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Z431132-5g

In stock

$17.90

Z431132-100g

100g

In stock

$79.90

Z431132-500g

500g

Available within 4-8 weeks(?)

$269.90

Basic Description

Synonyms	Zirconium(IV) chloride\|ZIRCONIUM TETRACHLORIDE\|10026-11-6\|Tetrachlorozirconium\|Zirconium chloride\|ZrCl4\|zirconium(4+) tetrachloride\|MFCD00011306\|Z88176T871\|Zirconium chloride (ZrCl4)\|Zirconium chloride, tetra-\|Zirconium chloride, (T-4)-\|HSDB 2531\|Zirconiu
Specifications & Purity	≥99.5% trace metals basis
Product Description	General Description We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. Application Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents. Direct amide formation from unactivated carboxylic acids and amines

Names and Identifiers

Pubchem Sid	488182925
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488182925
IUPAC Name	tetrachlorozirconium
INCHI	InChI=1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChi Key	DUNKXUFBGCUVQW-UHFFFAOYSA-J
Canonical SMILES	Cl[Zr](Cl)(Cl)Cl
Isomeric SMILES	Cl[Zr](Cl)(Cl)Cl
WGK Germany	3
RTECS	ZH7175000
PubChem CID	24817
UN Number	2503
Packing Group	III
Molecular Weight	233.04

Certificates

Certificate of Analysis(COA)

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11 results found

Lot Number	Certificate Type	Date	Item
C2408161	Certificate of Analysis	Dec 28, 2023	Z431132
G2405074	Certificate of Analysis	Dec 28, 2023	Z431132
L2320383	Certificate of Analysis	Dec 28, 2023	Z431132
L2320384	Certificate of Analysis	Dec 28, 2023	Z431132
L2320385	Certificate of Analysis	Dec 28, 2023	Z431132
D2426088	Certificate of Analysis	Nov 27, 2023	Z431132
K2314115	Certificate of Analysis	Nov 27, 2023	Z431132
K2314114	Certificate of Analysis	Nov 27, 2023	Z431132
B2308443	Certificate of Analysis	Feb 16, 2023	Z431132
B2308444	Certificate of Analysis	Feb 16, 2023	Z431132
B2308445	Certificate of Analysis	Feb 16, 2023	Z431132

Chemical and Physical Properties

Boil Point(°C)	331°C
Melt Point(°C)	437°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H302:Harmful if swallowed H317:May cause an allergic skin reaction H334:May cause allergy or asthma symptoms or breathing difficulties if inhaled H312:Harmful in contact with skin H332:Harmful if inhaled H290:May be corrosive to metals
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P284:[In case of inadequate ventilation] Wear respiratory protection. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P234:Keep only in original container. P390:Absorb spillage to prevent material damage. P406:Store in corrosive resistant/... container with a resistant inner liner. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. P342+P316:If experiencing respiratory symptoms: Get emergence medical help immediately.
WGK Germany	3
RTECS	ZH7175000
Class	8

