-BuLi | t-butyllithium | t-butyl-lithium | tert-butyllitium | t-butyllithum | t-butyl | Tert butyllithium | lithium | 2-methylpropane
Specifications & Purity1.7 M in pentane
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

tert -Butyllithium solution ( tert -BuLi) is an organolithium compound, used as a strong base in organic chemistry. It facilitates lithium-halogen exchange reaction and also can be employed in the deprotonation of C-H compounds and amines.


Application

tert -Butyllithium solution can be used as a strong base in the synthesis of: Alkyllithium derivatives form alkyl iodides and diiodoalkanes by halogen-lithium exchange reaction. Inorganic polymer [(LiMo 3 Se 3 )n] from [(InMo 3 Se 3 )n] by reductive intercalation method. Adducts of cinnamic acid (1,3- and 1,4-adducts) by reacting with C-C double of cinnamic acid.

Names and Identifiers

IUPAC Name lithium;2-methylpropane
INCHI InChI=1S/C4H9.Li/c1-4(2)3;/h1-3H3;/q-1;+1
InChi Key UBJFKNSINUCEAL-UHFFFAOYSA-N
Canonical SMILES [Li+].C[C-](C)C
Isomeric SMILES [Li+].C[C-](C)C
WGK Germany 2
PubChem CID 638178
Molecular Weight 64.06
Beilstein 3587204

Certificates

Certificate of Analysis(COA)

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To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

14 results found

Lot NumberCertificate TypeDateItem
G2417803Certificate of AnalysisJun 21, 2024 T433023
G2417804Certificate of AnalysisJun 21, 2024 T433023
G2417805Certificate of AnalysisJun 21, 2024 T433023
G2417806Certificate of AnalysisJun 21, 2024 T433023
D2402506Certificate of AnalysisMar 18, 2024 T433023
D2402507Certificate of AnalysisMar 18, 2024 T433023
D2402508Certificate of AnalysisMar 18, 2024 T433023
E2408012Certificate of AnalysisMar 18, 2024 T433023
F2413071Certificate of AnalysisMar 18, 2024 T433023
B2418208Certificate of AnalysisNov 11, 2023 T433023
K2323293Certificate of AnalysisNov 11, 2023 T433023
K2323294Certificate of AnalysisNov 11, 2023 T433023
K2323295Certificate of AnalysisNov 11, 2023 T433023
L2325042Certificate of AnalysisNov 11, 2023 T433023

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Chemical and Physical Properties

SensitivityCO2 sensitive；Moisture sensitive
Flash Point(°F)-56°F
Flash Point(°C)-49℃

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS09,   GHS05,   GHS07,   GHS02
Signal Danger
Hazard Statements

H411:Toxic to aquatic life with long lasting effects

H260:In contact with water releases flammable gases which may ignite spontaneously

H314:Causes severe skin burns and eye damage

H225:Highly Flammable liquid and vapor

H336:May cause drowsiness or dizziness

H250:Catches fire spontaneously if exposed to air

H304:May be fatal if swallowed and enters airways

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310:IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P223:Do not allow contact with water.

P231+P232:Handle under inert gas/... Protect from moisture.

P370+P378:In case of fire: Use ... to extinguish.

P422:Store contents under ...

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P310:Immediately call a POISON CENTER or doctor/physician.

P222:Do not allow contact with air.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P302+P334:IF ON SKIN: Immerse in cool water [or wrap in wet bandages].

P335+P334:Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

WGK Germany 2

Related Documents

 SDS

 Specification Sheet

References

1. Shigeo Hayashi, Naomi Ueno, Akio Murase, Junji Takada,.  (2014-02-13)  Design, synthesis and structure-activity relationship studies of novel and diverse cyclooxygenase-2 inhibitors as anti-inflammatory drugs..  Journal of enzyme inhibition and medicinal chemistry,  29  ((6)): ( 846-867 ).  [PMID:24517373]
2. Xinyi Chia,Adriano Ambrosi,Zdenek Sofer,Jan Luxa,Martin Pumera.  (2015-04-22)  Catalytic and charge transfer properties of transition metal dichalcogenides arising from electrochemical pretreatment..  ACS nano,  9  ((5)): (5164-5179).  [PMID:25894369]
3. Adeline Huiling Loo,Alessandra Bonanni,Zdenek Sofer,Martin Pumera.  (2015-05-28)  Transitional Metal/Chalcogen Dependant Interactions of Hairpin DNA with Transition Metal Dichalcogenides, MX2..  Chemphyschem : a European journal of chemical physics and physical chemistry,  16  ((11)): (2304-2306).  [PMID:26014462]
4. Hsiao-Fang Wang,Po-Ting Chiu,Chih-Ying Yang,Zhi-Hong Xie,Yu-Chueh Hung,Jing-Yu Lee,Jing-Cherng Tsai,Ishan Prasad,Hiroshi Jinnai,Edwin L Thomas,Rong-Ming Ho.  (2020-10-16)  Networks with controlled chirality via self-assembly of chiral triblock terpolymers..  Science advances,  6  ((42)):   [PMID:33055164]

Solution Calculators

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