Tungstophosphoric acid hydrate - Premium-Grade Reagents ,for Analysis, , high purity , CAS No.12501-23-4

Item Number
T485815
Grouped product items
SKUSizeAvailabilityPrice Qty
T485815-100g
100g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$452.90
T485815-250g
250g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$873.90

Basic Description

Synonyms12501-23-4 | phosphoric acid;trioxotungsten;hydrate | 12-Tungstophosphoric acid hydrate | Tungstophosphoric acid | Hydrogen phosphotungstate hydrate (H3PW12O40.xH2O) | Phosphotungstic acid, AR | DTXSID30583755 | AVFBYUADVDVJQL-UHFFFAOYSA-N | MFCD00149915 | AKOS005111017 | SB
Specifications & PurityPremium-Grade Reagents ,for Analysis,
Storage TempRoom temperature
Shipped InNormal
GradePremium pure, Suitable for Analysis

Names and Identifiers

IUPAC Name phosphoric acid;trioxotungsten;hydrate
INCHI InChI=1S/H3O4P.H2O.36O.12W/c1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;
InChi Key AVFBYUADVDVJQL-UHFFFAOYSA-N
Canonical SMILES O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O
Isomeric SMILES O.OP(=O)(O)O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O
WGK Germany 3
Alternate CAS 12067-99-1
PubChem CID 16212977
UN Number 3260
Molecular Weight 2880.05

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Chemical and Physical Properties

Solubility water: soluble at20°C
Melt Point(°C)~95°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS05,   GHS07
Signal Danger
Hazard Statements

H411:Toxic to aquatic life with long lasting effects

H314:Causes severe skin burns and eye damage

H302:Harmful if swallowed

H318:Causes serious eye damage

Precautionary Statements

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P391:Collect spillage.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P317:Get emergency medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3

