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T106669-5ml

5ml

Available within 4-8 weeks(?)

$19.90

T106669-10ml

10ml

Available within 4-8 weeks(?)

$35.90

T106669-25ml

25ml

Available within 4-8 weeks(?)

$80.90

T106669-100ml

100ml

Available within 4-8 weeks(?)

$290.90

Basic Description

Synonyms	Tris(2-aminoethyl)amine\|4097-89-6\|Tren\|N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine\|TAEA\|1,2-Ethanediamine, N,N-bis(2-aminoethyl)-\|2,2',2''-Triaminotriethylamine\|Nitrilotris(ethylamine)\|N',N'-bis(2-aminoethyl)ethane-1,2-diamine\|tris-(2-aminoethyl)amine\|N,N-b
Specifications & Purity	96%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Product Description： Tris(2-aminoethyl)amine (TREN) is a water soluble tripodal ligand that is majorly used in co-ordination chemistry. It has three aminoethylgroups that attach with the surface atoms to provide a scaffold assembly. Tris(2-aminoethyl)amine is a tetradentate chelating ligand and forms stable complexes with transition metals. It is also used as a carbon dioxide absorbent. Further, it acts as a reagent for cleavage of the fluorenylmethyloxycarbonyl (Fmoc) group in peptide synthesis. It reacts with aryl isocyanates and isothiocyanates to give tris-urea and -thiourea derivatives. Product Application： Building block for cryptands; precursor to a proazaphosphatrane, a stong, nonionic base. TREN can be grafted with multi-walled carbon nanotube (MWCNT) for use in solid phase extraction of metal ions for wastewater treatment based applications. It can also be used as a chelating agent in the surface treatment of silica nanoparticles which can further be used for a wide range of industrial applications.

Names and Identifiers

IUPAC Name	N',N'-bis(2-aminoethyl)ethane-1,2-diamine
INCHI	InChI=1S/C6H18N4/c7-1-4-10(5-2-8)6-3-9/h1-9H2
InChi Key	MBYLVOKEDDQJDY-UHFFFAOYSA-N
Canonical SMILES	C(CN(CCN)CCN)N
Isomeric SMILES	C(CN(CCN)CCN)N
WGK Germany	3
RTECS	KH8587082
PubChem CID	77731
UN Number	2922
Molecular Weight	146.23
Beilstein	1739626
Reaxy-Rn	1739626

Certificates

Certificate of Analysis(COA)

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14 results found

Lot Number	Certificate Type	Date	Item
K2317204	Certificate of Analysis	Jun 05, 2023	T106669
K2317205	Certificate of Analysis	Jun 05, 2023	T106669
H2316493	Certificate of Analysis	May 29, 2023	T106669
H2316494	Certificate of Analysis	May 29, 2023	T106669
H2316495	Certificate of Analysis	May 29, 2023	T106669
H2316496	Certificate of Analysis	May 29, 2023	T106669
E2325775	Certificate of Analysis	May 15, 2023	T106669
E2325800	Certificate of Analysis	May 15, 2023	T106669
E2325805	Certificate of Analysis	May 15, 2023	T106669
E2325806	Certificate of Analysis	May 15, 2023	T106669
F2228640	Certificate of Analysis	Jun 09, 2022	T106669
F2228652	Certificate of Analysis	Jun 09, 2022	T106669
F2228655	Certificate of Analysis	Jun 09, 2022	T106669
F2228657	Certificate of Analysis	Jun 09, 2022	T106669

Chemical and Physical Properties

Solubility	Miscible with water.
Sensitivity	Air Sensitive & Hygroscopic
Refractive Index	1.497
Flash Point(°F)	113 °C
Flash Point(°C)	113°C
Boil Point(°C)	114°C/15mmHg

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS08, GHS05
Signal	Danger
Hazard Statements	H301:Toxic if swallowed H314:Causes severe skin burns and eye damage H318:Causes serious eye damage H310:Fatal in contact with skin H370:Causes damage to organs
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P330:Rinse mouth. P262:Do not get in eyes, on skin, or on clothing. P361+P364:Take off immediately all contaminated clothing and wash it before reuse. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P316:IF SWALLOWED: Get emergency medical help immediately. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P308+P316:IF exposed or concerned: Get emergency medical help immediately. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3
RTECS	KH8587082
Reaxy-Rn	1739626

