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Tris(pentafluorophenyl)borane - 97%, high purity , CAS No.1109-15-5

  • ≥97%
Item Number
T109495
Grouped product items
SKUSizeAvailabilityPrice Qty
T109495-250mg
250mg
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$12.90
T109495-1g
1g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$34.90
T109495-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$119.90
T109495-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$399.90
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View related series
boranes Element classified compounds Olefin polymerization cocatalyst organic catalyst Pentafluorobenzenes

Basic Description

Synonymstris(pentafluorophenyl)-borane|Tris(perfluorophenyl)borane|Perfluorotriphenylboron|Tris(2,3,4,5,6-pentafluorophenyl)borane
Specifications & Purity97%
Storage TempStore at -20°C,Argon charged
Shipped InIce chest + Ice pads
Product Description

B(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.

Application：

A versatile reagent widely used in the preparation of d0 arene and other organometallic complexes useful as polymerization catalysts. 

Used with tri-tert-butylphosphine (570958) to study the heterolytic cleavage of dihydrogen at room temperature and one atmosphere pressure.

Names and Identifiers

IUPAC Name tris(2,3,4,5,6-pentafluorophenyl)borane
INCHI InChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
InChi Key OBAJXDYVZBHCGT-UHFFFAOYSA-N
Canonical SMILES B(C1=C(C(=C(C(=C1F)F)F)F)F)(C2=C(C(=C(C(=C2F)F)F)F)F)C3=C(C(=C(C(=C3F)F)F)F)F
Isomeric SMILES B(C1=C(C(=C(C(=C1F)F)F)F)F)(C2=C(C(=C(C(=C2F)F)F)F)F)C3=C(C(=C(C(=C3F)F)F)F)F
WGK Germany 3
PubChem CID 582056
Molecular Weight 511.98
Beilstein 2931347
Reaxy-Rn 2931347

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

26 results found

Lot NumberCertificate TypeDateItem
H2421052Certificate of AnalysisAug 06, 2024 T109495
H2421051Certificate of AnalysisAug 06, 2024 T109495
H2421050Certificate of AnalysisAug 06, 2024 T109495
H2421049Certificate of AnalysisAug 06, 2024 T109495
H2421048Certificate of AnalysisAug 06, 2024 T109495
E2428376Certificate of AnalysisMay 11, 2024 T109495
E2428375Certificate of AnalysisMay 11, 2024 T109495
E2428374Certificate of AnalysisMay 11, 2024 T109495
E2428346Certificate of AnalysisMay 11, 2024 T109495
C2419360Certificate of AnalysisMar 08, 2024 T109495
A2422336Certificate of AnalysisJan 08, 2024 T109495
A2422337Certificate of AnalysisJan 08, 2024 T109495
A2422335Certificate of AnalysisJan 08, 2024 T109495
J2327572Certificate of AnalysisOct 09, 2023 T109495
J2327573Certificate of AnalysisOct 09, 2023 T109495
J2327614Certificate of AnalysisOct 09, 2023 T109495
E2325789Certificate of AnalysisApr 25, 2023 T109495
E2325788Certificate of AnalysisApr 25, 2023 T109495
E2325764Certificate of AnalysisApr 25, 2023 T109495
E2325763Certificate of AnalysisApr 25, 2023 T109495
D23061294Certificate of AnalysisAug 16, 2022 T109495
D23061293Certificate of AnalysisAug 16, 2022 T109495
J2222533Certificate of AnalysisAug 16, 2022 T109495
J2222545Certificate of AnalysisAug 16, 2022 T109495
J2222546Certificate of AnalysisAug 16, 2022 T109495
J2222560Certificate of AnalysisAug 16, 2022 T109495

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Chemical and Physical Properties

SolubilitySoluble in hexane, chloroform, dichloromethane, toluene, and polar solvents
Sensitivityheat sensitive，Moisture sensitive
Melt Point(°C)126-130°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Danger
Hazard Statements

