Tris(triphenylphosphine)rhodium(I) chloride - 99.9% trace metals basis, high purity , CAS No.14694-95-2

Item Number

T475094

Grouped product items
SKU	Size	Availability	Price
T475094-250mg	250mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$181.90
T475094-1g	1g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$391.90
T475094-5g	5g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$1,059.90

Basic Description

Synonyms	14694-95-2\|Chlorotris(triphenylphosphine)rhodium(I)\|Tris(triphenylphosphine)rhodium(I) chloride\|Wilkinson's catalyst\|Tris(triphenylphosphine)chlororhodium\|Chlorotris(triphenylphosphine)rhodium\|16592-65-7\|rhodium;triphenylphosphane;chloride\|Tris(triphenylp
Specifications & Purity	99.9% trace metals basis
Storage Temp	Store at 2-8°C,Protected from light,Argon charged
Shipped In	Wet ice
Product Description	Description Hydrosilylation CatalystsCatalyst used for many organic reactions including:Chemoselective allylic alkylationsStoichiometric activation of Si-H bonds and hydrosilylationsInter- and intramolecular hydroacylation of alkenes along with a cocatalystPolymerization of diorganostannanesUseful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids. Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.

Names and Identifiers

IUPAC Name	rhodium;triphenylphosphane;chloride
INCHI	InChI=1S/3C18H15P.ClH.Rh/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h31-15H;1H;/p-1
InChi Key	QBERHIJABFXGRZ-UHFFFAOYSA-M
Canonical SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
WGK Germany	3
PubChem CID	84599
UN Number	1759
Molecular Weight	925.22
Beilstein	4581440
Reaxy-Rn	14664394

Certificates

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6 results found

Lot Number	Certificate Type	Date	Item
G2402507	Certificate of Analysis	Feb 01, 2024	T475094
G2402508	Certificate of Analysis	Feb 01, 2024	T475094
G2402509	Certificate of Analysis	Feb 01, 2024	T475094
B2423973	Certificate of Analysis	Jan 15, 2024	T475094
B2423990	Certificate of Analysis	Jan 15, 2024	T475094
B2423991	Certificate of Analysis	Jan 15, 2024	T475094

Sensitivity

Light & Air & Heat sensitive

Melt Point(°C)

245-250°C

Safety and Hazards(GHS)

Pictogram(s)	GHS09, GHS07
Signal	Warning
Hazard Statements	H411:Toxic to aquatic life with long lasting effects H413:May cause long lasting harmful effects to aquatic life H302:Harmful if swallowed H317:May cause an allergic skin reaction
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P270:Do not eat, drink or smoke when using this product. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage. P330:Rinse mouth. P301+P317:IF SWALLOWED: Get medical help.
WGK Germany	3
Reaxy-Rn	14664394
Merck Index	9758

References

1. S I Schlager. (1981-01-01) Effect of catalytic hydrogenation of cellular lipid and fatty acid on the susceptibility of tumor cells to humoral immune killing.. Methods in enzymology, 73 ((Pt B)): (191-199). [PMID:7300678]
2. Johannes Kiefer,Katharina Obert,Simone Himmler,Peter S Schulz,Peter Wasserscheid,Alfred Leipertz. (2008-09-16) Infrared spectroscopy of a Wilkinson catalyst in a room-temperature ionic liquid.. Chemphyschem : a European journal of chemical physics and physical chemistry, 9 ((15)): (2207-2213). [PMID:18792033]
3. V P Shevchenko,I Iu Nagaev,I S Levina,L E Kulikova,N F Miasoedov,A V Kamernitzkiĭ. (2010-06-10) [The synthesis of O-substituted 3-oximes of 6alpha-methyl-16alpha,17alpha-cyclohexanopregn-4-ene-3,20-dione tritium-labeled in 1 and 2 positions].. Bioorganicheskaia khimiia, 36 ((2)): (283-288). [PMID:20531488]
4. Sonsoles Rodriguez Aristegui,Marine Desage El-Murr,Bernard T Golding,Roger J Griffin,Ian R Hardcastle. (2006-12-15) Judicious application of allyl protecting groups for the synthesis of 2-morpholin-4-yl-4-oxo-4H-chromen-8-yl triflate, a key precursor of DNA-dependent protein kinase inhibitors.. Organic letters, 8 ((26)): (5927-5929). [PMID:17165896]

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Basic Description