Grouped product items

SKU

Size

Availability

Price

Qty

Z109460-25g

25g

In stock

$141.90

Z109460-100g

100g

In stock

$257.90

Z109460-500g

500g

Available within 4-8 weeks(?)

$1,158.90

Basic Description

Synonyms	Zirconium(IV) chloride\|ZIRCONIUM TETRACHLORIDE\|10026-11-6\|Tetrachlorozirconium\|Zirconium chloride\|ZrCl4\|zirconium(4+) tetrachloride\|MFCD00011306\|Z88176T871\|Zirconium chloride (ZrCl4)\|Zirconium chloride, tetra-\|Zirconium chloride, (T-4)-\|HSDB 2531\|Zirconiu
Specifications & Purity	≥99.9% metals basis
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Activator of pyrrolidines for improved convserion to the corresponding α,α-dimethylamines via a modified Bouveault reaction. Also suitable for nuclear reactor applications.

Names and Identifiers

IUPAC Name	tetrachlorozirconium
INCHI	InChI=1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChi Key	DUNKXUFBGCUVQW-UHFFFAOYSA-J
Canonical SMILES	Cl[Zr](Cl)(Cl)Cl
Isomeric SMILES	Cl[Zr](Cl)(Cl)Cl
WGK Germany	3
RTECS	ZH7175000
PubChem CID	24817
UN Number	2503
Packing Group	III
Molecular Weight	233.04

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

18 results found

Lot Number	Certificate Type	Date	Item
H2420370	Certificate of Analysis	Aug 02, 2024	Z109460
H2420367	Certificate of Analysis	Aug 02, 2024	Z109460
H2420369	Certificate of Analysis	Aug 02, 2024	Z109460
E2430469	Certificate of Analysis	May 22, 2024	Z109460
E2430470	Certificate of Analysis	May 22, 2024	Z109460
E2430471	Certificate of Analysis	May 22, 2024	Z109460
B2418465	Certificate of Analysis	Jan 18, 2024	Z109460
B2418467	Certificate of Analysis	Jan 18, 2024	Z109460
B2418692	Certificate of Analysis	Jan 18, 2024	Z109460
L2215755	Certificate of Analysis	Nov 30, 2022	Z109460
L2214976	Certificate of Analysis	Nov 30, 2022	Z109460
L2319113	Certificate of Analysis	Sep 15, 2022	Z109460
J2317149	Certificate of Analysis	Sep 15, 2022	Z109460
C2316584	Certificate of Analysis	Sep 15, 2022	Z109460
C2316581	Certificate of Analysis	Sep 15, 2022	Z109460
B2221082	Certificate of Analysis	Jan 03, 2022	Z109460
B2221080	Certificate of Analysis	Jan 03, 2022	Z109460
B2221079	Certificate of Analysis	Jan 03, 2022	Z109460

Chemical and Physical Properties

Solubility	Soluble in alcohol, ether, hydrochloric acid.
Sensitivity	Moisture sensitive
Boil Point(°C)	331°C
Melt Point(°C)	437°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H302:Harmful if swallowed H317:May cause an allergic skin reaction H334:May cause allergy or asthma symptoms or breathing difficulties if inhaled H312:Harmful in contact with skin H332:Harmful if inhaled H290:May be corrosive to metals
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P284:[In case of inadequate ventilation] Wear respiratory protection. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P234:Keep only in original container. P390:Absorb spillage to prevent material damage. P406:Store in corrosive resistant/... container with a resistant inner liner. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. P342+P316:If experiencing respiratory symptoms: Get emergence medical help immediately.
WGK Germany	3
RTECS	ZH7175000
Class	8

