Basic Description

Synonyms	TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE \| T0931 \| NSC199379 \| Chlorotris(triphenylphosphine)rhodium(I) \| chlorotris(triphenylphosphine)-rhodium(i) \| Tris(triphenylphosphine)rhodium(I) chloride \| tris-(triphenylphosphine)rhodium(i) chloride \| tris(trip
Specifications & Purity	≥97%
Storage Temp	Store at 2-8°C,Protected from light,Argon charged
Shipped In	Wet ice
Product Description	Product class M-P, Homogeneous Catalysts, Phosphorus Ligands - Achiral Reaction type Cross Coupling Reactions with Arenes, Allylic Alkylation, C-H Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Decarbonylation, Hydroformylation, Isomerization, Oligomerization, Oxidation Chemical properties Chemical formula C54H45ClP3Rh Empirical formula Rh(PPh3)3Cl Molecular weight 925.23 Metal Rh Theoretical metal content 11 Physical state crystalline Color red

Names and Identifiers

Pubchem Sid	488186262
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488186262
IUPAC Name	rhodium;triphenylphosphane;chloride
INCHI	InChI=1S/3C18H15P.ClH.Rh/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h31-15H;1H;/p-1
InChi Key	QBERHIJABFXGRZ-UHFFFAOYSA-M
Canonical SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
WGK Germany	3
PubChem CID	84599
UN Number	1759
Molecular Weight	925.22
Beilstein	4581440
Reaxy-Rn	14664394

Certificates

Certificate of Analysis(COA)

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9 results found

Lot Number	Certificate Type	Date	Item
G2214306	Certificate of Analysis	Apr 25, 2024	W106045
G2214308	Certificate of Analysis	Apr 25, 2024	W106045
I2103403	Certificate of Analysis	Jan 04, 2024	W106045
I2103402	Certificate of Analysis	Jun 07, 2023	W106045
E2317606	Certificate of Analysis	Jan 03, 2023	W106045
E2317636	Certificate of Analysis	Jan 03, 2023	W106045
E2317657	Certificate of Analysis	Jan 03, 2023	W106045
E2317668	Certificate of Analysis	Jan 03, 2023	W106045
I2320032	Certificate of Analysis	Jun 19, 2022	W106045

Chemical and Physical Properties

Solubility	Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution.
Sensitivity	Light, Air and Heat sensitive
Melt Point(°C)	245-250°C

Safety and Hazards(GHS)

Pictogram(s)	GHS09, GHS07
Signal	Warning
Hazard Statements	H411:Toxic to aquatic life with long lasting effects H413:May cause long lasting harmful effects to aquatic life H302:Harmful if swallowed H317:May cause an allergic skin reaction
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P270:Do not eat, drink or smoke when using this product. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage. P330:Rinse mouth. P301+P317:IF SWALLOWED: Get medical help.
WGK Germany	3
Reaxy-Rn	14664394
Merck Index	9758

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Hydrogenation Catalysts

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Organic block Catalyzer Silicon hydride

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang. (2020) Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 40 (5226). [PMID:] [10.1016/j.jeurceramsoc.2020.06.039]

References

1. Johannes Kiefer,Katharina Obert,Simone Himmler,Peter S Schulz,Peter Wasserscheid,Alfred Leipertz. (2008-09-16) Infrared spectroscopy of a Wilkinson catalyst in a room-temperature ionic liquid.. Chemphyschem : a European journal of chemical physics and physical chemistry, 9 ((15)): (2207-2213). [PMID:18792033]
2. V P Shevchenko,I Iu Nagaev,I S Levina,L E Kulikova,N F Miasoedov,A V Kamernitzkiĭ. (2010-06-10) [The synthesis of O-substituted 3-oximes of 6alpha-methyl-16alpha,17alpha-cyclohexanopregn-4-ene-3,20-dione tritium-labeled in 1 and 2 positions].. Bioorganicheskaia khimiia, 36 ((2)): (283-288). [PMID:20531488]
3. P Andrew Evans,John E Robinson,Erich W Baum,Aleem N Fazal. (2002-07-26) Intermolecular transition metal-catalyzed [4 + 2 + 2] cycloaddition reactions: a new approach to the construction of eight-membered rings.. Journal of the American Chemical Society, 124 ((30)): (8782-8783). [PMID:12137516]
4. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang. (2020) Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 40 (5226). [PMID:] [10.1016/j.jeurceramsoc.2020.06.039]

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SKU	Size	Availability	Price
W106045-100mg	100mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$20.90
W106045-250mg	250mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$40.90
W106045-500mg	500mg	In stock	$61.90
W106045-1g	1g	In stock	$95.90

Wilkinson’s catalyst - 97%, high purity , CAS No.14694-95-2