Catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes. Catalyst for the carbonylation of β,β-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids. Catalyst for cross-coupling reactions.
A cycloaddition catalyst.
Product class
M-C, Homogeneous Catalysts, Diene/Dienyl Ligands Reaction type
Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Mizoroki Heck Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation, Reduction Chemical properties
Theoretical metal content
Applications & references Palladium catalyzed conversion of aryl chlorides and triflates to nitroaromatics. 
Reference: J. Am. Chem. Soc. 2009, 131, 12898 (DOI: 10.1021/ja905768k) Site selective sp³ palladium catalyzed direct arylation for a rapid derivatization of heterocyclic compounds. 
Reference: J. Am. Chem. Soc. 2008, 130, 3266. (DOI: 10.1021/ja710451s) One-pot ketoindoline synthesis by Palladium catalyzed γ-arylation of β,γ-unsaturated ketones. 
Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529) Asymmetric synthesis of indolines by Palladium catalyzed arylation of β,γ-unsaturated ketones. 
Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529) Suzuki cross coupling of aryl chorides with arylboronic acids.
Reference: Angew. Chem. Int. Ed. 1998, 37, 3387. (DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO;2-P) Efficient method for Suzuki-Miyaura reaction of lithium triisopropyl 2-pyridylborates and aryl chlorides.
Reference: Angew. Chem. Int. Ed. 2008, 48, 4695. (DOI: 10.1002/anie.200801465) Palladium catalyzed aminocarbonylation of aryl halides.
Reference: J. Am. Chem. Soc. 2013, 135, 16841. (DOI: 10.1021/ja4098093) | 
