Tris(dibenzylideneacetone)dipalladium(0) - 97%, high purity , CAS No.51364-51-3

Item Number

T118850

• Synonyms: 51364-51-3|Tris(dibenzylideneacetone)dipalladium(0)|tris(dibenzylideneacetone)dipalladium|pd2(dba)3|52409-22-0|Pd2dba3|60748-47-2|TRIS DBA|Tris(Dibenzylideneacetone)dipalladium (0)|MFCD00013310|tris(dibenzylideneacetone) dipalladium|Bis(dibenzylideneaceto
• Specifications & Purity: 97%
• Storage Temp: Store at 2-8°C,Protected from light,Argon charged
• Shipped In: Wet ice

Product Description

Catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes. Catalyst for the carbonylation of β,β-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids. Catalyst for cross-coupling reactions.
A cycloaddition catalyst.

Product class
M-C, Homogeneous Catalysts, Diene/Dienyl Ligands

Reaction type
Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Mizoroki Heck Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation, Reduction

Chemical properties

Chemical formula

C51H42O3Pd2

Empirical formula

[Pd2(dba)3] x dba

Molecular weight

915.73

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

dark purple

Applications & references

Palladium catalyzed conversion of aryl chlorides and triflates to nitroaromatics.

Reference: J. Am. Chem. Soc. 2009, 131, 12898 (DOI: 10.1021/ja905768k)

Site selective sp³ palladium catalyzed direct arylation for a rapid derivatization of heterocyclic compounds.

Reference: J. Am. Chem. Soc. 2008, 130, 3266. (DOI: 10.1021/ja710451s)

One-pot ketoindoline synthesis by Palladium catalyzed γ-arylation of β,γ-unsaturated ketones.

Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529)

Asymmetric synthesis of indolines by Palladium catalyzed arylation of β,γ-unsaturated ketones.

Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529)

Suzuki cross coupling of aryl chorides with arylboronic acids.

Reference: Angew. Chem. Int. Ed. 1998, 37, 3387. (DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO;2-P)

Efficient method for Suzuki-Miyaura reaction of lithium triisopropyl 2-pyridylborates and aryl chlorides.

Reference: Angew. Chem. Int. Ed. 2008, 48, 4695. (DOI: 10.1002/anie.200801465)

Palladium catalyzed aminocarbonylation of aryl halides.

Reference: J. Am. Chem. Soc. 2013, 135, 16841. (DOI: 10.1021/ja4098093)