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Zirconium propoxide solution - 70 wt. % in n-propanol, high purity , CAS No.23519-77-9

22 Citations

70 wt. % in n-propanol

CAS#: 23519-77-9
Formula: C₁₂H₂₈O₄Zr
Molecular Weight: 327.57
Beilstein Registry Number: 3679533
MDL number: MFCD00015307
PubChem CID: 90139

Item Number

Z106340

Grouped product items
SKU	Size	Availability	Price
Z106340-10g	10g	In stock	$9.90
Z106340-25g	25g	In stock	$16.90
Z106340-100g	100g	In stock	$46.90
Z106340-500g	500g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$163.90

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Element classified compounds Transition metal compounds

Basic Description

Synonyms	Zirconium(IV) Propoxide \| 23519-77-9 \| Zirconium tetrapropanolate \| 1-Propanol, zirconium(4+) salt \| zirconium propoxide \| Propyl alcohol, zirconium(4+) salt \| Tetrapropyl zirconate \| propan-1-olate;zirconium(4+) \| A7Z4N4E80X \| UNII-A7Z4N4E80X \| EINECS 245-711-9 \| PROPYL ZIRCO
Specifications & Purity	70 wt. % in n-propanol
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Application Zirconium(IV) n-propoxide is used as a precursor in the production of zirconia. It is also used to study the thermophysical properties like thermal conductivity and thermal effusivity of hybrid films and thereby adjusting optic properties of the films.

Names and Identifiers

IUPAC Name	propan-1-olate;zirconium(4+)
INCHI	InChI=1S/4C3H7O.Zr/c41-2-3-4;/h42-3H2,1H3;/q4*-1;+4
InChi Key	XPGAWFIWCWKDDL-UHFFFAOYSA-N
Canonical SMILES	CCC[O-].CCC[O-].CCC[O-].CCC[O-].[Zr+4]
Isomeric SMILES	CCC[O-].CCC[O-].CCC[O-].CCC[O-].[Zr+4]
WGK Germany	3
PubChem CID	90139
UN Number	1993
Packing Group	I
Molecular Weight	327.57
Beilstein	3679533
Reaxy-Rn	3935210

Certificates

Certificate of Analysis(COA)

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35 results found

Lot Number	Certificate Type	Date	Item
H2419465	Certificate of Analysis	Aug 10, 2024	Z106340
H2419464	Certificate of Analysis	Aug 10, 2024	Z106340
E2413503	Certificate of Analysis	Apr 23, 2024	Z106340
E2413516	Certificate of Analysis	Apr 23, 2024	Z106340
E2413517	Certificate of Analysis	Apr 23, 2024	Z106340
E2413518	Certificate of Analysis	Apr 23, 2024	Z106340
F2428063	Certificate of Analysis	Apr 23, 2024	Z106340
G2429018	Certificate of Analysis	Apr 23, 2024	Z106340
G2429036	Certificate of Analysis	Apr 23, 2024	Z106340
B2428304	Certificate of Analysis	Feb 01, 2024	Z106340
B2428303	Certificate of Analysis	Feb 01, 2024	Z106340
B2428302	Certificate of Analysis	Feb 01, 2024	Z106340
B2428301	Certificate of Analysis	Feb 01, 2024	Z106340
H2328623	Certificate of Analysis	Aug 18, 2023	Z106340
H2328625	Certificate of Analysis	Aug 18, 2023	Z106340
H2328626	Certificate of Analysis	Aug 18, 2023	Z106340
A2411044	Certificate of Analysis	Aug 18, 2023	Z106340
C2308282	Certificate of Analysis	Feb 18, 2023	Z106340
C2308281	Certificate of Analysis	Feb 18, 2023	Z106340
C2308277	Certificate of Analysis	Feb 18, 2023	Z106340
C2308275	Certificate of Analysis	Feb 18, 2023	Z106340
H2229531	Certificate of Analysis	Jul 16, 2022	Z106340
A2309417	Certificate of Analysis	Jul 16, 2022	Z106340
H2229749	Certificate of Analysis	Jul 16, 2022	Z106340
H2229533	Certificate of Analysis	Jul 16, 2022	Z106340
H2229532	Certificate of Analysis	Jul 16, 2022	Z106340
H2229530	Certificate of Analysis	Jul 16, 2022	Z106340
E2210158	Certificate of Analysis	Jan 20, 2022	Z106340
E2210151	Certificate of Analysis	Jan 20, 2022	Z106340
E2210153	Certificate of Analysis	Jan 20, 2022	Z106340
C2202285	Certificate of Analysis	Jan 20, 2022	Z106340
C2202281	Certificate of Analysis	Jan 20, 2022	Z106340
C2202280	Certificate of Analysis	Jan 20, 2022	Z106340
C2202274	Certificate of Analysis	Jan 20, 2022	Z106340
E2210154	Certificate of Analysis	Jan 20, 2022	Z106340