Related Documents

Citations of This Product

1. Yuanning Yue, Ying Liao, Jiarong Lu, Yue Pan, Meiyu Zhang, Guiyue Chen, Xin Zhou, Xinyu Kuang, Hui Zhao, Xiaobo Chen, Xiang Feng, Hao Yan, Yibin Liu, Chaohe Yang.  (2024)  Metal-doped M-NH4-PW catalyst with enhanced electron transfer for formaldehyde-propylene condensation to 4-methyl-1,3-dioxane.  Molecular Catalysis,  553  (113813).  [PMID:]
2. Xue-qi Zhang, Rui Ding, Jing Lv, Yu-chen Zhang, An-lan Ji, Jie Fu, Xiao Lv, Sheng-ying Yang, Lan Yao, Xuan Liang, Jie Liu, Hai-bin Yu.  (2023)  The novel damage-reporting and self-healing coatings prepared by electrospinning technology based on AIE agents and photothermal shape memory polymer.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:]
3. Yaqi Xue, Haihong Xia, Jing Li, Jiantao Su, Fei Ge, Xiaohui Yang, Jianchun Jiang, Minghao Zhou.  (2023)  Heteropolyacids promoted MOF-derived high-performance Co(H4)@C-HPW0.25 catalysts for catalytic transfer hydrogenation of vanillin in mild condition.  CHEMICAL ENGINEERING JOURNAL,  478  (147456).  [PMID:16737835]
4. Xiaolan Yang, Jitao Li, Qiulan Li, Dezhi Yang, Yaling Yang.  (2024)  Colorimetric detection for raloxifene based on Cu-PTs nanozyme with peroxidase-like activity.  JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS,  239  (115922).  [PMID:38134706]
5. Li-Zhi Zhang, Hong-Bin Ju, Tao Geng, De-Bao Li, Ya-Jie Jiang, Ya-Kui Wang.  (2023)  Study on the epoxidation of chain olefins using biquaternary ammonium phosphotungstic acid phase transfer catalysts under no-solvent condition.  CHEMISTRY-A EUROPEAN JOURNAL,    (e202303559).  [PMID:38088217]
6. Zhonghai Liu, Junwei Liao, Yuying Gong, Jinliang Song, Tiejun Wang.  (2024)  Efficient production of jet-fuel precursors via one-pot dehydration-oligomerization of higher alcohols from upgrading of bioethanol.  ENERGY CONVERSION AND MANAGEMENT,  299  (117833).  [PMID:11134351]
7. Yan Gao, Shumin Zhao, Miao Yan, Yongxia Li, Jianshe Zhao.  (2024)  High efficiency extraction oxidation desulfurization of model liquid fuel catalyzed by MIL-101(Fe) supported peroxo-polyoxometalates.  MICROPOROUS AND MESOPOROUS MATERIALS,  364  (112857).  [PMID:21278800]
8. Pu Li, Qiang Liu, Zhenni Xiang, Jian Wang, Wan-Xia Wu, Wen-Jing Yi.  (2023)  ROS-responsive core crosslinked micelles by combination of enzymatic polymerization and thiol-ene click chemistry for anticancer drug delivery.  EUROPEAN POLYMER JOURNAL,  199  (15): (112473).  [PMID:12960329]
9. Wen-shuo Zhang, Li-peng Tan, Jun Shen, Yu-gao Wang, Gang Liu, Qing-bai Xu.  (2023)  Detoxification of coal-tar pitch by alkylation method and toxicity evaluation by chemical index, fumes and water-soluble substances.  CHEMICAL ENGINEERING SCIENCE,  282  (119311).  [PMID:16338413]
10. Yuan-song Zhang, Xuechao Xu, Juanli Yang, Mengyuan Tan, Wenyuan Zhou, Lu Gao, Zhen-quan Yang.  (2023)  Directional immobilization of phage on the palladium-based nanozyme for colorimetric detection of Cronobacter sakazakii in powdered infant formula.  LWT-FOOD SCIENCE AND TECHNOLOGY,  186  (115260).  [PMID:22064484]
11. Yulin Zhang, Guozhao Ji, Aimin Li.  (2023)  Production of limonene epoxides from tire pyrolysis oil by polyoxometalate immobilized on SBA-15.  PROCESS SAFETY AND ENVIRONMENTAL PROTECTION,  178  (287).  [PMID:]
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14. Wei Mao, Jiawen Hao, Lingyu Zeng, Hao Wang, Hao Xu, Jinghong Zhou.  (2023)  Catalytic Conversion of Carbohydrates into 5-Hydroxymethylfurfural by Phosphotungstic Acid Encapsulated in MIL-101 (Cr, Sn) Catalyst in Deep Eutectic Solvents.  INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,  24  (14): (11480).  [PMID:37511237]
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31. Mingzhen Huang, Siyuan Hu, Dongren Cai, Guowu Zhan.  (2023)  Experimental and theoretical studies of carbon monoxide oxidation over W/Cu/Ce trimetallic oxides: the effect of W addition.  Materials Today Chemistry,  27  (101295).  [PMID:]
32. Hong Yuan, Xin Bao, Yong-Zhong Du, Jian You, Fu-Qiang Hu.  (2022)  Preparation and evaluation of SiO2-deposited stearic acid-g-chitosan nanoparticles for doxorubicin delivery.  International Journal of Nanomedicine,      [PMID:23055724]
33. Ning Zhang, Xiaojing Cui, Chizhou Wang, Shaodi Wu, Yuhua Zhao, Yongqin Qi, Xianglin Hou, Haibo Jin, Tiansheng Deng.  (2023)  Degradation of vinyl ester resin and its composites via cleavage of ester bonds to recycle valuable chemicals and produce polyurethane.  WASTE MANAGEMENT,  155  (260).  [PMID:36402102]
34. Boyong Ye, Ruru Zhou, Caili Wang, Zixuan Wang, Zixin Zhong, Zhaoyin Hou.  (2023)  Alcoholysis of waste PLA-based plastics to methyl lactate over sulfated ZrO2/SiO2 catalyst.  APPLIED CATALYSIS A-GENERAL,  649  (118936).  [PMID:]
35. Jiang Tianze, Xie Laozhi, Zhou Songlei, Liu Yipu, Huang Yukun, Mei Ni, Ma Fenfen, Gong Jingru, Gao Xiaoling, Chen Jun.  (2022)  Metformin and histone deacetylase inhibitor based anti-inflammatory nanoplatform for epithelial-mesenchymal transition suppression and metastatic tumor treatment.  JOURNAL OF NANOBIOTECHNOLOGY,  20  (1): (1-21).  [PMID:36045429]