References

1. A Z El-Sonbati,A A El-Bindary,I G A Rashed. (2002-06-27) Polymer complexes XXXVII novel models and structural of symmetrical poly-Schiff base on heterobinuclear complexes of dioxouranium(VI).. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58 ((7)): (1411-1424). [PMID:12083664]
2. Fouad Albaaj,Alastair Hutchison. (2003-03-27) Hyperphosphataemia in renal failure: causes, consequences and current management.. Drugs, 63 ((6)): (577-596). [PMID:12656655]
3. Ilanit Doron-Mor,Hagai Cohen,Sidney R Cohen,Ronit Popovitz-Biro,Abraham Shanzer,Alexander Vaskevich,Israel Rubinstein. (2004-11-17) Layer-by-layer assembly of ordinary and composite coordination multilayers.. Langmuir : the ACS journal of surfaces and colloids, 20 ((24)): (10727-10733). [PMID:15544408]
4. Abed Al Aziz Quntar,Morris Srebnik. (2006-01-18) Direct cyclopropanation of 1-alkynylphosphonates by Cp2ZrCl2/2EtMgBr/2AlCl3 to afford cyclopropylmethylphosphonates.. The Journal of organic chemistry, 71 ((2)): (730-733). [PMID:16408986]
5. Bryce M Whited,Aaron S Goldstein,Drago Skrtic,Brian J Love. (2006-06-14) Fabrication and characterization of poly(DL-lactic-co-glycolic acid)/zirconia-hybridized amorphous calcium phosphate composites.. Journal of biomaterials science. Polymer edition, 17 ((4)): (403-418). [PMID:16768292]
6. Thomas A Dineen,Matthew A Zajac,Andrew G Myers. (2006-12-15) Efficient transamidation of primary carboxamides by in situ activation with N,N-dialkylformamide dimethyl acetals.. Journal of the American Chemical Society, 128 ((50)): (16406-16409). [PMID:17165798]
7. Harish Kumar,Anupama Parmar. (2007-04-17) Ultrasound promoted ZrCl(4) catalyzed rapid synthesis of substituted 1,2,3,4-tetrahydropyrimidine-2-ones in solvent or dry media.. Ultrasonics sonochemistry, 15 ((2)): (129-132). [PMID:17434782]
8. Lutz Ackermann,Ludwig T Kaspar,Andreas Althammer. (2007-06-07) Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.. Organic & biomolecular chemistry, 5 ((12)): (1975-1978). [PMID:17551648]
9. Surendra Singh,Patrick J Guiry. (2009-07-04) Microwave-assisted synthesis of substituted tetrahydropyrans catalyzed by ZrCl4 and its application in the asymmetric synthesis of exo- and endo-brevicomin.. The Journal of organic chemistry, 74 ((15)): (5758-5761). [PMID:19572587]
10. Yajuan Yang,Changhua Liu,Haixia Wu,Rui Li. (2009-11-13) Preparation and characterization of films based on zirconium sulfophenyl phosphonate and chitosan.. Carbohydrate research, 345 ((1)): (148-153). [PMID:19906365]
11. Young Soo Ko,Jeong Suk Lee,Jin-Heong Yim,Jong-Ki Jeon,Kyeong Youl Jung. (2010-04-01) Influence of nanopores of MCM-41 and SBA-15 confining (n-BuCp)2ZrCl2 on copolymerization of ethylene-alpha-olefin.. Journal of nanoscience and nanotechnology, 10 ((1)): (180-185). [PMID:20352830]
12. Yun-Yang Wan,Rong Lu,Kazuhiro Akiyama,Katsuhisa Okamoto,Takayuki Honda,Yu-Min Du,Takashi Yoshida,Tetsuo Miyakoshi,Charles J Knill,John F Kennedy. (2010-04-07) Effects of lacquer polysaccharides, glycoproteins and isoenzymes on the activity of free and immobilised laccase from Rhus vernicifera.. International journal of biological macromolecules, 47 ((1)): (76-81). [PMID:20363247]
13. Ahmed Kamal,B Ashwini Kumar,Paidakula Suresh,Nagula Shankaraiah,M Shiva Kumar. (2010-12-15) An efficient one-pot synthesis of benzothiazolo-4β-anilino-podophyllotoxin congeners: DNA topoisomerase-II inhibition and anticancer activity.. Bioorganic & medicinal chemistry letters, 21 ((1)): (350-353). [PMID:21144748]
14. Tian-Yi Ma,Hui Li,An-Na Tang,Zhong-Yong Yuan. (2011-05-17) Ordered, mesoporous metal phosphonate materials with microporous crystalline walls for selective separation techniques.. Small (Weinheim an der Bergstrasse, Germany), 7 ((13)): (1827-1837). [PMID:21574251]
15. Helena Lundberg,Fredrik Tinnis,Hans Adolfsson. (2012-03-01) Direct amide coupling of non-activated carboxylic acids and amines catalysed by zirconium(IV) chloride.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((13)): (3822-3826). [PMID:22368037]
