F1910080Determine the necessary mass, volume, or concentration for preparing a solution.
Basic Description
| Synonyms | TRIMETHYL PHOSPHITE|121-45-9|Trimethylphosphite|Trimethoxyphosphine|Phosphorous acid, trimethyl ester|Methyl phosphite|Trimethylfosfit|Trimethoxyfosfin|PHOSPHOROUS ACID TRIMETHYL ESTER|NSC 6513|Trimethyl ester of phosphorous acid|P(OMe)3|Methyl phosphite |
|---|---|
| Specifications & Purity | CP, ≥95% |
| Storage Temp | Room temperature |
| Shipped In | Normal |
| Grade | CP |
Names and Identifiers
Certificates
Certificate of Analysis(COA)
Enter Lot Number to search for COA:
Chemical and Physical Properties
| Refractive Index | 1.4095 |
|---|---|
| Flash Point(°F) | 82.4 °F |
| Flash Point(°C) | 28℃ |
| Boil Point(°C) | 112°C |
| Melt Point(°C) | -78°C |
Safety and Hazards(GHS)
| Pictogram(s) | GHS08, GHS07, GHS02 |
|---|---|
| Signal | Warning |
| Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H373:Causes damage to organs through prolonged or repeated exposure H302:Harmful if swallowed H226:Flammable liquid and vapor H313:May be harmful in contact with skin |
| Precautionary Statements | P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P501:Dispose of contents/container to ... P312:Call a POISON CENTER or doctor/... if you feel unwell. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P201:Obtain special instructions before use. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P337+P313:IF eye irritation persists: Get medical advice/attention. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P330:Rinse mouth. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P301+P317:IF SWALLOWED: Get medical help. P319:Get medical help if you feel unwell. |
| WGK Germany | 1 |
| RTECS | TH1400000 |
| Class | 3 |
Related Documents
References
| 1. M A Mehlman,P H Craig,M A Gallo. (1984-01-01) Teratological evaluation of trimethyl phosphite in the rat.. Toxicology and applied pharmacology, 72 ((1)): (119-123). [PMID:6710478] |
| 2. Bangwei Ding,Wesley G Bentrude. (2003-03-13) Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage.. Journal of the American Chemical Society, 125 ((11)): (3248-3259). [PMID:12630880] |
| 3. Tian-lin Zhang,Zai-feng Li,Zhen Jia,Jun-hong Wang. (2005-03-15) [Studies on the reactions of unsaturated chloride polyether polyol with trimethyl phosphite by FTIR].. Guang pu xue yu guang pu fen xi = Guang pu, 24 ((11)): (1334-1337). [PMID:15762469] |
| 4. D Vaughan Griffiths,Mohamad J Al-Jeboori,Yuen-Ki Cheong,Philip Duncanson,Jayne E Harris,Michael C Salt,Helen V Taylor. (2008-01-26) Electron-rich heteroaroylphosphonates and their reaction with trimethyl phosphite.. Organic & biomolecular chemistry, 6 ((3)): (577-585). [PMID:18219430] |
| 5. Arjen VanDoorn,Mario Kallenbach,Alejandro A Borquez,Ian T Baldwin,Gustavo Bonaventure. (2010-08-11) Rapid modification of the insect elicitor N-linolenoyl-glutamate via a lipoxygenase-mediated mechanism on Nicotiana attenuata leaves.. BMC plant biology, 10 (164-164). [PMID:20696061] |
| 6. Shinichi Yamabe,Noriko Tsuchida,Shoko Yamazaki. (2010-10-15) Correlation between the rate order and the number of molecules in the reaction of trimethyl phosphite with water in acetonitrile solvent.. The journal of physical chemistry. A, 114 ((43)): (11699-11707). [PMID:20942499] |
| 7. N Ramanathan,Bishnu Prasad Kar,K Sundararajan,K S Viswanathan. (2012-11-21) Matrix isolation infrared and DFT study of the trimethyl phosphite-hydrogen chloride interaction: hydrogen bonding versus nucleophilic substitution.. The journal of physical chemistry. A, 116 ((49)): (12014-12023). [PMID:23163609] |
| 8. D H Barton,C O Bardin,D Doller. (1994-04-01) The functionalisation of saturated hydrocarbons--XXX. Model studies on the mechanism of some oxygenases.. Bioorganic & medicinal chemistry, 2 ((4)): (259-266). [PMID:7922137] |
| 9. J C Lin,Y F Chen,C Y Chen. (1999-08-24) Surface characterization and platelet adhesion studies of plasma polymerized phosphite and its copolymers with dimethylsulfate.. Biomaterials, 20 ((16)): (1439-1447). [PMID:10458557] |