References

1. Chinta Reddy Venkat Reddy,John G Verkade. (2007-03-21) Merrifield Resin-C6H4CH2N3P(MeNCH2CH2)3N: an efficient reusable catalyst for room-temperature 1,4-addition reactions and a more convenient synthesis of its precursor P(MeNCH2CH2)3N.. The Journal of organic chemistry, 72 ((8)): (3093-3096). [PMID:17367193]
2. Surendra Prasad,Radhey M Naik,Abhishek Srivastava. (2007-12-11) Application of ruthenium catalyzed oxidation of [tris(2-aminoethyl)amine] in trace determination of ruthenium in environmental water samples.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70 ((5)): (958-965). [PMID:18069053]
3. Huei-Chi Lin,Yi-Hsin Chou,Jyisy Yang. (2007-12-18) Development of an aminocarboxylic acid-modified infrared chemical sensor for selective determination of tyrosine in urine.. Analytica chimica acta, 606 ((2)): (230-238). [PMID:18082655]
4. Xinping Huang,Xijun Chang,Qun He,Yuemei Cui,Yunhui Zhai,Na Jiang. (2008-02-26) Tris(2-aminoethyl) amine functionalized silica gel for solid-phase extraction and preconcentration of Cr(III), Cd(II) and Pb(II) from waters.. Journal of hazardous materials, 157 ((1)): (154-160). [PMID:18295398]
5. Lukman Hakim,Akhmad Sabarudin,Koji Oshita,Mitsuko Oshima,Shoji Motomizu. (2008-09-02) Synthesis of chitosan-based resins modified with tris(2-aminoethyl)amine moiety and its application to collection/concentration and determination of trace mercury by inductively coupled plasma atomic emission spectrometry.. Talanta, 76 ((5)): (1256-1260). [PMID:18761187]
6. Suhua Wang,Haipeng Song,Wei Yi Ong,Ming Yong Han,Dejian Huang. (2009-09-26) Positively charged and pH self-buffering quantum dots for efficient cellular uptake by charge mediation and monitoring cell membrane permeability.. Nanotechnology, 20 ((42)): (425102-425102). [PMID:19779229]
7. Margandan Bhagiyalakshmi,Lee Ji Yun,Ramani Anuradha,Hyun Tae Jang. (2009-11-27) Utilization of rice husk ash as silica source for the synthesis of mesoporous silicas and their application to CO2 adsorption through TREN/TEPA grafting.. Journal of hazardous materials, 175 ((1-3)): (928-938). [PMID:19939554]
8. Pascal Dimitrov Raytchev,Olivier Perraud,Christophe Aronica,Alexandre Martinez,Jean-Pierre Dutasta. (2010-02-20) A new class of C3-symmetrical hemicryptophane hosts: triamide- and tren-hemicryptophanes.. The Journal of organic chemistry, 75 ((6)): (2099-2102). [PMID:20166689]
9. Paloma Arranz,Antonio Bianchi,Rafael Cuesta,Claudia Giorgi,M Luz Godino,M D Gutiérrez,Rafael López,Antonio Santiago. (2010-09-15) Binding and removal of sulfate, phosphate, arsenate, tetrachloromercurate, and chromate in aqueous solution by means of an activated carbon functionalized with a pyrimidine-based anion receptor (HL). Crystal structures of [H3L(HgCl4)]·H2O and [H3L(HgBr4)]·H2O showing anion-π interactions.. Inorganic chemistry, 49 ((20)): (9321-9332). [PMID:20836504]
10. Jung-Ho Shin,Hoi Jong Jung,Young Jun An,Yoo-Bok Cho,Sun-Shin Cha,Jung-Hye Roe. (2011-03-09) Graded expression of zinc-responsive genes through two regulatory zinc-binding sites in Zur.. Proceedings of the National Academy of Sciences of the United States of America, 108 ((12)): (5045-5050). [PMID:21383173]
