Basic Description

Synonyms	CHEBI:38913 \| Trimethyl borate-11B \| Boric acid (H3BO3), trimethyl ester \| trimethoxy borane \| Trimethoxyborane \| Urea,N-(cyclohexylmethyl)-N'-cyclopentyl- \| trimethyl boric acid \| Borester O \| MFCD00008346 \| Trimethyl borate, purified by redistillation,
Specifications & Purity	98%
Storage Temp	Room temperature,Argon charged
Shipped In	Normal
Product Description	Trimethyl borate reacts with a Grignard reagent or organolithium compounds to yield dimethyl boronates, which upon subsequent aqueous acid treatment afford corresponding boronic acids. The resultant boronic acids or esters are useful intermediates in various cross-coupling reactions such as Suzuki coupling and Chan-Lam coupling.It is also used in the preparation of sodium borohydride.

Names and Identifiers

IUPAC Name	trimethyl borate
INCHI	InChI=1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
InChi Key	WRECIMRULFAWHA-UHFFFAOYSA-N
Canonical SMILES	B(OC)(OC)OC
Isomeric SMILES	B(OC)(OC)OC
WGK Germany	1
RTECS	ED5600000
PubChem CID	8470
UN Number	2416
Packing Group	II
Molecular Weight	103.91
Beilstein	1697939
Reaxy-Rn	1697939

Enter Lot Number to search for COA:

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17 results found

Lot Number	Certificate Type	Date	Item
G2422349	Certificate of Analysis	Jul 06, 2024	T104043
G2422350	Certificate of Analysis	Jul 06, 2024	T104043
G2422351	Certificate of Analysis	Jul 06, 2024	T104043
H2421306	Certificate of Analysis	Apr 28, 2024	T104043
K2310436	Certificate of Analysis	Oct 26, 2023	T104043
K2310435	Certificate of Analysis	Oct 26, 2023	T104043
C2429032	Certificate of Analysis	Oct 26, 2023	T104043
F2306896	Certificate of Analysis	Jun 09, 2023	T104043
F2306898	Certificate of Analysis	Jun 09, 2023	T104043
K22171080	Certificate of Analysis	Nov 28, 2022	T104043
G2229439	Certificate of Analysis	Jul 16, 2022	T104043
I2311041	Certificate of Analysis	Jul 16, 2022	T104043
G2229437	Certificate of Analysis	Jul 16, 2022	T104043
G2229436	Certificate of Analysis	Jul 16, 2022	T104043
B2211163	Certificate of Analysis	Dec 09, 2021	T104043
B2211181	Certificate of Analysis	Dec 09, 2021	T104043
B2211167	Certificate of Analysis	Dec 09, 2021	T104043

Solubility	Miscible with tetrahydrofuran, ether, isoporpylamine, hexane and methanol.
Sensitivity	moisture sensitive
Refractive Index	1.3562-1.3582
Flash Point(°F)	17.6 °F
Flash Point(°C)	-8℃
Boil Point(°C)	67～68°C
Melt Point(°C)	-29°C

Pictogram(s)	GHS06, GHS08, GHS02
Signal	Warning
Hazard Statements	H319:Causes serious eye irritation H225:Highly Flammable liquid and vapor H360:May damage fertility or the unborn child H370:Causes damage to organs H301+H311+H331:Toxic if swallowed, in contact with skin or if inhaled
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P403+P235:Store in a well-ventilated place. Keep cool. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P362+P364:Take off contaminated clothing and wash it before reuse. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P317:Get emergency medical help.
WGK Germany	1
RTECS	ED5600000
Reaxy-Rn	1697939
Class	3
Merck Index	9712
RIDADR	UN 2416 3 / PGII

1. Longli Ma, Xuanyang Li, Jian Tan, Zhan Fang, Zhu Liu, Yuan Wang, Chuming Ye, Pengshu Yi, Mingxin Ye, Jianfeng Shen. (2023) Anion-Immobilized Gel Polymer Electrolyte with a High Ion Transference Number for High-Performance Lithium/Sodium Metal Batteries. ACS Applied Materials & Interfaces, 15 (49): (57201–57210). [PMID:38041638]
2. Chaoze Liu, Zheng Zhou, Jiawei Ji, Yaxin Gu, Song Yan, Shaobo Yang, Rongjuan Zhang, Zhenya Liu, Yanming Xue, Chengchun Tang. (2023) Controllable preparation of boron nitride microspheres and their epoxy-based thermoconductive composites. CERAMICS INTERNATIONAL, 49 (27138). [PMID:]
3. Zexia Li, Jingwen Yang, Hejun Gao, Jiaxiao Qiao, Wei Qiao, Peng Wang, Jun Zhang, Chengchun Tang, Yanming Xue. (2023) Boron Nitride Microspheres via Pyrolysis of Polymerized Precursors. ACS Omega, 8 (17): (15239–15248). [PMID:37151536]
4. Dewei Qiu, Ping Zhou, Jiawei Kang, Zhijun Chen, Zhiyong Xu, Hanwen Yang, Jun Tao, Fanrong Ai. (2022) ZnO nanoparticle modified chitosan/borosilicate bioglass composite scaffold for inhibiting bacterial infection and promoting bone regeneration. Biomedical Materials, 17 (6): (65023). [PMID:36394277]

1. Longli Ma, Xuanyang Li, Jian Tan, Zhan Fang, Zhu Liu, Yuan Wang, Chuming Ye, Pengshu Yi, Mingxin Ye, Jianfeng Shen. (2023) Anion-Immobilized Gel Polymer Electrolyte with a High Ion Transference Number for High-Performance Lithium/Sodium Metal Batteries. ACS Applied Materials & Interfaces, 15 (49): (57201–57210). [PMID:38041638]
2. Chaoze Liu, Zheng Zhou, Jiawei Ji, Yaxin Gu, Song Yan, Shaobo Yang, Rongjuan Zhang, Zhenya Liu, Yanming Xue, Chengchun Tang. (2023) Controllable preparation of boron nitride microspheres and their epoxy-based thermoconductive composites. CERAMICS INTERNATIONAL, 49 (27138). [PMID:]
3. Zexia Li, Jingwen Yang, Hejun Gao, Jiaxiao Qiao, Wei Qiao, Peng Wang, Jun Zhang, Chengchun Tang, Yanming Xue. (2023) Boron Nitride Microspheres via Pyrolysis of Polymerized Precursors. ACS Omega, 8 (17): (15239–15248). [PMID:37151536]
4. Dewei Qiu, Ping Zhou, Jiawei Kang, Zhijun Chen, Zhiyong Xu, Hanwen Yang, Jun Tao, Fanrong Ai. (2022) ZnO nanoparticle modified chitosan/borosilicate bioglass composite scaffold for inhibiting bacterial infection and promoting bone regeneration. Biomedical Materials, 17 (6): (65023). [PMID:36394277]

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SKU	Size	Availability	Price	Qty
T104043-100ml	100ml	In stock	$15.90
T104043-500ml	500ml	In stock	$47.90