Wilkinson’s catalyst - 99.95% metals basis, high purity , CAS No.14694-95-2

Item Number

W347495

Grouped product items
SKU	Size	Availability	Price
W347495-250mg	250mg	In stock	$343.90
W347495-1g	1g	In stock	$1,133.90
W347495-5g	5g	In stock	$2,746.90

Discover Wilkinson’s catalyst by Aladdin Scientific in 99.95% metals basis for only $343.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	14694-95-2\|Chlorotris(triphenylphosphine)rhodium(I)\|Tris(triphenylphosphine)rhodium(I) chloride\|Wilkinson's catalyst\|Tris(triphenylphosphine)chlororhodium\|Chlorotris(triphenylphosphine)rhodium\|16592-65-7\|rhodium;triphenylphosphane;chloride\|Tris(triphenylp
Specifications & Purity	99.95% metals basis
Storage Temp	Store at 2-8°C,Protected from light,Argon charged
Shipped In	Wet ice
Product Description	Product class M-P, Homogeneous Catalysts, Phosphorus Ligands - Achiral Reaction type Cross Coupling Reactions with Arenes, Allylic Alkylation, C-H Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Decarbonylation, Hydroformylation, Isomerization, Oligomerization, Oxidation Chemical properties Chemical formula C54H45ClP3Rh Empirical formula Rh(PPh3)3Cl Molecular weight 925.23 Metal Rh Theoretical metal content 11 Physical state crystalline Color Metal purity red 99.95

Names and Identifiers

IUPAC Name	rhodium;triphenylphosphane;chloride
INCHI	InChI=1S/3C18H15P.ClH.Rh/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h31-15H;1H;/p-1
InChi Key	QBERHIJABFXGRZ-UHFFFAOYSA-M
Canonical SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
WGK Germany	3
PubChem CID	84599
UN Number	1759
Molecular Weight	925.22
Beilstein	4581440
Reaxy-Rn	14664394

Certificates

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4 results found

Lot Number	Certificate Type	Date	Item
B2208526	Certificate of Analysis	Dec 17, 2021	W347495
B2208527	Certificate of Analysis	Dec 17, 2021	W347495
B2208529	Certificate of Analysis	Dec 17, 2021	W347495
E2429032	Certificate of Analysis	Dec 17, 2021	W347495

Solubility

Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution.

Sensitivity

Light, Air and Heat sensitive

Melt Point(°C)

245-250°C

Safety and Hazards(GHS)

Pictogram(s)	GHS09, GHS07
Signal	Warning
Hazard Statements	H411:Toxic to aquatic life with long lasting effects H413:May cause long lasting harmful effects to aquatic life H302:Harmful if swallowed H317:May cause an allergic skin reaction
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P270:Do not eat, drink or smoke when using this product. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage. P330:Rinse mouth. P301+P317:IF SWALLOWED: Get medical help.
WGK Germany	3
Reaxy-Rn	14664394
Merck Index	9758

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Basic Description