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Wilkinson’s catalyst - 97%, high purity , CAS No.14694-95-2

  • ≥97%
Item Number
W106045
Grouped product items
SKUSizeAvailabilityPrice Qty
W106045-100mg
100mg
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$20.90
W106045-250mg
250mg
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$40.90
W106045-500mg
500mg
In stock
$61.90
W106045-1g
1g
In stock
$95.90
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Discover Wilkinson’s catalyst by Aladdin Scientific in 97% for only $20.90. Available - in Ligands at Aladdin Scientific. Tags: Element classified compounds, Transition metal compounds.

View related series
Element classified compounds Transition metal compounds

Basic Description

SynonymsTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | T0931 | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(trip
Specifications & Purity97%
Storage TempStore at 2-8°C,Protected from light,Argon charged
Shipped InWet ice
Product Description

Product class
M-P, Homogeneous Catalysts, Phosphorus Ligands - Achiral

Reaction type
Cross Coupling Reactions with Arenes, Allylic Alkylation, C-H Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Decarbonylation, Hydroformylation, Isomerization, Oligomerization, Oxidation

Chemical properties

Chemical formula

C54H45ClP3Rh

Empirical formula

Rh(PPh3)3Cl

Molecular weight

925.23

Metal

Rh

Theoretical metal content

11

Physical state

crystalline

Color

red

Names and Identifiers

Pubchem Sid488186262
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488186262
IUPAC Name rhodium;triphenylphosphane;chloride
INCHI InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1
InChi Key QBERHIJABFXGRZ-UHFFFAOYSA-M
Canonical SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
Isomeric SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
WGK Germany 3
PubChem CID 84599
UN Number 1759
Molecular Weight 925.22
Beilstein 4581440
Reaxy-Rn 14664394

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

9 results found

Lot NumberCertificate TypeDateItem
G2214306Certificate of AnalysisApr 25, 2024 W106045
G2214308Certificate of AnalysisApr 25, 2024 W106045
I2103403Certificate of AnalysisJan 04, 2024 W106045
I2103402Certificate of AnalysisJun 07, 2023 W106045
E2317606Certificate of AnalysisJan 03, 2023 W106045
E2317636Certificate of AnalysisJan 03, 2023 W106045
E2317657Certificate of AnalysisJan 03, 2023 W106045
E2317668Certificate of AnalysisJan 03, 2023 W106045
I2320032Certificate of AnalysisJun 19, 2022 W106045

Chemical and Physical Properties

SolubilitySoluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution.
SensitivityLight, Air and Heat sensitive
Melt Point(°C)245-250°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07
Signal Warning
Hazard Statements

H411:Toxic to aquatic life with long lasting effects

H413:May cause long lasting harmful effects to aquatic life

H302:Harmful if swallowed

H317:May cause an allergic skin reaction

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P270:Do not eat, drink or smoke when using this product.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P330:Rinse mouth.

P301+P317:IF SWALLOWED: Get medical help.

WGK Germany 3
Reaxy-Rn 14664394
Merck Index 9758

Related Documents

 SDS

 Specification Sheet

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FAQs and Articles

FAQ
Hydrogenation Catalysts
Categories: Technical articles
Tags:
Catalysts Organic catalyst Transition metal catalyst Hydrogenation Catalysts Hydrogenation Reduce
Hydrosilylation and Hydrosilylation Catalyst
Categories: Technical articles
Tags:
Organic block Catalyzer Silicon hydride

References

1. Johannes Kiefer,Katharina Obert,Simone Himmler,Peter S Schulz,Peter Wasserscheid,Alfred Leipertz.  (2008-09-16)  Infrared spectroscopy of a Wilkinson catalyst in a room-temperature ionic liquid..  Chemphyschem : a European journal of chemical physics and physical chemistry,  9  ((15)): (2207-2213).  [PMID:18792033]
2. V P Shevchenko,I Iu Nagaev,I S Levina,L E Kulikova,N F Miasoedov,A V Kamernitzkiĭ.  (2010-06-10)  [The synthesis of O-substituted 3-oximes of 6alpha-methyl-16alpha,17alpha-cyclohexanopregn-4-ene-3,20-dione tritium-labeled in 1 and 2 positions]..  Bioorganicheskaia khimiia,  36  ((2)): (283-288).  [PMID:20531488]
3. P Andrew Evans,John E Robinson,Erich W Baum,Aleem N Fazal.  (2002-07-26)  Intermolecular transition metal-catalyzed [4 + 2 + 2] cycloaddition reactions: a new approach to the construction of eight-membered rings..  Journal of the American Chemical Society,  124  ((30)): (8782-8783).  [PMID:12137516]

Solution Calculators

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