Alternative Products

References

1. A Z El-Sonbati,A A El-Bindary,I G A Rashed. (2002-06-27) Polymer complexes XXXVII novel models and structural of symmetrical poly-Schiff base on heterobinuclear complexes of dioxouranium(VI).. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58 ((7)): (1411-1424). [PMID:12083664]
2. Fouad Albaaj,Alastair Hutchison. (2003-03-27) Hyperphosphataemia in renal failure: causes, consequences and current management.. Drugs, 63 ((6)): (577-596). [PMID:12656655]
3. Ilanit Doron-Mor,Hagai Cohen,Sidney R Cohen,Ronit Popovitz-Biro,Abraham Shanzer,Alexander Vaskevich,Israel Rubinstein. (2004-11-17) Layer-by-layer assembly of ordinary and composite coordination multilayers.. Langmuir : the ACS journal of surfaces and colloids, 20 ((24)): (10727-10733). [PMID:15544408]
4. Abed Al Aziz Quntar,Morris Srebnik. (2006-01-18) Direct cyclopropanation of 1-alkynylphosphonates by Cp2ZrCl2/2EtMgBr/2AlCl3 to afford cyclopropylmethylphosphonates.. The Journal of organic chemistry, 71 ((2)): (730-733). [PMID:16408986]
5. Bryce M Whited,Aaron S Goldstein,Drago Skrtic,Brian J Love. (2006-06-14) Fabrication and characterization of poly(DL-lactic-co-glycolic acid)/zirconia-hybridized amorphous calcium phosphate composites.. Journal of biomaterials science. Polymer edition, 17 ((4)): (403-418). [PMID:16768292]
6. Thomas A Dineen,Matthew A Zajac,Andrew G Myers. (2006-12-15) Efficient transamidation of primary carboxamides by in situ activation with N,N-dialkylformamide dimethyl acetals.. Journal of the American Chemical Society, 128 ((50)): (16406-16409). [PMID:17165798]
7. Harish Kumar,Anupama Parmar. (2007-04-17) Ultrasound promoted ZrCl(4) catalyzed rapid synthesis of substituted 1,2,3,4-tetrahydropyrimidine-2-ones in solvent or dry media.. Ultrasonics sonochemistry, 15 ((2)): (129-132). [PMID:17434782]
8. Lutz Ackermann,Ludwig T Kaspar,Andreas Althammer. (2007-06-07) Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.. Organic & biomolecular chemistry, 5 ((12)): (1975-1978). [PMID:17551648]
9. Surendra Singh,Patrick J Guiry. (2009-07-04) Microwave-assisted synthesis of substituted tetrahydropyrans catalyzed by ZrCl4 and its application in the asymmetric synthesis of exo- and endo-brevicomin.. The Journal of organic chemistry, 74 ((15)): (5758-5761). [PMID:19572587]
10. Yajuan Yang,Changhua Liu,Haixia Wu,Rui Li. (2009-11-13) Preparation and characterization of films based on zirconium sulfophenyl phosphonate and chitosan.. Carbohydrate research, 345 ((1)): (148-153). [PMID:19906365]
11. Young Soo Ko,Jeong Suk Lee,Jin-Heong Yim,Jong-Ki Jeon,Kyeong Youl Jung. (2010-04-01) Influence of nanopores of MCM-41 and SBA-15 confining (n-BuCp)2ZrCl2 on copolymerization of ethylene-alpha-olefin.. Journal of nanoscience and nanotechnology, 10 ((1)): (180-185). [PMID:20352830]
12. Yun-Yang Wan,Rong Lu,Kazuhiro Akiyama,Katsuhisa Okamoto,Takayuki Honda,Yu-Min Du,Takashi Yoshida,Tetsuo Miyakoshi,Charles J Knill,John F Kennedy. (2010-04-07) Effects of lacquer polysaccharides, glycoproteins and isoenzymes on the activity of free and immobilised laccase from Rhus vernicifera.. International journal of biological macromolecules, 47 ((1)): (76-81). [PMID:20363247]
13. Ahmed Kamal,B Ashwini Kumar,Paidakula Suresh,Nagula Shankaraiah,M Shiva Kumar. (2010-12-15) An efficient one-pot synthesis of benzothiazolo-4β-anilino-podophyllotoxin congeners: DNA topoisomerase-II inhibition and anticancer activity.. Bioorganic & medicinal chemistry letters, 21 ((1)): (350-353). [PMID:21144748]
14. Tian-Yi Ma,Hui Li,An-Na Tang,Zhong-Yong Yuan. (2011-05-17) Ordered, mesoporous metal phosphonate materials with microporous crystalline walls for selective separation techniques.. Small (Weinheim an der Bergstrasse, Germany), 7 ((13)): (1827-1837). [PMID:21574251]
