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Tetrabutylphosphonium hydroxide solution - 40 wt.% in H2O, high purity , CAS No.14518-69-5

15 Citations

40 wt.% in H2O

CAS#: 14518-69-5
Formula: (CH₃CH₂CH₂CH₂)₄P(OH)
Molecular Weight: 276.44
Beilstein Registry Number: 4826225
EC Number: 238-528-0
MDL number: MFCD00068456
PubChem CID: 84487

Item Number

T121851

Grouped product items
SKU	Size	Availability	Price
T121851-5ml	5ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$19.90
T121851-25ml	25ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$79.90
T121851-50ml	50ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$129.90

View related series

Element classified compounds Phosphorus compounds

Basic Description

Synonyms	TBPH \| SCHEMBL108027 \| EINECS 238-528-0 \| DFQPZDGUFQJANM-UHFFFAOYSA-M \| TBPH solution \| Phosphonium, tetrabutyl-, hydroxide (1:1) \| AKOS015950702 \| DTXSID70884758 \| T2571 \| MFCD00068456 \| tetrabutylphosphanium;hydroxide \| FT-0769999 \| Tetrabutylphosphoniu
Specifications & Purity	40 wt.% in H2O
Shipped In	Normal
Product Description	Tetrabutylphosphonium hydroxide (TBPH) can be used: • To convert poorly water-soluble acidic APIs into TBP ionic liquids (IL). • As a cation source in the synthesis of Good′s buffer ionic liquids (GB-ILs) via an acid−base neutralization reaction with Good′s buffer anions. • To synthesize tetrabutylphosphonium acetate, which along with Cu2O-nanoparticles forms an excellent catalyst system for protodecarboxylation reactions

Names and Identifiers

IUPAC Name	tetrabutylphosphanium;hydroxide
INCHI	InChI=1S/C16H36P.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1
InChi Key	DFQPZDGUFQJANM-UHFFFAOYSA-M
Canonical SMILES	CCCC[P+](CCCC)(CCCC)CCCC.[OH-]
Isomeric SMILES	CCCC[P+](CCCC)(CCCC)CCCC.[OH-]
WGK Germany	3
PubChem CID	84487
Molecular Weight	276.44
Beilstein	4826225
Reaxy-Rn	4826225

Certificates

Certificate of Analysis(COA)

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8 results found

Lot Number	Certificate Type	Date	Item
K2310112	Certificate of Analysis	Oct 31, 2023	T121851
K2310113	Certificate of Analysis	Oct 31, 2023	T121851
C2317662	Certificate of Analysis	Mar 10, 2023	T121851
C2317663	Certificate of Analysis	Mar 10, 2023	T121851
C2317677	Certificate of Analysis	Mar 10, 2023	T121851
C2210675	Certificate of Analysis	Feb 25, 2022	T121851
C2210698	Certificate of Analysis	Feb 25, 2022	T121851
C2210699	Certificate of Analysis	Feb 25, 2022	T121851

Chemical and Physical Properties

Solubility	Miscible with water
Refractive Index	1.412

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage
Precautionary Statements	P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician.
WGK Germany	3
Reaxy-Rn	4826225

