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Size

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Z118638-10g

10g

Available within 4-8 weeks(?)

$68.90

Z118638-50g

50g

Available within 4-8 weeks(?)

$239.90

Z118638-250g

250g

Available within 4-8 weeks(?)

$1,077.90

Basic Description

Synonyms	7699-45-8\|Zinc dibromide\|zinc;dibromide\|ZINCUM BROMATUM\|OO7ZBU9703\|DTXSID8052512\|ZINCBROMIDE\|7899-45-8\|zinc (II) bromide\|dibromozinc\|ZINC BROMIDE [MI]\|ZINC BROMIDE [HSDB]\|ZINC BROMIDE [WHO-DD]\|ZINCUM BROMATUM [HPUS]\|DTXCID2031085\|VNDYJBBGRKZCSX-UHFFFAOYSA
Specifications & Purity	99.999% metals basis
Storage Temp	Argon charged
Shipped In	Normal
Grade	PrimorTrace™
Product Description	Zinc bromide is an inorganic salt. Zinc bromide supported on hydroxyapatite (Zn-HAP) promotes the synthesis of 3-substituted indoles. Zinc bromide (ZnBr2) may be used for the following studies: Removal of dimethoxytrityl ethers from deoxynucleosides. Removal of N-acyl protecting group in nucleoside derivatives. Alkylation of O-silylated dienolates of unsaturated ketones and esters. As catalyst in the synthesis of α-perfluoroalkylated homoallylic alcohols.

Names and Identifiers

IUPAC Name	zinc;dibromide
INCHI	InChI=1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChi Key	VNDYJBBGRKZCSX-UHFFFAOYSA-L
Canonical SMILES	[Zn+2].[Br-].[Br-]
Isomeric SMILES	[Zn+2].[Br-].[Br-]
WGK Germany	3
RTECS	ZH1150000
PubChem CID	10421208
UN Number	3077
Packing Group	III
Molecular Weight	225.2

Certificates

Certificate of Analysis(COA)

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6 results found

Lot Number	Certificate Type	Date	Item
F2111040	Certificate of Analysis	Mar 13, 2023	Z118638
B23111064	Certificate of Analysis	Jan 04, 2023	Z118638
B23111065	Certificate of Analysis	Jan 04, 2023	Z118638
B23111100	Certificate of Analysis	Jan 04, 2023	Z118638
C2406060	Certificate of Analysis	Jan 04, 2023	Z118638
G2211026	Certificate of Analysis	Aug 03, 2022	Z118638

Chemical and Physical Properties

Solubility	Very soluble in ethanol and soluble in ethyl ether. Soluble in water (at 20°C 4470g/L).
Sensitivity	Hygroscopic
Refractive Index	1.5452
Boil Point(°C)	697°C
Melt Point(°C)	394°C

Safety and Hazards(GHS)

Pictogram(s)	GHS09, GHS05, GHS07
Signal	Danger
Hazard Statements	H411:Toxic to aquatic life with long lasting effects H314:Causes severe skin burns and eye damage H302:Harmful if swallowed H318:Causes serious eye damage H317:May cause an allergic skin reaction H400:Very toxic to aquatic life H410:Very toxic to aquatic life with long lasting effects
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage. P330:Rinse mouth. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3
RTECS	ZH1150000
Class	9
Merck Index	1029
RIDADR	UN3260 - class 8 - PG 3 - MP - RQ - Corrosive solid, acidic, inorganic, n.o.s., HI: all

