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Ytterbium(III) trifluoromethanesulfonate - 99.99%, high purity , CAS No.54761-04-5

  • PrimorTrace™
  • ≥99.99% metals basis
Item Number
Y475150
Grouped product items
SKUSizeAvailabilityPrice Qty
Y475150-1g
1g
In stock
$74.90
Y475150-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$247.90

Basic Description

Synonyms54761-04-5|Ytterbium(III) trifluoromethanesulfonate|ytterbium triflate|Ytterbium(III) triflate|Yb(OTf)3|Ytterbium(3+) triflate|ytterbiumtriflate|Ytterbium triflate [MI]|YTTERBIUM TRIFLUOROMETHANESULFONATE|MFCD06200261|ytterbium(iii)trifluoromethanesulfona
Specifications & Purity99.99%
Storage TempArgon charged
Shipped InNormal
GradePrimorTrace™
Product Description

Description

A water-tolerant Lewis acid catalyst recently used in one-pot syntheses ofβ-lactams, and in stereocontrolled radical and nucleophilic addition reactions. Catalyzes the synthesis of deoxypenostatin A in a novel, stereoselective, intramolecular Diels-Alder reaction.Lewis acid catalyst used with a silylated chinchona alkaloid in an asymmetric synthesis of substituted β-lactams from an acid chloride and aryl imine. Also used to catalyze an aldehyde-ene reaction in a synthesis of the guaiane skeleton.An important Lewis acid catalyst for a variety of synthetic reactions, including allylborations.

Names and Identifiers

IUPAC Name trifluoromethanesulfonate;ytterbium(3+)
INCHI InChI=1S/3CHF3O3S.Yb/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChi Key AHZJKOKFZJYCLG-UHFFFAOYSA-K
Canonical SMILES C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Yb+3]
Isomeric SMILES C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Yb+3]
WGK Germany 3
PubChem CID 2733225
UN Number 3261
Molecular Weight 620.25
Reaxy-Rn 8938748

Certificates

Certificate of Analysis(COA)

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2 results found

Lot NumberCertificate TypeDateItem
K2328532Certificate of AnalysisNov 09, 2023 Y475150
K2328533Certificate of AnalysisNov 09, 2023 Y475150

Chemical and Physical Properties

SensitivityHygroscopic

Safety and Hazards(GHS)

Pictogram(s) GHS07
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

WGK Germany 3
Reaxy-Rn 8938748
Merck Index 10106

Related Documents

References

1. Mukund P. Sibi,Jianguo Ji.  (1996-09-06)  Acyclic Stereocontrol in Radical Reactions. Diastereoselective Radical Addition/Allylation of N-Propenoyloxazolidinone..  The Journal of organic chemistry,  61  ((18)): (6090-6091).  [PMID:11667436]
2. Jason W J Kennedy,Dennis G Hall.  (2004-06-19)  Lewis acid catalyzed allylboration: discovery, optimization, and application to the formation of stereogenic quaternary carbon centers..  The Journal of organic chemistry,  69  ((13)): (4412-4428).  [PMID:15202896]

Solution Calculators