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Tris(triphenylphosphine)rhodium(I) chloride - 99.9% trace metals basis, high purity , CAS No.14694-95-2

1 Citations
  • ≥99.9% metals basis
Item Number
T475094
Grouped product items
SKUSizeAvailabilityPrice Qty
T475094-250mg
250mg
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$181.90
T475094-1g
1g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$391.90
T475094-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$1,059.90
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Basic Description

SynonymsTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | T0931 | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(trip
Specifications & Purity≥99.9% metals basis
Storage TempStore at 2-8°C,Protected from light,Argon charged
Shipped InWet ice
Product Description

Description

Hydrosilylation CatalystsCatalyst used for many organic reactions including:Chemoselective allylic alkylationsStoichiometric activation of Si-H bonds and hydrosilylationsInter- and intramolecular hydroacylation of alkenes along with a cocatalystPolymerization of diorganostannanesUseful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids. Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.

Names and Identifiers

IUPAC Name rhodium;triphenylphosphane;chloride
INCHI InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1
InChi Key QBERHIJABFXGRZ-UHFFFAOYSA-M
Canonical SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
Isomeric SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
WGK Germany 3
PubChem CID 84599
UN Number 1759
Molecular Weight 925.22
Beilstein 4581440
Reaxy-Rn 14664394

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

6 results found

Lot NumberCertificate TypeDateItem
G2402507Certificate of AnalysisFeb 01, 2024 T475094
G2402508Certificate of AnalysisFeb 01, 2024 T475094
G2402509Certificate of AnalysisFeb 01, 2024 T475094
B2423973Certificate of AnalysisJan 15, 2024 T475094
B2423990Certificate of AnalysisJan 15, 2024 T475094
B2423991Certificate of AnalysisJan 15, 2024 T475094

Chemical and Physical Properties

SensitivityLight & Air & Heat sensitive
Melt Point(°C)245-250°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07
Signal Warning
Hazard Statements

H411:Toxic to aquatic life with long lasting effects

H413:May cause long lasting harmful effects to aquatic life

H302:Harmful if swallowed

H317:May cause an allergic skin reaction

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P270:Do not eat, drink or smoke when using this product.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P330:Rinse mouth.

P301+P317:IF SWALLOWED: Get medical help.

WGK Germany 3
Reaxy-Rn 14664394
Merck Index 9758

Related Documents

 SDS

 Specification Sheet

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FAQs and Articles

FAQ
Hydrogenation Catalysts
Categories: Technical articles
Tags:
Catalysts Organic catalyst Transition metal catalyst Hydrogenation Catalysts Hydrogenation Reduce
Hydrosilylation and Hydrosilylation Catalyst
Categories: Technical articles
Tags:
Organic block Catalyzer Silicon hydride

Citations of This Product

How to Cite Aladdin Scientific Products?
1. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang.  (2020)  Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process.  JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,  40  (5226).  [PMID:] [10.1016/j.jeurceramsoc.2020.06.039]

References

1. S I Schlager.  (1981-01-01)  Effect of catalytic hydrogenation of cellular lipid and fatty acid on the susceptibility of tumor cells to humoral immune killing..  Methods in enzymology,  73  ((Pt B)): (191-199).  [PMID:7300678]
2. Johannes Kiefer,Katharina Obert,Simone Himmler,Peter S Schulz,Peter Wasserscheid,Alfred Leipertz.  (2008-09-16)  Infrared spectroscopy of a Wilkinson catalyst in a room-temperature ionic liquid..  Chemphyschem : a European journal of chemical physics and physical chemistry,  9  ((15)): (2207-2213).  [PMID:18792033]
3. V P Shevchenko,I Iu Nagaev,I S Levina,L E Kulikova,N F Miasoedov,A V Kamernitzkiĭ.  (2010-06-10)  [The synthesis of O-substituted 3-oximes of 6alpha-methyl-16alpha,17alpha-cyclohexanopregn-4-ene-3,20-dione tritium-labeled in 1 and 2 positions]..  Bioorganicheskaia khimiia,  36  ((2)): (283-288).  [PMID:20531488]
4. Sonsoles Rodriguez Aristegui,Marine Desage El-Murr,Bernard T Golding,Roger J Griffin,Ian R Hardcastle.  (2006-12-15)  Judicious application of allyl protecting groups for the synthesis of 2-morpholin-4-yl-4-oxo-4H-chromen-8-yl triflate, a key precursor of DNA-dependent protein kinase inhibitors..  Organic letters,  8  ((26)): (5927-5929).  [PMID:17165896]
5. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang.  (2020)  Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process.  JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,  40  (5226).  [PMID:] [10.1016/j.jeurceramsoc.2020.06.039]

Solution Calculators

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