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Trifluoroacetic acid-d - 99.5 atom % D+0.03%TMS,for NMR, high purity , CAS No.599-00-8

  • ≥99.5 atom% D
  • contains 0.03%(v/v) TMS,for NMR
Item Number
T109782
Grouped product items
SKUSizeAvailabilityPrice Qty
T109782-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$103.90
T109782-10g
10g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$171.90
T109782-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$399.90
View related series
Deuterated reagent Stable isotope

Basic Description

SynonymsTrifluoroacetic acid-d|599-00-8|deuterio 2,2,2-trifluoroacetate|Deuterotrifluoroacetic acid|TFA-d|CF3COOD|Acetic acid-d, trifluoro-|deuterated trifluoroacetic acid|MFCD00044563|Trifluoroacetic acid-d (TFA-d)|Trifluoroacetic acid-d, 99.5 atom % D|Acetic ac
Specifications & Purity99.5 atom % D+0.03%TMS,for NMR
Storage TempArgon charged
Shipped InNormal
Product Description

Trifluoroacetic acid-d is a standard purity solvent suitable for routine NMR analyses (conducted at ambient temperatures where quality is less critical).
Trifluoroacetic acid-d is a synthetic reagent having isotopic purity of 99.5atom%D. It undergoes SE′ reaction with (R)-(E)-1,3-diphenyl-3-trimethylsilylpropene, via antistereochemistry to afford (R)-(E)-1,3-diphenylpropene-3-d.Vapor phase dissociation of trifluoroacetic acid-d has been studied.
Application:

Trifluoroacetic acid-d may be employed as solvent to investigate the conformations of cyclic peptides by proton NMR spectra. It may be used to compose NMR solvent mixture to investigate the NMR spectra of high molecular weight polyesters such as polyglycolide (PG) and poly(ethylene terephthalate) (PET).

Names and Identifiers

IUPAC Name deuterio 2,2,2-trifluoroacetate
INCHI InChI=1S/C2HF3O2/c3-2(4,5)1(6)7/h(H,6,7)/i/hD
InChi Key DTQVDTLACAAQTR-DYCDLGHISA-N
Canonical SMILES C(=O)(C(F)(F)F)O
Isomeric SMILES [2H]OC(=O)C(F)(F)F
WGK Germany 3
PubChem CID 71502
UN Number 2699
Molecular Weight 115.03
Beilstein 1768662

Certificates

Certificate of Analysis(COA)

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11 results found

Lot NumberCertificate TypeDateItem
C2419361Certificate of AnalysisMar 07, 2024 T109782
H2103464Certificate of AnalysisJan 02, 2024 T109782
A2220325Certificate of AnalysisOct 16, 2023 T109782
A2220346Certificate of AnalysisOct 16, 2023 T109782
I2305682Certificate of AnalysisAug 26, 2023 T109782
I2305683Certificate of AnalysisAug 26, 2023 T109782
I2305685Certificate of AnalysisAug 26, 2023 T109782
B2309819Certificate of AnalysisNov 05, 2022 T109782
B2309883Certificate of AnalysisNov 05, 2022 T109782
B2309890Certificate of AnalysisNov 05, 2022 T109782
A2220344Certificate of AnalysisDec 29, 2021 T109782

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Chemical and Physical Properties

SolubilitySoluble in water.
SensitivityHygroscopic
Refractive Index1.3
Boil Point(°C)75°C
Melt Point(°C)-15°C

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS07
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H412:Harmful to aquatic life with long lasting effects

H332:Harmful if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P271:Use only outdoors or in a well-ventilated area.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P317:Get emergency medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3

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