16. Stefania Fioravanti,Lucio Pellacani,Maria Cecilia Vergari. (2012-09-26) Fluorinated β-nitro amines by a selective ZrCl4-catalyzed aza-Henry reaction of (E)-trifluoromethyl aldimines.. Organic & biomolecular chemistry, 10 ((41)): (8207-8210). [PMID:23007677]
17. Yongjuan Chen,Seyed-Iman Roohani-Esfahani,ZuFu Lu,Hala Zreiqat,Colin R Dunstan. (2015-01-21) Zirconium ions up-regulate the BMP/SMAD signaling pathway and promote the proliferation and differentiation of human osteoblasts.. PloS one, 10 ((1)): (e0113426-e0113426). [PMID:25602473]
18. Takashi Toyao,Mika Fujiwaki,Kenta Miyahara,Tae-Ho Kim,Yu Horiuchi,Masaya Matsuoka. (2015-09-24) Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions.. ChemSusChem, 8 ((22)): (3905-3912). [PMID:26395673]
19. Hongqiao Zhou,Changhui Fu,Xiaowei Chen,Longfei Tan,Jie Yu,Qiong Wu,Liuhui Su,Zhongbing Huang,Feng Cao,Xiangling Ren,Jun Ren,Ping Liang,Xianwei Meng. (2018-04-20) Mitochondria-targeted zirconium metal-organic frameworks for enhancing the efficacy of microwave thermal therapy against tumors.. Biomaterials science, 6 ((6)): (1535-1545). [PMID:29670952]
20. Jochen Ortmeyer,Alexander Bodach,Lesia Sandig-Predzymirska,Bodo Zibrowius,Florian Mertens,Michael Felderhoff. (2019-01-19) Direct Hydrogenation of Aluminum via Stabilization with Triethylenediamine: A Mechanochemical Approach to Synthesize the Triethylenediamine\u2009⋅\u2009AlH3 Adduct.. Chemphyschem : a European journal of chemical physics and physical chemistry, 20 ((10)): (1360-1368). [PMID:30657245]
21. Lyudmila V Parfenova,Pavel V Kovyazin,Almira Kh Bikmeeva. (2020-05-14) Bimetallic Zr,Zr-Hydride Complexes in Zirconocene Catalyzed Alkene Dimerization.. Molecules (Basel, Switzerland), 25 ((9)): [PMID:32397335]
22. Yasuhiro Torisawa,Takao Nishi,Jun ichi Minamikawa. (2003-04-26) A study on the conversion of indanones into carbostyrils.. Bioorganic & medicinal chemistry, 11 ((10)): (2205-2209). [PMID:12713830]
23. Giles W Theaker,Colin Morton,Peter Scott. (2008-12-04) Awakening a dormant catalyst: salicylaldimine systems for ethene/tert-butylstyrene copolymerization.. Dalton transactions (Cambridge, England : 2003), (48) ((48)): (6883-6885). [PMID:19050773]
24. Xiaoyin Xiao,Gabriel A Montaño,Amy Allen,Komandoor E Achyuthan,David R Wheeler,Susan M Brozik. (2011-06-28) Lipid bilayer templated gold nanoparticles nanoring formation using zirconium ion coordination chemistry.. Langmuir : the ACS journal of surfaces and colloids, 27 ((15)): (9484-9489). [PMID:21699157]
25. Lyudmila V Parfenova,Irina V Zakirova,Pavel V Kovyazin,Stanislav G Karchevsky,Galina P Istomina,Leonard M Khalilov,Usein M Dzhemilev. (2016-07-29) Intramolecular mobility of η(5)-ligands in chiral zirconocene complexes and the enantioselectivity of alkene functionalization by organoaluminum compounds.. Dalton transactions (Cambridge, England : 2003), 45 ((32)): (12814-12826). [PMID:27468433]
26. Ines Sifaoui,Idaira Pacheco-Fernández,José E Piñero,Verónica Pino,Jacob Lorenzo-Morales. (2021-02-19) A Simple in vivo Assay Using Amphipods for the Evaluation of Potential Biocompatible Metal-Organic Frameworks.. Frontiers in bioengineering and biotechnology, 9 (584115-584115). [PMID:33598453]
27. Xuefeng Liu. (2020) Preparation, characterization and growth mechanism of ZrO2 nanosheets. Ceramics International, 46 (4): (4864-4869). [PMID:]
28. Xuefeng Liu. (2020) Effect of NaOH on the preparation of two-dimensional flake-like zirconia nanostructures. Chemical Physics Letters, 754 (1): (137755). [PMID:]
29. Xuefeng Liu. (2021) Partially stabilized tetragonal ZrO2 whiskers with preferred [001] direction derived from CaF2. Journal of Materiomics, 7 (4): (879-885). [PMID:]

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Zirconium(IV) chloride - ≥99.5% trace metals basis, high purity , CAS No.10026-11-6