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T111021-1g

Available within 4-8 weeks(?)

$35.90

T111021-5g

Available within 4-8 weeks(?)

$158.90

T111021-10g

10g

Available within 4-8 weeks(?)

$284.90

T111021-25g

25g

Available within 4-8 weeks(?)

$595.90

T111021-100g

100g

Available within 4-8 weeks(?)

$2,379.90

Basic Description

Synonyms	14221-01-3\|Tetrakis(triphenylphosphine)palladium\|Tetrakis(triphenylphosphine)palladium(0)\|Tetrakis(triphenylphosphine) palladium(0)\|Tetra(triphenylphosphine)palladium\|palladium;triphenylphosphane\|Palladium-tetrakis(triphenylphosphine)\|PD(PPH3)4\|Palladium,
Specifications & Purity	Pd ≥8.9%
Storage Temp	Store at -20°C,Argon charged
Shipped In	Ice chest + Ice pads
Product Description	A high-yielding catalyst used in coupling reactions. Product class M-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - Achiral Reaction type Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Hiyama Coupling Reaction, Mizoroki Heck Coupling Reaction, Negishi Coupling Reaction, Sonogashira-Hagihara Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Cyclization, Isomerization, Oxidation, Reduction Chemical properties Chemical formula C72H60P4Pd Empirical formula [Pd(PPh3)4] Molecular weight 1155.58 Metal Pd Theoretical metal content 9 Physical state crystalline Color yellow Applications & references Suzuki coupling reaction as key synthesis step in the preparation of the chiral, nonracemic 3-aryl piperidine (OSU 6162), a potential central nervous system agent. Reference: Org. Proc. Res. Dev. 2003, 7, 385. (DOI: 10.1021/op025620u) Aryl-aryl Negishi coupling reaction in the preparation of 5-[2-Methoxy-5-(4-pyridinyl)phenyl]-2,1,3-benzoxadiazole (PDE472), a selective inhibitor of the phosphodiesterase PDE4D isoenzyme, which is well known as drug target for the treatment of asthma. Reference: Org. Proc. Res. Dev. 2003, 7, 436. (DOI: 10.1021/op025615q) Palladium catalyzed synthesis of trans-1,2-diazetidines by cyclization of 2,3-allenyl hydrazines with aryl halides. Reference: Angew. Chem. Int. Ed. 2008, 47, 4581. (DOI: 10.1021/anie.200800364) Palladium catalyzed cross coupling reaction of α-diazocarbonyl compounds with arylboronic acids providing access to α-aryl substituted α,β-unsaturated carbonyl compounds. Reference: J. Am. Chem. Soc. 2008, 130, 1566. (DOI: 10.1021/ja0782293) Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups. Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)

Names and Identifiers

IUPAC Name	palladium;triphenylphosphane
INCHI	InChI=1S/4C18H15P.Pd/c41-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h41-15H;
InChi Key	NFHFRUOZVGFOOS-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]
WGK Germany	3
PubChem CID	11979704
Molecular Weight	1155.56
Beilstein	6704828
Reaxy-Rn	6704828

Certificates

Certificate of Analysis(COA)

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19 results found

Lot Number	Certificate Type	Date	Item
H2415051	Certificate of Analysis	Jul 26, 2024	T111021
G2431521	Certificate of Analysis	Jul 26, 2024	T111021
G2431520	Certificate of Analysis	Jul 26, 2024	T111021
G2431517	Certificate of Analysis	Jul 26, 2024	T111021
G2431519	Certificate of Analysis	Jul 26, 2024	T111021
G2230245	Certificate of Analysis	May 07, 2024	T111021
G2230246	Certificate of Analysis	May 07, 2024	T111021
G2230247	Certificate of Analysis	May 07, 2024	T111021
G2230248	Certificate of Analysis	May 07, 2024	T111021
K2316093	Certificate of Analysis	Jul 12, 2023	T111021
K1929224	Certificate of Analysis	Jul 12, 2023	T111021
I2113187	Certificate of Analysis	Jun 16, 2023	T111021
I2113188	Certificate of Analysis	Jun 16, 2023	T111021
I2113189	Certificate of Analysis	Jun 16, 2023	T111021
G2116002	Certificate of Analysis	Apr 18, 2023	T111021
G2103245	Certificate of Analysis	Apr 18, 2023	T111021
G2103244	Certificate of Analysis	Apr 18, 2023	T111021
G2103243	Certificate of Analysis	Apr 18, 2023	T111021
G2315066	Certificate of Analysis	Jul 07, 2022	T111021

