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Tetrabutylammonium hydrogen difluoride solution - technical, ~50% in methylene chloride (T), high purity , CAS No.23868-34-0
Basic Description Synonyms ZHBDKVWQJKYIFF-UHFFFAOYSA-M | tetrabutylazanium;fluoride;hydrofluoride | FT-0713578 | tetra-n-butylammonium bifluoride | D75244 | SCHEMBL1847525 | tetrabutylammonium fluoride hydrofluoride | Tetrabutylammonium bifluoride | MFCD00077877 | DTXSID10447386 | Specifications & Purity technical, ~50% in methylene chloride (T) Storage Temp Store at 2-8°C Shipped In Wet ice Grade technical grade Product Description Application
Used as an etchant for silica films Reactant for: Nucleophilic fluorination Ring-opening fluorination reaction Substitution reactions Tetrabutylammonium hydrogen difluoride (TBABF) can be used as a reagent: For the conversion of aromatic boronic acids and esters into corresponding tetrabutylammonium trifluoroborate salts. These salts are utilized as surrogates of boronic acids in Suzuki-Miyaura cross-coupling reactions. In the nucleophilic fluorination of organic halides, tosylates, and triflates. For the regioselective synthesis of fluorohydrins by ring-opening of terminal epoxides.
Names and Identifiers IUPAC Name tetrabutylazanium;fluoride;hydrofluoride INCHI InChI=1S/C16H36N.2FH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;2*1H/q+1;;/p-1 InChi Key ZHBDKVWQJKYIFF-UHFFFAOYSA-M Canonical SMILES CCCC[N+](CCCC)(CCCC)CCCC.F.[F-] Isomeric SMILES CCCC[N+](CCCC)(CCCC)CCCC.F.[F-] PubChem CID 10891295 Molecular Weight 281.48 Reaxy-Rn 4729304
Safety and Hazards(GHS) Pictogram(s) GHS05 Signal Danger Hazard Statements H314: Causes severe skin burns and eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
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P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P302+P361+P354: IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P316: Get emergency medical help immediately.
Reaxy-Rn 4729304
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