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Wei Guo,Jian Han,Shengmin Wu,Xiongjie Shi,Qiangwei Wang,Bingsheng Zhou. (2019-12-06) Bis(2-ethylhexyl)-2,3,4,5-tetrabromophthalate Affects Lipid Metabolism in Zebrafish Larvae via DNA Methylation Modification.. Environmental science & technology, 54 ((1)): (355-363). [PMID:31804803]
2. Ping Xiang,Rong-Yan Liu,Hong-Jie Sun,Yun-Wen Yang,Xin-Yi Cui,Lena Q Ma. (2017-03-21) Effects of novel brominated flame retardant TBPH and its metabolite TBMEHP on human vascular endothelial cells: Implication for human health risks.. Environmental research, 156 (834-842). [PMID:28318508]
3. Wenbin Jin,Yuqi Ke,Xianxian Liu,Qiwei Yang,Zongbi Bao,Baogen Su,Qilong Ren,Yiwen Yang,Huabin Xing. (2017-04-08) Enhanced self-assembly for the solubilization of cholesterol in molecular solvent/ionic liquid mixtures.. Physical chemistry chemical physics : PCCP, 19 ((17)): (10835-10842). [PMID:28387400]
4. Lei Yuan, Leihao Zhang, Guilin Li, Shaojuan Zeng, Qizhou Xue, Chongyang Jiang, Xiangping Zhang. (2023) Phenoxy-Nitrile Bifunctional Ionic Liquid for Efficient Electroreduction of CO2 to Oxalate. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 62 (41): (16931–16938). [PMID:10747847] [10.1021/acs.iecr.3c02876]
5. Heming Zhang, Chan Meng, Qian Su, Li Dong, Wen Liu, Xiaokang Wang, Yunong Li, Weiguo Cheng. (2023) Sterically regulated halogen-free bifunctional ionic liquids for catalytic conversion of CO2 into cyclic carbonates. ChemistrySelect, 8 (37): (e202301015). [PMID:17906697] [10.1002/slct.202301015]
6. Peng Wang, Jixia Qiu, Peng Gao, Rui Dong, Yunyan Han, Mingjin Fan. (2023) The tribological behaviors and anti-corrosion performances of 5-phenyltetrazole ionic liquid additives for water lubricants. WEAR, 516-517 (204621). [PMID:] [10.1016/j.wear.2023.204621]
7. Haolin Li, Lin Ma, Ping Wen, Yunyan Han, Rui Dong, Mingjin Fan. (2022) Molecular structure insight into the tribological behavior of sulfonate ionic liquids as lubricants for titanium alloys. JOURNAL OF MOLECULAR LIQUIDS, 357 (119082). [PMID:] [10.1016/j.molliq.2022.119082]
8. Qiao Yang, Jingcheng Hao. (2022) Synthesis of metal sulfides via ionic liquid-mediated assembly strategy and their photocatalytic degradation of dyes in water. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 633 (127848). [PMID:] [10.1016/j.colsurfa.2021.127848]
9. Ran Ping, Penghui Zhao, Qianqian Zhang, Guangyu Zhang, Fusheng Liu, Mengshuai Liu. (2021) Catalytic Conversion of CO2 from Simulated Flue Gases with Aminophenol-Based Protic Ionic Liquids to Produce Quinazoline-2,4(1H,3H)-diones under Mild Conditions. ACS Sustainable Chemistry & Engineering, 9 (14): (5240–5249). [PMID:] [10.1021/acssuschemeng.1c01466]
10. Fangchao Cheng, Panpan Zhao, Tulong Ouyang, Jianping Sun, Yiqiang Wu. (2021) Comprehensive utilization strategy of cellulose in a facile, controllable, high-yield preparation process of cellulose nanocrystals using aqueous tetrabutylphosphonium hydroxide. GREEN CHEMISTRY, 23 (4): (1805-1815). [PMID:] [10.1039/D0GC04370B]
11. Qiang Yuan, Jifeng Pang, Wenguang Yu, Mingyuan Zheng. (2020) Vapor-Phase Furfural Decarbonylation over a High-Performance Catalyst of 1%Pt/SBA-15. Catalysts, 10 (11): (1304). [PMID:] [10.3390/catal10111304]
12. Fusheng Liu, Ran Ping, Yongqiang Gu, Penghui Zhao, Bin Liu, Jun Gao, Mengshuai Liu. (2020) Efficient One Pot Capture and Conversion of CO2 into Quinazoline-2,4(1H,3H)-diones Using Triazolium-Based Ionic Liquids. ACS Sustainable Chemistry & Engineering, 8 (7): (2910–2918). [PMID:] [10.1021/acssuschemeng.9b07242]
13. Hao Wu, Zhaizhu Deng, Bijian Zhou, Minghui Qi, Minghuang Hong, Guobin Ren. (2019) Improved transdermal permeability of ibuprofen by ionic liquid technology: Correlation between counterion structure and the physicochemical and biological properties. JOURNAL OF MOLECULAR LIQUIDS, 283 (399). [PMID:] [10.1016/j.molliq.2019.03.046]
14. Zhenhao Wei, Kake Zhu, Lanyu Xing, Fan Yang, Yunsheng Li, Yarong Xu, Xuedong Zhu. (2017) Steam-assisted transformation of natural kaolin to hierarchical ZSM-11 using tetrabutylphosphonium hydroxide as structure-directing agent: synthesis, structural characterization and catalytic performance in the methanol-to-aromatics reaction. RSC Advances, 7 (39): (24015-24021). [PMID:] [10.1039/C7RA03141F]
15. Yanjun Gong, Qiongzheng Hu, Yongxian Guo, Li Yu. (2017) Photocatalyzed Reduction of Chromium(VI) and Thermal-Driven Heterogeneous Separation. ACS Sustainable Chemistry & Engineering, 5 (6): (4511–4516). [PMID:] [10.1021/acssuschemeng.7b00554]