References

1. N Sakairi,H Kuzuhara. (1996-01-04) Facile preparation of phenyl 1-thioglycosides of partially methylated maltooligosaccharides by restricted thiolysis of fully methylated cyclodextrins.. Carbohydrate research, 280 ((1)): (139-143). [PMID:8581893]
2. S Takeda,Y Kaneko,H Eto,M Tokizawa,S Sato,K Yoshida,S Namiki,M Ogawa. (2000-08-03) alpha,alpha-gem-Difluorination of alpha-(alkylthio)acetophenone derivatives with N-fluoropyridinium salts.. Chemical & pharmaceutical bulletin, 48 ((7)): (1097-1100). [PMID:10923850]
3. A E Hassan,R A Abou-Elkair,J A Montgomery,J A Secrist. (2000-09-22) Convenient syntheses of 6-methylpurine and related nucleosides.. Nucleosides, nucleotides & nucleic acids, 19 ((7)): (1123-1134). [PMID:10999252]
4. Ramesh Kaul,Yann Brouillette,Zohreh Sajjadi,Karl A Hansford,William D Lubell. (2004-09-18) Selective tert-butyl ester deprotection in the presence of acid labile protecting groups with use of ZnBr2.. The Journal of organic chemistry, 69 ((18)): (6131-6133). [PMID:15373501]
5. Daniela Andrei,Stanislaw F Wnuk. (2006-01-04) Synthesis of the multisubstituted halogenated olefins via cross-coupling of dihaloalkenes with alkylzinc bromides.. The Journal of organic chemistry, 71 ((1)): (405-408). [PMID:16388671]
6. Carles Rodríguez-Escrich,Anna Olivella,Fèlix Urpí,Jaume Vilarrasa. (2007-02-14) Toward a total synthesis of amphidinolide X and Y. The tetrahydrofuran-containing fragment C12-C21.. Organic letters, 9 ((6)): (989-992). [PMID:17295497]
7. Ruixue Deng,Liangdong Sun,Zhi Li. (2007-11-10) Nickel-catalyzed carboannulation reaction of o-bromobenzyl zinc bromide with unsaturated compounds.. Organic letters, 9 ((25)): (5207-5210). [PMID:17990889]
8. Biswajit Kalita,Angus A Lamar,Kenneth M Nicholas. (2008-09-20) Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons.. Chemical communications (Cambridge, England), ((36)(36)): (4291-4293). [PMID:18802547]
9. Frederic G Buono,Rama Chidambaram,Richard H Mueller,Robert E Waltermire. (2008-11-05) Insights into palladium-catalyzed cyanation of bromobenzene: additive effects on the rate-limiting step.. Organic letters, 10 ((23)): (5325-5328). [PMID:18980375]
10. Thomas Hameury,Jérôme Guillemont,Luc Van Hijfte,Véronique Bellosta,Janine Cossy. (2009-05-09) Diastereodivergent addition of allenylzincs to aryl glyoxylates.. Organic letters, 11 ((11)): (2397-2400). [PMID:19422262]
11. Yu Sung Chun,Young Ok Ko,Hyunik Shin,Sang-gi Lee. (2009-07-04) Tandem Blaise-alkenylation with unactivated alkynes: one-pot synthesis of alpha-vinylated beta-enaminoesters from nitriles.. Organic letters, 11 ((15)): (3414-3417). [PMID:19572602]
12. Chutian Shu,Kanwar Sidhu,Li Zhang,Xiao-Jun Wang,Dhileepkumar Krishnamurthy,Chris H Senanayake. (2010-09-08) Palladium-catalyzed cross-coupling of cyclopropylmagnesium bromide with aryl bromides mediated by zinc halide additives.. The Journal of organic chemistry, 75 ((19)): (6677-6680). [PMID:20815373]
13. Isabelle Aillaud,Caroline Haurena,Erwan Le Gall,Thierry Martens,Gino Ricci. (2010-11-13) 2-chlorophenyl zinc bromide: a convenient nucleophile for the mannich-related multicomponent synthesis of clopidogrel and ticlopidine.. Molecules (Basel, Switzerland), 15 ((11)): (8144-8155). [PMID:21072025]
14. Yejian Han,Lizhi Zhu,Yuan Gao,Chi-Sing Lee. (2011-01-12) A highly convergent cascade cyclization to cis-hydrindanes with all-carbon quaternary centers and its application in the synthesis of the aglycon of dendronobiloside A.. Organic letters, 13 ((4)): (588-591). [PMID:21218775]