11. Nicholas N Lyssenko,Gregory Brubaker,Bradley D Smith,Jonathan D Smith. (2011-08-13) A novel compound inhibits reconstituted high-density lipoprotein assembly and blocks nascent high-density lipoprotein biogenesis downstream of apolipoprotein AI binding to ATP-binding cassette transporter A1-expressing cells.. Arteriosclerosis, thrombosis, and vascular biology, 31 ((11)): (2700-2706). [PMID:21836073]
12. Nobuko Mibu,Kazumi Yokomizo,Wataru Uchida,Satoshi Takemura,Jianrong Zhou,Hatsumi Aki,Takeshi Miyata,Kunihiro Sumoto. (2012-03-03) Molecular symmetry and biological activities of new symmetrical tris(2-aminoethyl)amine derivatives.. Chemical & pharmaceutical bulletin, 60 ((3)): (408-414). [PMID:22382425]
13. Paul D Bonnitcha,Byung J Kim,Rosalie K Hocking,Jack K Clegg,Peter Turner,Suzanne M Neville,Trevor W Hambley. (2012-08-14) Cobalt complexes with tripodal ligands: implications for the design of drug chaperones.. Dalton transactions (Cambridge, England : 2003), 41 ((37)): (11293-11304). [PMID:22885674]
14. Inés Martí,Jenifer Rubio,Michael Bolte,M Isabel Burguete,Cristian Vicent,Roberto Quesada,Ignacio Alfonso,Santiago V Luis. (2012-12-21) Tuning chloride binding, encapsulation, and transport by peripheral substitution of pseudopeptidic tripodal small cages.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((52)): (16728-16741). [PMID:23255264]
15. Radu Custelcean. (2013-01-24) Urea-functionalized crystalline capsules for recognition and separation of tetrahedral oxoanions.. Chemical communications (Cambridge, England), 49 ((22)): (2173-2182). [PMID:23340607]
16. Mariana Borsoi-Ribeiro,Igor Tadeu Lazzarotto Bresolin,Mookambeswaran Vijayalakshmi,Sônia Maria Alves Bueno. (2013-09-03) Behavior of human immunoglobulin G adsorption onto immobilized Cu(II) affinity hollow-fiber membranes.. Journal of molecular recognition : JMR, 26 ((10)): (514-520). [PMID:23996494]
17. Wanyi Tai,Ran Mo,Yue Lu,Tianyue Jiang,Zhen Gu. (2014-05-31) Folding graft copolymer with pendant drug segments for co-delivery of anticancer drugs.. Biomaterials, 35 ((25)): (7194-7203). [PMID:24875756]
18. Jose Manuel Ageitos,Jo-Ann Chuah,Keiji Numata. (2015-04-02) Chemo-Enzymatic Synthesis of Linear and Branched Cationic Peptides: Evaluation as Gene Carriers.. Macromolecular bioscience, 15 ((7)): (990-1003). [PMID:25828913]
19. Md Najbul Hoque,Abhijit Gogoi,Gopal Das. (2015-05-15) Anion complexation with cyanobenzoyl substituted first and second generation tripodal amide receptors: crystal structure and solution studies.. Dalton transactions (Cambridge, England : 2003), 44 ((34)): (15220-15231). [PMID:25970818]
20. Sophia G Robinson,Philip T Burns,Amanda M Miceli,Kyle A Grice,Caitlin E Karver,Lihua Jin. (2016-07-05) Calorimetric studies of the interactions of metalloenzyme active site mimetics with zinc-binding inhibitors.. Dalton transactions (Cambridge, England : 2003), 45 ((29)): (11817-11829). [PMID:27373714]
21. Valeria M Nurchi,Guido Crisponi,Gavino Sanna,Inmaculada Pérez-Toro,Juan Niclos-Gutierrez,Maria Josefa Gonzalez-Perez,Alicia Domínguez Martín. (2019-02-27) Complex formation equilibria of polyamine ligands with copper(II) and zinc(II).. Journal of inorganic biochemistry, 194 (26-33). [PMID:30807891]
22. Frita Yuliati,Jennifer Hong,Keshia S Indriadi,Francesco Picchioni,Ranjita K Bose. (2020-08-06) Thermally Reversible Polymeric Networks from Vegetable Oils.. Polymers, 12 ((8)): [PMID:32751512]