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44. Heming Zhang, Chan Meng, Qian Su, Li Dong, Wen Liu, Xiaokang Wang, Yunong Li, Weiguo Cheng. (2023) Sterically regulated halogen-free bifunctional ionic liquids for catalytic conversion of CO2 into cyclic carbonates. ChemistrySelect, 8 (37): (e202301015). [PMID:17906697] [10.1002/slct.202301015]
45. Peng Wang, Jixia Qiu, Peng Gao, Rui Dong, Yunyan Han, Mingjin Fan. (2023) The tribological behaviors and anti-corrosion performances of 5-phenyltetrazole ionic liquid additives for water lubricants. WEAR, 516-517 (204621). [PMID:] [10.1016/j.wear.2023.204621]
46. Haolin Li, Lin Ma, Ping Wen, Yunyan Han, Rui Dong, Mingjin Fan. (2022) Molecular structure insight into the tribological behavior of sulfonate ionic liquids as lubricants for titanium alloys. JOURNAL OF MOLECULAR LIQUIDS, 357 (119082). [PMID:] [10.1016/j.molliq.2022.119082]
47. Qiao Yang, Jingcheng Hao. (2022) Synthesis of metal sulfides via ionic liquid-mediated assembly strategy and their photocatalytic degradation of dyes in water. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 633 (127848). [PMID:] [10.1016/j.colsurfa.2021.127848]
48. Ran Ping, Penghui Zhao, Qianqian Zhang, Guangyu Zhang, Fusheng Liu, Mengshuai Liu. (2021) Catalytic Conversion of CO2 from Simulated Flue Gases with Aminophenol-Based Protic Ionic Liquids to Produce Quinazoline-2,4(1H,3H)-diones under Mild Conditions. ACS Sustainable Chemistry & Engineering, 9 (14): (5240–5249). [PMID:] [10.1021/acssuschemeng.1c01466]
49. Fangchao Cheng, Panpan Zhao, Tulong Ouyang, Jianping Sun, Yiqiang Wu. (2021) Comprehensive utilization strategy of cellulose in a facile, controllable, high-yield preparation process of cellulose nanocrystals using aqueous tetrabutylphosphonium hydroxide. GREEN CHEMISTRY, 23 (4): (1805-1815). [PMID:] [10.1039/D0GC04370B]
50. Qiang Yuan, Jifeng Pang, Wenguang Yu, Mingyuan Zheng. (2020) Vapor-Phase Furfural Decarbonylation over a High-Performance Catalyst of 1%Pt/SBA-15. Catalysts, 10 (11): (1304). [PMID:] [10.3390/catal10111304]
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