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Tungsten hexacarbonyl - 97%, high purity , CAS No.14040-11-0

  • ≥97%
Item Number
T113664
Grouped product items
SKUSizeAvailabilityPrice Qty
T113664-1g
1g
In stock
$39.90
T113664-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$365.90
T113664-10g
10g
In stock
$169.90
View related series
lnorganic Catalysts

Basic Description

SynonymsW(CO)6;Hexacarbonyltungsten; Tungsten carbonyl;Tungsten(0) hexacarbonyl
Specifications & Purity≥97%
Shipped InNormal
Product Description

A precursor to a Fischer carbene complex which reduces Pd(II) to a nanoparticulate Pd(0) that is catalytically active in Hiyama cross-coupling.


Product class
Homogeneous Catalysts, Electronic Materials, Metal based Electronic Materials, M-(CO)

Reaction type
Cross Coupling Reactions with Arenes, Hiyama Coupling Reaction

Chemical properties

Chemical formula

C6O6W

Empirical formula

W(CO)6

Molecular weight

351.90

Metal

W

Theoretical metal content

52

Physical state

powder

Color

white

Names and Identifiers

WGK Germany 3
UN Number 2811
Molecular Weight 351.9

Certificates

Certificate of Analysis(COA)

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14 results found

Lot NumberCertificate TypeDateItem
E2420355Certificate of AnalysisMar 28, 2024 T113664
E2420394Certificate of AnalysisMar 28, 2024 T113664
E2420587Certificate of AnalysisMar 28, 2024 T113664
E2420597Certificate of AnalysisMar 28, 2024 T113664
E23081133Certificate of AnalysisJan 30, 2023 T113664
E23081311Certificate of AnalysisJan 30, 2023 T113664
E23081316Certificate of AnalysisJan 30, 2023 T113664
E23081323Certificate of AnalysisJan 30, 2023 T113664
L2326060Certificate of AnalysisJan 30, 2023 T113664
K2228699Certificate of AnalysisNov 21, 2022 T113664
K2228703Certificate of AnalysisNov 21, 2022 T113664
K2228711Certificate of AnalysisNov 21, 2022 T113664
K2214772Certificate of AnalysisNov 07, 2022 T113664
K2214801Certificate of AnalysisNov 07, 2022 T113664

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Chemical and Physical Properties

SolubilitySlightly soluble in tetrahydrofuran. Insoluble in water.
Boil Point(°C)175°C
Melt Point(°C)150°C

Safety and Hazards(GHS)

Pictogram(s) GHS06
Signal Danger
Hazard Statements

H301:Toxic if swallowed

H311:Toxic in contact with skin

H331:Toxic if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310:IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P311:Call a POISON CENTER or doctor/...

WGK Germany 3

Related Documents

References

1. J Feldmann.  (2001-09-01)  Determination of Ni(CO)4, Fe(CO)5, Mo(CO)6, and W(CO)6 in sewage gas by using cryotrapping gas chromatography inductively coupled plasma mass spectrometry..  Journal of environmental monitoring : JEM,  ((1)): (33-37).  [PMID:11529076]
2. Keisha-Gay Hylton,A Denise Main,Lisa McElwee-White.  (2003-02-15)  Catalytic carbonylation of functionalized diamines: application to the core structure of DMP 323 and DMP 450..  The Journal of organic chemistry,  68  ((4)): (1615-1617).  [PMID:12585919]
3. Lei Li,John T Millay,John P Turner,Fred L King.  (2003-12-31)  Millisecond pulsed radio frequency glow discharge time of flight mass spectrometry: temporal and spatial variations in molecular energetics..  Journal of the American Society for Mass Spectrometry,  15  ((1)): (87-102).  [PMID:14698559]
4. F Porrati,R Sachser,M Huth.  (2009-05-08)  The transient electrical conductivity of W-based electron-beam-induced deposits during growth, irradiation and exposure to air..  Nanotechnology,  20  ((19)): (195301-195301).  [PMID:19420637]
5. Seth M Dumbris,Delmy J Díaz,Lisa McElwee-White.  (2009-10-30)  Preparation of hydantoins by catalytic oxidative carbonylation of alpha-amino amides..  The Journal of organic chemistry,  74  ((22)): (8862-8865).  [PMID:19863059]
6. S Martin,L Chen,R Brédy,J Bernard,G Montagne,X Zhu.  (2011-01-26)  Excitation and dissociation of tungsten hexacarbonyl W(CO)6: statistical and nonstatistical dissociation processes..  The Journal of chemical physics,  134  ((3)): (034304-034304).  [PMID:21261350]
7. Camille Cau,Sergey I Nikitenko.  (2011-11-08)  Mechanism of W(CO)6 sonolysis in diphenylmethane..  Ultrasonics sonochemistry,  19  ((3)): (498-502).  [PMID:22054911]
8. Sarah M Eichfeld,Lorraine Hossain,Yu-Chuan Lin,Aleksander F Piasecki,Benjamin Kupp,A Glen Birdwell,Robert A Burke,Ning Lu,Xin Peng,Jie Li,Angelica Azcatl,Stephen McDonnell,Robert M Wallace,Moon J Kim,Theresa S Mayer,Joan M Redwing,Joshua A Robinson.  (2015-01-28)  Highly scalable, atomically thin WSe2 grown via metal-organic chemical vapor deposition..  ACS nano,  ((2)): (2080-2087).  [PMID:25625184]
9. Zaizhu Lou,Quan Gu,Lin Xu,Yusen Liao,Can Xue.  (2015-04-16)  Surfactant-free synthesis of plasmonic tungsten oxide nanowires with visible-light-enhanced hydrogen generation from ammonia borane..  Chemistry, an Asian journal,  10  ((6)): (1291-1294).  [PMID:25873477]
10. Dipankar Srimani,Sudeshna Sawoo,Amitabha Sarkar.  (2007-08-07)  Convenient synthesis of palladium nanoparticles and catalysis of Hiyama coupling reaction in water..  Organic letters,  ((18)): (3639-3642).  [PMID:17676861]

Solution Calculators