Trimethyl(methylcyclopentadienyl)platinum(IV) - 98%, high purity , CAS No.94442-22-5

Item Number

T118816

• Synonyms: Umicore HS161;Umicore DePt01;MeCpPtMe3, HS161
• Specifications & Purity: ≥98%
• Storage Temp: Store at -20°C,Argon charged
• Shipped In: Ice chest + Ice pads

Product Description

MeCpPtMe3 is a commonly used organometallic precursor for platinum.
MeCpPtMe3 was used for the deposition of ultrathin metallic layers of platinum by electron beam induced deposition, atomic sputtering.These deposits find application in microelectronics, catalysis, photonics and chemical sensing.

Application

MeCpPtMe3 is a homogeneous catalyst useful for hydrosilylation reactions.

Storage and Stability

Do not store above 4°C (39°F). Store in a tightly closed original container under dry inert gas protected from direct sunlight in a dry, cool and well-ventilated area.

Product class
M-C, Homogeneous Catalysts, Electronic Materials, PGM based Electronic Materials, Alkyl Ligands, Arene/Aryl Ligands

Reaction type
Hydrosilylation, Oxidation

Chemical properties

Chemical formula

C9H16Pt

Empirical formula

[Pt(Me)3(CpMe)]

Molecular weight

319.31

Metal

Pt

Theoretical metal content

61

Physical state

powder

Color

white

Applications & references

Platinum nanoparticles are formed by gas phase loading of the volatile platinum compounds on metal-organic frameworks and by subsequent reduction with 100 bar hydrogen. For instance, the Pt component shows high catalytic activity in solvent-free and base-free oxidation of alcohols in air at room temperature.

Reference: Chem. Eur. J. 2008, 14, 8204 (DOI: 10.1002/chem.200801043)

Trimethyl(methylcyclopentadienyl)platinum(IV) as an effective photoinitiator for hydrosilylation reactions.

Reference: Inorg. Chem. 2004, 43, 6869 (DOI: 10.1021/ic0496222)

Trimethyl(methylcyclopentadienyl)platinum(IV) is often used as ALD and CVD precursor.

Reference:  WO2010 033318 ; Electrochimica Acta 2012, 75, 101 (10.1016/j.electacta.2012.04.084)