23. Alessandro Scarso,Giovanni Zaupa,Florence Bodar Houillon,Leonard J Prins,Paolo Scrimin. (2007-01-16) Tripodal, cooperative, and allosteric transphosphorylation metallocatalysts.. The Journal of organic chemistry, 72 ((2)): (376-385). [PMID:17221952]
24. Mariana Borsoi Ribeiro,Mookambesvaran Vijayalakshmi,Daniele Todorova-Balvay,Sonia Maria Alves Bueno. (2007-12-11) Effect of IDA and TREN chelating agents and buffer systems on the purification of human IgG with immobilized nickel affinity membranes.. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 861 ((1)): (64-73). [PMID:18068557]
25. Radu Custelcean,Priscilla Remy,Peter V Bonnesen,De-en Jiang,Bruce A Moyer. (2008-02-01) Sulfate recognition by persistent crystalline capsules with rigidified hydrogen-bonding cavities.. Angewandte Chemie (International ed. in English), 47 ((10)): (1866-1870). [PMID:18236480]
26. Aileen Chin,Mark Edgar,Charles J Harding,Vickie McKee,Jane Nelson. (2009-08-06) A novel trisprotonated beta-dialdiminate cryptand.. Dalton transactions (Cambridge, England : 2003), (32) ((32)): (6315-6326). [PMID:19655065]
27. Agnieszka Iwan,Henryk Janeczek,Bozena Kaczmarczyk,Bozena Jarzabek,Michal Sobota,Patrice Rannou. (2009-12-29) Star-shaped azomethines based on tris(2-aminoethyl)amine. Characterization, thermal and optical study.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 75 ((2)): (891-900). [PMID:20036614]
28. Nathalie Busschaert,Philip A Gale,Cally J E Haynes,Mark E Light,Stephen J Moore,Christine C Tong,Jeffery T Davis,William A Harrell. (2010-08-10) Tripodal transmembrane transporters for bicarbonate.. Chemical communications (Cambridge, England), 46 ((34)): (6252-6254). [PMID:20694202]
29. Zhijuan Zhang,Fei Rong,Yibing Xie,Yong Wang,Haiyan Yang,Degang Fu. (2011-04-01) Controllable assembly of dimers and trimers of gold Nanoparticle bridged by Tris(2-aminoethyl)amine.. Journal of nanoscience and nanotechnology, 11 ((3)): (2163-2167). [PMID:21449364]
30. Ajay Venugopal,Waldemar Fegler,Thomas P Spaniol,Laurent Maron,Jun Okuda. (2011-10-12) Dihydrogen addition in a dinuclear rare-earth metal hydride complex supported by a metalated TREN ligand.. Journal of the American Chemical Society, 133 ((44)): (17574-17577). [PMID:21985245]
31. Bo Yu,Shu-Hao Hsu,Chenguang Zhou,Xinmei Wang,Megan C Terp,Yun Wu,Lesheng Teng,Yicheng Mao,Feng Wang,Weiming Xue,Samson T Jacob,Kalpana Ghoshal,Robert J Lee,Ly J Lee. (2012-06-02) Lipid nanoparticles for hepatic delivery of small interfering RNA.. Biomaterials, 33 ((25)): (5924-5934). [PMID:22652024]
32. Li-Yun Kong,Wei-Da Shan,Sheng-Li Han,Tao Zhang,Lang-Chong He,Kuan Huang,Sheng Dai. (2017-12-02) Interfacial Engineering of Supported Liquid Membranes by Vapor Cross-Linking for Enhanced Separation of Carbon Dioxide.. ChemSusChem, 11 ((1)): (185-192). [PMID:29193841]

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Tris(2-aminoethyl)amine - 96%, high purity , CAS No.4097-89-6

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

more

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

References

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SKU	Size	Availability	Price
T106669-5ml	5ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$19.90
T106669-10ml	10ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$35.90
T106669-25ml	25ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$80.90
T106669-100ml	100ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$290.90