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Wilkinson’s catalyst - 99.95% metals basis, high purity , CAS No.14694-95-2
Discover Wilkinson’s catalyst by Aladdin Scientific in 99.95% metals basis for only $343.90. Available - in Ligands at Aladdin Scientific. Tags: .
Basic Description Synonyms TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | T0931 | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(trip Specifications & Purity ≥99.95% metals basis Storage Temp Store at 2-8°C,Protected from light,Argon charged Shipped In Wet ice Product Description Product class
Reaction type
Chemical properties
Theoretical metal content
Names and Identifiers IUPAC Name rhodium;triphenylphosphane;chloride INCHI InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1 InChi Key QBERHIJABFXGRZ-UHFFFAOYSA-M Canonical SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh] Isomeric SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh] WGK Germany 3 PubChem CID 84599 UN Number 1759 Molecular Weight 925.22 Beilstein 4581440 Reaxy-Rn 14664394
Chemical and Physical Properties Solubility Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution. Sensitivity Light, Air and Heat sensitive Melt Point(°C) 245-250°C
Safety and Hazards(GHS) Pictogram(s) GHS09 , GHS07 Signal Warning Hazard Statements H411: Toxic to aquatic life with long lasting effects
H413: May cause long lasting harmful effects to aquatic life
H302: Harmful if swallowed
H317: May cause an allergic skin reaction
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P333+P313: IF SKIN irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
P330: Rinse mouth.
P301+P317: IF SWALLOWED: Get medical help.
WGK Germany 3 Reaxy-Rn 14664394 Merck Index 9758
Citations of This Product 1. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang. (2020) Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 40 (5226). [PMID: [10.1016/j.jeurceramsoc.2020.06.039 ]
References 1. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang. (2020) Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 40 (5226). [PMID: [10.1016/j.jeurceramsoc.2020.06.039 ]
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