A water-tolerant Lewis acid catalyst recently used in one-pot syntheses ofβ-lactams, and in stereocontrolled radical and nucleophilic addition reactions. Catalyzes the synthesis of deoxypenostatin A in a novel, stereoselective, intramolecular Diels-Alder reaction.Lewis acid catalyst used with a silylated chinchona alkaloid in an asymmetric synthesis of substituted β-lactams from an acid chloride and aryl imine. Also used to catalyze an aldehyde-ene reaction in a synthesis of the guaiane skeleton.An important Lewis acid catalyst for a variety of synthetic reactions, including allylborations.
1.Mukund P. Sibi,Jianguo Ji. (1996-09-06) Acyclic Stereocontrol in Radical Reactions. Diastereoselective Radical Addition/Allylation of N-Propenoyloxazolidinone.. The Journal of organic chemistry, 61 ((18)):(6090-6091). [PMID:11667436]
2.Jason W J Kennedy,Dennis G Hall. (2004-06-19) Lewis acid catalyzed allylboration: discovery, optimization, and application to the formation of stereogenic quaternary carbon centers.. The Journal of organic chemistry, 69 ((13)):(4412-4428). [PMID:15202896]
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