36. Chongfu Wu, Zhenhua Sun, Changshen Ye, Zhaoyang Qi, Jie Chen, Zhixian Huang, Ting Qiu.  (2023)  Encapsulation of HPW and preparation of composites rich in Zr-defects by manual grinding: Synergistic catalysis for efficient oxidative desulfurization at room temperature.  CHEMICAL ENGINEERING JOURNAL,  451  (138906).  [PMID:]
37. Kunpeng Zhou, Zhengchao Zhang, Jingwen Xue, Jianmeng Shang, Dejun Ding, Weifen Zhang, Zhijun Liu, Fang Yan, Ni Cheng.  (2022)  Hybrid Ag nanoparticles/polyoxometalate-polydopamine nano-flowers loaded chitosan/gelatin hydrogel scaffolds with synergistic photothermal/chemodynamic/Ag+ anti-bacterial action for accelerated wound healing.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  221  (135).  [PMID:36029962]
38. Xiaoyan Xue, Yan Sun, Qiwen Sun, Weiren Bao, Zongsen Zhang, Liping Chang, Jiancheng Wang, Kechang Xie.  (2022)  Esterification of 1-hexene and acetic acid using resin-supported phosphotungstic acid catalysts.  Journal of Science-Advanced Materials and Devices,  (100486).  [PMID:]
39. Yan Gao, Miao Yan, Jianshe Zhao.  (2022)  Metal–organic framework (UIO-66-NH2)-encapsulated peroxophosphotungstate (PW4) loaded on graphene oxide (GO) as catalyst for desulfurization of fuel.  MICROPOROUS AND MESOPOROUS MATERIALS,  341  (112105).  [PMID:]
40. Zheng Min, He Huiting, Li Xiangzhou, Yin Dulin.  (2022)  Imidazolized Activated Carbon Anchoring Phosphotungstic Acid as a Recyclable Catalyst for Oxidation of Alcohols With Aqueous Hydrogen Peroxide.  Frontiers in Chemistry,  10    [PMID:35844654]
41. Kaifeng Lu, Yifan Wang, Caidi Jin, Robert Liao, Weihong Tan, Jun Ye, Lingjun Zhu, Shurong Wang.  (2022)  Novel Approach on Developing TiO2-Supported Heteropolyacids Catalyst for the Efficient Conversion of Xylose to Furfural.  ENERGY & FUELS,  36  (14): (7599–7607).  [PMID:]
42. Zhao Zheng, Mu Li, Yuyan Lai, Youjin Cao, Panchao Yin.  (2022)  Decoupling Segmental Dynamics and Ionic Transport for Superionic Anhydrous Proton Conductors of Polyoxometalate-poly(ethylene glycol) Nanocomposites.  MACROMOLECULAR RAPID COMMUNICATIONS,  44  (1): (2200227).  [PMID:35642732]
43. Baoli Wang, Yijing Ai, Yucen Yao, Meng Jiang, Lijun Yan, Shiguan Xu, Wei Sun.  (2022)  Electrochemical synergy between FeNi nanoalloy@tungsten carbide on N-doped graphitized carbon layers as an excellent electrocatalyst for oxygen evolution reaction.  ELECTROCHIMICA ACTA,  415  (140254).  [PMID:]
44. Keng Xuan, Shikun Chen, Yanfeng Pu, Yaoping Guo, Yadan Guo, Yun Li, Chenxi Pu, Ning Zhao, Fukui Xiao.  (2022)  Encapsulating phosphotungstic acid within metal-organic framework for direct synthesis of dimethyl carbonate from CO2 and methanol.  Journal of CO2 Utilization,  59  (101960).  [PMID:]
45. Boyong Ye, Wenyang Zhang, Ruru Zhou, Yuanyuan Jiang, Zixin Zhong, Zhaoyin Hou.  (2022)  Dehydration of fructose to 5-hydroxymethylfurfural over a mesoporous sulfonated high-crosslinked polymer in different solvents.  NEW JOURNAL OF CHEMISTRY,  46  (14): (6756-6764).  [PMID:]
46. Qian-Qian Wang, Li-Hui Mao, Da-Xiang Wang, Yan-Mei Ma, Xin-Li Shi, Xi-Hao Tian.  (2022)  Construction of two new polyoxometalate complexes and their recyclability in photodegradation of cephalexin and ceftiofur.  INORGANICA CHIMICA ACTA,  536  (120902).  [PMID:]
47. Huiting He, Min Zheng, Qiang Liu, Jian Liu, Juan Zhao, Yuting Zhuang, Xianxiang Liu, Qiong Xu, Steven R. Kirk, Dulin Yin.  (2022)  Hydroxyl-assisted selective epoxidation of perillyl alcohol with hydrogen peroxide by vanadium-substituted phosphotungstic acid hinged on imidazolyl activated carbon.  NEW JOURNAL OF CHEMISTRY,  46  (14): (6636-6645).  [PMID:]
48. Jiawen Hao, Wei Mao, Guirong Ye, Yi Xia, Cui Wei, Ling Zeng, Jinghong Zhou.  (2022)  Tin–chromium bimetallic metal–organic framework MIL-101 (Cr, Sn) as a catalyst for glucose conversion into HMF.  BIOMASS & BIOENERGY,  159  (106395).  [PMID:]
49. Yue Gao, Qing-Bo Meng, Bao-Xin Wang, Yu Zhang, Hui Mao, Da-Wei Fang, Xi-Ming Song.  (2022)  Polyacrylonitrile Derived Robust and Flexible Poly(ionic liquid)s Nanofiber Membrane as Catalyst Supporter.  Catalysts,  12  (3): (266).  [PMID:]
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52. Li Jianyu, Zhang Jiaojing, Wang Yuanyuan, Wang Huan, Song Hua.  (2022)  Preparation of highly active g-C3N4 supported amphiphilic quaternary ammonium phosphotungstate catalyst for solvent-free oxidative desulfurization of benzothiophene.  Reaction Kinetics Mechanisms and Catalysis,  135  (1): (219-231).  [PMID:]
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55. Zhengfei Yu, Xifeng Chen, Yibo Zhang, Hongyu Tu, Pen Pan, Shuai Li, Yuxiang Han, Minjun Piao, Jianglei Hu, Fengwei Shi, Xia Yang.  (2022)  Phosphotungstic acid and propylsulfonic acid bifunctionalized ordered mesoporous silica: A highly efficient and reusable catalysts for esterification of oleic acid.  CHEMICAL ENGINEERING JOURNAL,  430  (133059).  [PMID:]
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References