15. Ganesan Gobi Rajeshwaran,Arasambattu K Mohanakrishnan. (2011-02-24) Synthetic studies on indolocarbazoles: total synthesis of staurosporine aglycon.. Organic letters, 13 ((6)): (1418-1421). [PMID:21341756]
16. Kensuke Kiyokawa,Nodoka Tachikake,Makoto Yasuda,Akio Baba. (2011-09-15) Direct synthesis of alkynylstannanes: ZnBr2 catalyst for the reaction of tributyltin methoxide and terminal alkynes.. Angewandte Chemie (International ed. in English), 50 ((44)): (10393-10396). [PMID:21915973]
17. Fernando Ferreira,François Morvan. (2005-10-27) Silyl protecting groups for oligonucleotide synthesis removed by a ZnBr2 treatment.. Nucleosides, nucleotides & nucleic acids, 24 ((5-7)): (1009-1013). [PMID:16248081]
18. Erik Lundberg,Stefan Bäckström,Uwe H Sauer,A Elisabeth Sauer-Eriksson. (2006-05-26) The transthyretin-related protein: structural investigation of a novel protein family.. Journal of structural biology, 155 ((3)): (445-457). [PMID:16723258]
19. J R Baker,O Thominet,H Britton,S Caddick. (2006-12-29) An efficient synthesis of epoxydiynes and a key fragment of neocarzinostatin chromophore.. Organic letters, 9 ((1)): (45-48). [PMID:17192081]
20. Yang Yu,Di Liu,Chunsheng Liu,Heng Jiang,Genxiang Luo. (2007-09-13) An Efficient one-pot Biginelli condensation of aliphatic aldehydes catalyzed by zinc bromide under solvent-free conditions.. Preparative biochemistry & biotechnology, 37 ((4)): (381-387). [PMID:17849292]
21. Teiichi Murakami,Yukari Sato,Motonari Shibakami. (2008-04-15) Stereoselective glycosylations using benzoylated glucosyl halides with inexpensive promoters.. Carbohydrate research, 343 ((8)): (1297-1308). [PMID:18406402]
22. Kathleen Simis,Mingzu Lei,Amy Tsai Lu,Krishnamohan C V Sharma,Ron L Hale,Ryan Timmons,Jim Cassella. (2008-09-19) Nicotine aerosol generation from thermally reversible zinc halide complexes using the Staccato system.. Drug development and industrial pharmacy, 34 ((9)): (936-942). [PMID:18800254]
23. Yasuhiro Inui,Masakazu Tanaka,Masanori Imai,Keitaro Tanaka,Hiroshi Suemune. (2009-10-06) Asymmetric Rh-catalyzed intermolecular hydroacylation of 1,5-hexadiene with salicylaldehyde.. Chemical & pharmaceutical bulletin, 57 ((10)): (1158-1160). [PMID:19801881]
24. Toshiaki Sasada,Youichi Aoki,Reiko Ikeda,Norio Sakai,Takeo Konakahara. (2011-07-23) Synthesis of tri- or tetrasubstituted pyrimidine derivatives through the [5+1] annulation of enamidines with either N,N-dimethylformamide dialkyl acetals or orthoesters and their application in a ring transformation of pyrimidines to pyrido[2,3-d]pyrimidin-5-one derivatives.. Chemistry (Weinheim an der Bergstrasse, Germany), 17 ((34)): (9385-9394). [PMID:21780196]
25. Saisai Li, Yun Huang, Wenhao Ren, Xing Li, Mingshan Wang, Haijun Cao . (2021) Stabilize lithium metal anode through in-situ forming a multi-component composite protective layer. Chemical Engineering Journal , 422 (2021): (129911). [PMID:]

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Zinc bromide - 99.999% metals basis, high purity , CAS No.7699-45-8

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

References

Solution Calculators

Molarity Calculator

Dilution Calculator

Reconstitution Calculator

SKU	Size	Availability	Price
Z118638-10g	10g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$68.90
Z118638-50g	50g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$239.90
Z118638-250g	250g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$1,077.90