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Synonyms | TRIMETHYL BORATE | 121-43-7 | Trimethoxyborane | Methyl borate | Trimethoxyboron | trimethylborate | Boric acid trimethyl ester | Boric acid, trimethyl ester | Trimethoxyborine | Borester O | Boric acid (H3BO3), trimethyl ester | B(OCH3)3 | NSC 777 | (MeO)3B | B(OMe)3 | Trimethylester |
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Specifications & Purity | 98% |
Storage Temp | Room temperature,Argon charged |
Shipped In | Normal |
Product Description | Trimethyl borate reacts with a Grignard reagent or organolithium compounds to yield dimethyl boronates, which upon subsequent aqueous acid treatment afford corresponding boronic acids. The resultant boronic acids or esters are useful intermediates in various cross-coupling reactions such as Suzuki coupling and Chan-Lam coupling.It is also used in the preparation of sodium borohydride. |
IUPAC Name | trimethyl borate |
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INCHI | InChI=1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3 |
InChi Key | WRECIMRULFAWHA-UHFFFAOYSA-N |
Canonical SMILES | B(OC)(OC)OC |
Isomeric SMILES | B(OC)(OC)OC |
WGK Germany | 1 |
RTECS | ED5600000 |
PubChem CID | 8470 |
UN Number | 2416 |
Packing Group | II |
Molecular Weight | 103.91 |
Beilstein | 1697939 |
Reaxy-Rn | 1697939 |
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Lot Number | Certificate Type | Date | Item |
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G2422349 | Certificate of Analysis | Jul 06, 2024 | T104043 |
G2422350 | Certificate of Analysis | Jul 06, 2024 | T104043 |
G2422351 | Certificate of Analysis | Jul 06, 2024 | T104043 |
H2421306 | Certificate of Analysis | Apr 28, 2024 | T104043 |
K2310436 | Certificate of Analysis | Oct 26, 2023 | T104043 |
K2310435 | Certificate of Analysis | Oct 26, 2023 | T104043 |
C2429032 | Certificate of Analysis | Oct 26, 2023 | T104043 |
F2306896 | Certificate of Analysis | Jun 09, 2023 | T104043 |
F2306898 | Certificate of Analysis | Jun 09, 2023 | T104043 |
K22171080 | Certificate of Analysis | Nov 28, 2022 | T104043 |
G2229439 | Certificate of Analysis | Jul 16, 2022 | T104043 |
I2311041 | Certificate of Analysis | Jul 16, 2022 | T104043 |
G2229437 | Certificate of Analysis | Jul 16, 2022 | T104043 |
G2229436 | Certificate of Analysis | Jul 16, 2022 | T104043 |
B2211163 | Certificate of Analysis | Dec 09, 2021 | T104043 |
B2211181 | Certificate of Analysis | Dec 09, 2021 | T104043 |
B2211167 | Certificate of Analysis | Dec 09, 2021 | T104043 |
Solubility | Miscible with tetrahydrofuran, ether, isoporpylamine, hexane and methanol. |
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Sensitivity | moisture sensitive |
Refractive Index | 1.3562-1.3582 |
Flash Point(°F) | 17.6 °F |
Flash Point(°C) | -8℃ |
Boil Point(°C) | 67~68°C |
Melt Point(°C) | -29°C |
Pictogram(s) | GHS06, GHS08, GHS02 |
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Signal | Warning |
Hazard Statements | H319:Causes serious eye irritation H225:Highly Flammable liquid and vapor H360:May damage fertility or the unborn child H370:Causes damage to organs H301+H311+H331:Toxic if swallowed, in contact with skin or if inhaled |
Precautionary Statements | P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P403+P235:Store in a well-ventilated place. Keep cool. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P362+P364:Take off contaminated clothing and wash it before reuse. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P317:Get emergency medical help. |
WGK Germany | 1 |
RTECS | ED5600000 |
Reaxy-Rn | 1697939 |
Class | 3 |
Merck Index | 9712 |
RIDADR | UN 2416 3 / PGII |
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1. Longli Ma, Xuanyang Li, Jian Tan, Zhan Fang, Zhu Liu, Yuan Wang, Chuming Ye, Pengshu Yi, Mingxin Ye, Jianfeng Shen. (2023) Anion-Immobilized Gel Polymer Electrolyte with a High Ion Transference Number for High-Performance Lithium/Sodium Metal Batteries. ACS Applied Materials & Interfaces, 15 (49): (57201–57210). [PMID:38041638] |
2. Chaoze Liu, Zheng Zhou, Jiawei Ji, Yaxin Gu, Song Yan, Shaobo Yang, Rongjuan Zhang, Zhenya Liu, Yanming Xue, Chengchun Tang. (2023) Controllable preparation of boron nitride microspheres and their epoxy-based thermoconductive composites. CERAMICS INTERNATIONAL, 49 (27138). [PMID:] |
3. Zexia Li, Jingwen Yang, Hejun Gao, Jiaxiao Qiao, Wei Qiao, Peng Wang, Jun Zhang, Chengchun Tang, Yanming Xue. (2023) Boron Nitride Microspheres via Pyrolysis of Polymerized Precursors. ACS Omega, 8 (17): (15239–15248). [PMID:37151536] |
4. Dewei Qiu, Ping Zhou, Jiawei Kang, Zhijun Chen, Zhiyong Xu, Hanwen Yang, Jun Tao, Fanrong Ai. (2022) ZnO nanoparticle modified chitosan/borosilicate bioglass composite scaffold for inhibiting bacterial infection and promoting bone regeneration. Biomedical Materials, 17 (6): (65023). [PMID:36394277] |
1. Longli Ma, Xuanyang Li, Jian Tan, Zhan Fang, Zhu Liu, Yuan Wang, Chuming Ye, Pengshu Yi, Mingxin Ye, Jianfeng Shen. (2023) Anion-Immobilized Gel Polymer Electrolyte with a High Ion Transference Number for High-Performance Lithium/Sodium Metal Batteries. ACS Applied Materials & Interfaces, 15 (49): (57201–57210). [PMID:38041638] |
2. Chaoze Liu, Zheng Zhou, Jiawei Ji, Yaxin Gu, Song Yan, Shaobo Yang, Rongjuan Zhang, Zhenya Liu, Yanming Xue, Chengchun Tang. (2023) Controllable preparation of boron nitride microspheres and their epoxy-based thermoconductive composites. CERAMICS INTERNATIONAL, 49 (27138). [PMID:] |
3. Zexia Li, Jingwen Yang, Hejun Gao, Jiaxiao Qiao, Wei Qiao, Peng Wang, Jun Zhang, Chengchun Tang, Yanming Xue. (2023) Boron Nitride Microspheres via Pyrolysis of Polymerized Precursors. ACS Omega, 8 (17): (15239–15248). [PMID:37151536] |
4. Dewei Qiu, Ping Zhou, Jiawei Kang, Zhijun Chen, Zhiyong Xu, Hanwen Yang, Jun Tao, Fanrong Ai. (2022) ZnO nanoparticle modified chitosan/borosilicate bioglass composite scaffold for inhibiting bacterial infection and promoting bone regeneration. Biomedical Materials, 17 (6): (65023). [PMID:36394277] |