Chemical and Physical Properties

Solubility	Soluble in 1% Toluene.
Sensitivity	Heat, Light, Air, Moisture Sensitive.
Melt Point(°C)	103-107°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H413:May cause long lasting harmful effects to aquatic life H302:Harmful if swallowed H317:May cause an allergic skin reaction
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P270:Do not eat, drink or smoke when using this product. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P301+P317:IF SWALLOWED: Get medical help.
WGK Germany	3
Reaxy-Rn	6704828

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References

1. Jesse J Chen,Ching-Hsuan Tsai,Xin Cai,Allen T Horhota,Larry W McLaughlin,Jack W Szostak. (2009-03-24) Enzymatic primer-extension with glycerol-nucleoside triphosphates on DNA templates.. PloS one, 4 ((3)): (e4949-e4949). [PMID:19305495]
2. V P Baillargeon,J K Stille. (1986-02-01) Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride.. Journal of the American Chemical Society, 108 ((3)): (452-461). [PMID:22175460]
3. Haiyin Li,Xiqi Zhang,Xiaoyong Zhang,Bin Yang,Yang Yang,Zengfang Huang,Yen Wei. (2014-06-14) Zwitterionic red fluorescent polymeric nanoparticles for cell imaging.. Macromolecular bioscience, 14 ((10)): (1361-1367). [PMID:24923807]
4. Wenhan Zhang, Joseph M Ready,. (2014-07-01) The ketene-surrogate coupling: catalytic conversion of aryl iodides into aryl ketenes through ynol ethers.. Angewandte Chemie (International ed. in English), 53 ((34)): ( 8980-8984 ). [PMID:24975840]
5. Shouchun Yin,Lin Dong,Yijun Xia,Bin Dong,Xingxing He,Dong Chen,Huayu Qiu,Bo Song. (2015-05-01) Controlled self-assembly of a pyrene-based bolaamphiphile by acetate ions: from nanodisks to nanofibers by fluorescence enhancement.. Soft matter, 11 ((22)): (4424-4429). [PMID:25925332]
6. Chanchal Chakraborty,Rakesh K Pandey,Md Delwar Hossain,Zdenek Futera,Satoshi Moriyama,Masayoshi Higuchi. (2015-08-19) Platinum(II)-Based Metallo-Supramolecular Polymer with Controlled Unidirectional Dipoles for Tunable Rectification.. ACS applied materials & interfaces, 7 ((34)): (19034-19042). [PMID:26285226]
7. Debabrata Jana,Shatabdi Boxi,Partha P Parui,Binay K Ghorai. (2015-09-09) Planar-rotor architecture based pyrene-vinyl-tetraphenylethylene conjugated systems: photophysical properties and aggregation behavior.. Organic & biomolecular chemistry, 13 ((43)): (10663-10674). [PMID:26347380]
8. Hongyu Mi,Mingming Guan,Jilin Liu,Hongyan Shan,Qiang Fei,Yanfu Huan,Guodong Feng. (2017-01-17) Conjugated polymer with carboxylate groups-Hg. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 176 (168-173). [PMID:28092827]
9. Hong-Yu Mi,Ji-Lin Liu,Ming-Ming Guan,Qing-Wen Liu,Zhi-Quan Zhang,Guo-Dong Feng. (2018-06-02) Fluorescence chemical sensor for determining trace levels of nitroaromatic explosives in water based on conjugated polymer with guanidinium side groups.. Talanta, 187 (314-320). [PMID:29853053]
10. Mingming Guan,Chunling Xu,Jiahua Ma,Ting Yang,Jilin Liu,Guodong Feng. (2019-02-05) A Conjugated Polymer Fluorescent Sensor for Continuous Identification of Copper(II) and Pyrophosphate in Blood Serum and Synovial Fluid.. Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 35 ((6)): (625-630). [PMID:30713218]
11. Hong-Lei Xu,Nikolay V Tkachenko,Zi-Chuan Wang,Wei-Xing Chen,Lei Qiao,Alvaro Muñoz-Castro,Alexander I Boldyrev,Zhong-Ming Sun. (2020-10-22) A sandwich-type cluster containing Ge@Pd3 planar fragment flanked by aromatic nonagermanide caps.. Nature communications, 11 ((1)): (5286-5286). [PMID:33082326]

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Tetrakis(triphenylphosphine)palladium(0) - Pd ≥8.9%, high purity , CAS No.14221-01-3

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

more

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

FAQs and Articles

References

Solution Calculators

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SKU	Size	Availability	Price
T111021-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$35.90
T111021-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$158.90
T111021-10g	10g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$284.90
T111021-25g	25g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$595.90
T111021-100g	100g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$2,379.90