15. Helena Lundberg,Fredrik Tinnis,Hans Adolfsson. (2012-03-01) Direct amide coupling of non-activated carboxylic acids and amines catalysed by zirconium(IV) chloride.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((13)): (3822-3826). [PMID:22368037]
16. Stefania Fioravanti,Lucio Pellacani,Maria Cecilia Vergari. (2012-09-26) Fluorinated β-nitro amines by a selective ZrCl4-catalyzed aza-Henry reaction of (E)-trifluoromethyl aldimines.. Organic & biomolecular chemistry, 10 ((41)): (8207-8210). [PMID:23007677]
17. Yongjuan Chen,Seyed-Iman Roohani-Esfahani,ZuFu Lu,Hala Zreiqat,Colin R Dunstan. (2015-01-21) Zirconium ions up-regulate the BMP/SMAD signaling pathway and promote the proliferation and differentiation of human osteoblasts.. PloS one, 10 ((1)): (e0113426-e0113426). [PMID:25602473]
18. Takashi Toyao,Mika Fujiwaki,Kenta Miyahara,Tae-Ho Kim,Yu Horiuchi,Masaya Matsuoka. (2015-09-24) Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions.. ChemSusChem, 8 ((22)): (3905-3912). [PMID:26395673]
19. Serkan Gökpinar,Tatyana Diment,Christoph Janiak. (2017-07-19) Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use.. Dalton transactions (Cambridge, England : 2003), 46 ((30)): (9895-9900). [PMID:28719671]
20. Gauthier J-P Deblonde,Trevor D Lohrey,Rebecca J Abergel. (2019-05-17) Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones.. Dalton transactions (Cambridge, England : 2003), 48 ((23)): (8238-8247). [PMID:31094380]
21. Erik A Wu,Swastika Banerjee,Hanmei Tang,Peter M Richardson,Jean-Marie Doux,Ji Qi,Zhuoying Zhu,Antonin Grenier,Yixuan Li,Enyue Zhao,Grayson Deysher,Elias Sebti,Han Nguyen,Ryan Stephens,Guy Verbist,Karena W Chapman,Raphaële J Clément,Abhik Banerjee,Ying Shirley Meng,Shyue Ping Ong. (2021-02-25) A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries.. Nature communications, 12 ((1)): (1256-1256). [PMID:33623048]
22. Yasuhiro Torisawa,Takao Nishi,Jun ichi Minamikawa. (2003-04-26) A study on the conversion of indanones into carbostyrils.. Bioorganic & medicinal chemistry, 11 ((10)): (2205-2209). [PMID:12713830]
23. Giles W Theaker,Colin Morton,Peter Scott. (2008-12-04) Awakening a dormant catalyst: salicylaldimine systems for ethene/tert-butylstyrene copolymerization.. Dalton transactions (Cambridge, England : 2003), (48) ((48)): (6883-6885). [PMID:19050773]
24. Xiaoyin Xiao,Gabriel A Montaño,Amy Allen,Komandoor E Achyuthan,David R Wheeler,Susan M Brozik. (2011-06-28) Lipid bilayer templated gold nanoparticles nanoring formation using zirconium ion coordination chemistry.. Langmuir : the ACS journal of surfaces and colloids, 27 ((15)): (9484-9489). [PMID:21699157]
25. Dana Rutherford,Stephen Exarhos,Changlu Xu,Matt Niacaris,Crystal Mariano,Bryce Dayap,Lorenzo Mangolini,Huinan Liu. (2019-07-25) Synthesis, characterization, and cytocompatibility of yttria stabilized zirconia nanopowders for creating a window to the brain.. Journal of biomedical materials research. Part B, Applied biomaterials, 108 ((3)): (925-938). [PMID:31339630]
26. Xuefeng Liu. (2020) Preparation, characterization and growth mechanism of ZrO2 nanosheets. Ceramics International, 46 (4): (4864-4869). [PMID:]
27. Xuefeng Liu. (2020) Effect of NaOH on the preparation of two-dimensional flake-like zirconia nanostructures. Chemical Physics Letters, 754 (1): (137755). [PMID:]
28. Xuefeng Liu. (2021) Partially stabilized tetragonal ZrO2 whiskers with preferred [001] direction derived from CaF2. Journal of Materiomics, 7 (4): (879-885). [PMID:]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.

Zirconium(IV) chloride - ≥99.9% metals basis, high purity , CAS No.10026-11-6