1. Yuanning Yue, Ying Liao, Jiarong Lu, Yue Pan, Meiyu Zhang, Guiyue Chen, Xin Zhou, Xinyu Kuang, Hui Zhao, Xiaobo Chen, Xiang Feng, Hao Yan, Yibin Liu, Chaohe Yang.  (2024)  Metal-doped M-NH4-PW catalyst with enhanced electron transfer for formaldehyde-propylene condensation to 4-methyl-1,3-dioxane.  Molecular Catalysis,  553  (113813).  [PMID:]
2. Xue-qi Zhang, Rui Ding, Jing Lv, Yu-chen Zhang, An-lan Ji, Jie Fu, Xiao Lv, Sheng-ying Yang, Lan Yao, Xuan Liang, Jie Liu, Hai-bin Yu.  (2023)  The novel damage-reporting and self-healing coatings prepared by electrospinning technology based on AIE agents and photothermal shape memory polymer.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:]
3. Yaqi Xue, Haihong Xia, Jing Li, Jiantao Su, Fei Ge, Xiaohui Yang, Jianchun Jiang, Minghao Zhou.  (2023)  Heteropolyacids promoted MOF-derived high-performance Co(H4)@C-HPW0.25 catalysts for catalytic transfer hydrogenation of vanillin in mild condition.  CHEMICAL ENGINEERING JOURNAL,  478  (147456).  [PMID:16737835]
4. Xiaolan Yang, Jitao Li, Qiulan Li, Dezhi Yang, Yaling Yang.  (2024)  Colorimetric detection for raloxifene based on Cu-PTs nanozyme with peroxidase-like activity.  JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS,  239  (115922).  [PMID:38134706]
5. Li-Zhi Zhang, Hong-Bin Ju, Tao Geng, De-Bao Li, Ya-Jie Jiang, Ya-Kui Wang.  (2023)  Study on the epoxidation of chain olefins using biquaternary ammonium phosphotungstic acid phase transfer catalysts under no-solvent condition.  CHEMISTRY-A EUROPEAN JOURNAL,    (e202303559).  [PMID:38088217]
6. Zhonghai Liu, Junwei Liao, Yuying Gong, Jinliang Song, Tiejun Wang.  (2024)  Efficient production of jet-fuel precursors via one-pot dehydration-oligomerization of higher alcohols from upgrading of bioethanol.  ENERGY CONVERSION AND MANAGEMENT,  299  (117833).  [PMID:11134351]
7. Yan Gao, Shumin Zhao, Miao Yan, Yongxia Li, Jianshe Zhao.  (2024)  High efficiency extraction oxidation desulfurization of model liquid fuel catalyzed by MIL-101(Fe) supported peroxo-polyoxometalates.  MICROPOROUS AND MESOPOROUS MATERIALS,  364  (112857).  [PMID:21278800]
8. Pu Li, Qiang Liu, Zhenni Xiang, Jian Wang, Wan-Xia Wu, Wen-Jing Yi.  (2023)  ROS-responsive core crosslinked micelles by combination of enzymatic polymerization and thiol-ene click chemistry for anticancer drug delivery.  EUROPEAN POLYMER JOURNAL,  199  (15): (112473).  [PMID:12960329]
9. Wen-shuo Zhang, Li-peng Tan, Jun Shen, Yu-gao Wang, Gang Liu, Qing-bai Xu.  (2023)  Detoxification of coal-tar pitch by alkylation method and toxicity evaluation by chemical index, fumes and water-soluble substances.  CHEMICAL ENGINEERING SCIENCE,  282  (119311).  [PMID:16338413]
10. Yuan-song Zhang, Xuechao Xu, Juanli Yang, Mengyuan Tan, Wenyuan Zhou, Lu Gao, Zhen-quan Yang.  (2023)  Directional immobilization of phage on the palladium-based nanozyme for colorimetric detection of Cronobacter sakazakii in powdered infant formula.  LWT-FOOD SCIENCE AND TECHNOLOGY,  186  (115260).  [PMID:22064484]
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Solution Calculators