H301:Toxic if swallowed

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

WGK Germany 3
Reaxy-Rn 2931347
Merck Index 9755

Related Documents

 SDS

 Specification Sheet

FAQs and Articles

FAQ
Hydrogenation Catalysts
Categories: Technical articles
Tags:
Catalysts Organic catalyst Transition metal catalyst Hydrogenation Catalysts Hydrogenation Reduce
Diethylsilane
Categories: Technical articles
Tags:
Chemical synthesis Reducing agent Diethylsilane Organosilicon Reagents Iridium-Catalyzed

References

1. Gregory C Welch,Douglas W Stephan.  (2007-01-31)  Facile heterolytic cleavage of dihydrogen by phosphines and boranes..  Journal of the American Chemical Society,  129  ((7)): (1880-1881).  [PMID:17260994]
2. Jiawei Chen,Eugene X-Y Chen.  (2015-05-29)  Reactivity of Amine/E(C6F5)3 (E = B, Al) Lewis Pairs toward Linear and Cyclic Acrylic Monomers: Hydrogenation vs. Polymerization..  Molecules (Basel, Switzerland),  20  ((6)): (9575-9590).  [PMID:26016548]
3. Taegon Kang,Xavier Banquy,Jinhwa Heo,Chanoong Lim,Nathaniel A Lynd,Pontus Lundberg,Dongyeop X Oh,Han-Koo Lee,Yong-Ki Hong,Dong Soo Hwang,John Herbert Waite,Jacob N Israelachvili,Craig J Hawker.  (2015-12-24)  Mussel-Inspired Anchoring of Polymer Loops That Provide Superior Surface Lubrication and Antifouling Properties..  ACS nano,  10  ((1)): (930-937).  [PMID:26695175]
4. Xufeng Ling,Jianyu Yuan,Xuliang Zhang,Yuli Qian,Shaik M Zakeeruddin,Bryon W Larson,Qian Zhao,Junwei Shi,Jiacheng Yang,Kang Ji,Yannan Zhang,Yongjie Wang,Chunyang Zhang,Steffen Duhm,Joseph M Luther,Michael Grätzel,Wanli Ma.  (2020-05-26)  Guanidinium-Assisted Surface Matrix Engineering for Highly Efficient Perovskite Quantum Dot Photovoltaics..  Advanced materials (Deerfield Beach, Fla.),  32  ((26)): (e2001906-e2001906).  [PMID:32449221]
5. Berthold Wegner,Dominique Lungwitz,Ahmed E Mansour,Claudia E Tait,Naoki Tanaka,Tianshu Zhai,Steffen Duhm,Michael Forster,Jan Behrends,Yoshiaki Shoji,Andreas Opitz,Ullrich Scherf,Emil J W List-Kratochvil,Takanori Fukushima,Norbert Koch.  (2020-10-01)  An Organic Borate Salt with Superior p-Doping Capability for Organic Semiconductors..  Advanced science (Weinheim, Baden-Wurttemberg, Germany),  7  ((17)): (2001322-2001322).  [PMID:32995128]
6. Jeong-Chan Lee,Minho Lee,Ho-Jun Lee,Kwangguk Ahn,Jaewook Nam,Steve Park.  (2020-10-22)  Numerical Simulations and In Situ Optical Microscopy Connecting Flow Pattern, Crystallization, and Thin-Film Properties for Organic Transistors with Superior Device-to-Device Uniformity..  Advanced materials (Deerfield Beach, Fla.),  32  ((48)): (e2004864-e2004864).  [PMID:33084113]
7. Hans Fuhrmann,Simon Brenner,Perdita Arndt,Rhett Kempe.  (1996-11-06)  Octahedral Group 4 Metal Complexes That Contain Amine, Amido, and Aminopyridinato Ligands: Synthesis, Structure, and Application in alpha-Olefin Oligo- and Polymerization..  Inorganic chemistry,  35  ((23)): (6742-6745).  [PMID:11666837]
8. Dan Voicu,Douglas W Stephan,Eugenia Kumacheva.  (2015-11-27)  Microfluidic Separation of Ethylene and Ethane Using Frustrated Lewis Pairs..  ChemSusChem,  8  ((24)): (4202-4208).  [PMID:26609918]

Solution Calculators

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