Chemical and Physical Properties

Solubility	Soluble in alcohol, toluene
Sensitivity	Moisture sensitive.
Refractive Index	1.451
Flash Point(°F)	83°F
Flash Point(°C)	28℃
Boil Point(°C)	208°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS07, GHS02
Signal	Danger
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H318:Causes serious eye damage H336:May cause drowsiness or dizziness H226:Flammable liquid and vapor
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	3
Reaxy-Rn	3935210
Class	3

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Citations of This Product

1. Zhen Xu, Fan Wu, Kai Pan, Yalong Liao, Fei Wang, Longdi Cheng, Jianyong Yu, Yi-Tao Liu, Bin Ding. (2024) Ceramic aerogels constructed from dense, non-porous ceramic nanofibers with robust and elastic properties up to 1300 °C. CERAMICS INTERNATIONAL, 50 (6381). [PMID:16467868]
2. Xiaoxia Ye, Rixin Huang, Zhihong Zheng, Juan Liu, Jie Chen, Yuancai Lv. (2023) Anti-abrasion collagen fiber-based membrane functionalized by UiO-66-NH2 with ultra-high efficiency and stability for oil-in-water emulsions separation. CHINESE JOURNAL OF CHEMICAL ENGINEERING, [PMID:10854409]
3. Jing Jiang, Xueyu Yuan, Xi He, Shengjie Guan, Qian Wu, Ming Liu, Li Liu, Yudong Huang. (2023) Effects of cross-linking degree and steric hindrance on the thermal degradation behavior of novel hybrid zirconium-silicone resin. POLYMER, 284 (126306). [PMID:]
4. Jian-Li Chen, Xiao-Hui Jia, Xinyue Xia, Xuan Wu, Yan-Neng Xu, Gang Yuan, Ze-Yun Gu, Kathy Qian Luo, Ming-Heng Yuan, Ruibin Jiang, Jianfang Wang, Xiao-Ming Zhu. (2023) Codelivery of vorinostat and chloroquine by autophagy-inhibitory hollow ZrO2 nanoshells for synergistic combination chemotherapy. CHEMICAL ENGINEERING JOURNAL, 471 (144740). [PMID:]
5. Zhuoli Xu, Fuping Li, Yan Zhang, Sixuan Zhang, Kang Zhao, Yufei Tang. (2023) Ultralight ZrB2/ZrC nanofiber aerogels with excellent elasticity and ultra-low thermal conductivity. MATERIALS LETTERS, 344 (134393). [PMID:]
6. Di Zhang, Hongli Hu, Ji-an Wei, Xin Xu, Lei Chen, Xiaohui Wu, Qianqian Yu, Bo-xing Zhang, LinGe Wang. (2023) Zr-doped TiO2 ceramic nanofibrous membranes for enhancing photocatalytic organic pollutants degradation and antibacterial activity. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 665 (131231). [PMID:]
7. Jinfeng Tian, Liwei Yan, Hao Zhang, Yuan Wang, Yuanbo Cai, Yisen Huang, Zhaohui Lu, Shuang Xia, Yang Chen, Zhengguang Heng, Huawei Zou, Mei Liang. (2023) Enhanced flexibility and ablative performance of silicone rubber by constructing an interpenetrating zirconium-containing polysiloxane double network. POLYMER, 270 (125749). [PMID:]
8. Bohan Wang, Wenjun Yu, Le Fu. (2023) Bioactive porous ZrO2-based ceramics with a hierarchical porosity for artificial bone scaffolds. CERAMICS INTERNATIONAL, 49 (13752). [PMID:]
9. Le Fu, Bohan Wang, Ying Deng, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia. (2022) Liquid-phase sintering of ZrO2-based nanocrystalline glass–ceramics achieved by multielement co-doping. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 106 (4): (2702-2715). [PMID:]
10. Shuai Wang, Leilei Song, Shengkai Liu, Xiaoyuan Pei, Yufen Zhao, Chunying Min, Ruiqi Shao, Tianshuai Ma, Yue Yin, Zhiwei Xu, Chunhong Wang. (2023) Metal-organic framework nanoparticles as a free radical scavenger improving the stability of epoxy under high dose gamma irradiation. POLYMER DEGRADATION AND STABILITY, 207 (110231). [PMID:]
11. Rui Huang, Hongye Wang, Cheng Tao, Hua Hao, Zhonghua Yao, Hanxing Liu, Minghe Cao. (2023) Multivariant Me ions design of Bi(Ni0.5Zr0.5)O3 amorphous thin film with high energy storage capability. SCRIPTA MATERIALIA, 226 (115194). [PMID:]
12. Wei-Lian Xie, Xiao-Min Li, Jiao-Min Lin, Long-zhang Dong, Yu Chen, Ning Li, Jing-Wen Shi, Jing-Jing Liu, Jiang Liu, Shun-Li Li, Ya-Qian Lan. (2022) Keeping Superprotonic Conductivity over a Wide Temperature Region via Sulfate Hopping Sites-Decorated Zirconium-Oxo Clusters. Small, 18 (48): (2205444). [PMID:36284496]
13. Le Fu, Lei Li, Yongxin Cheng, Bohan Wang, Hui Wu. (2022) Influences of powder morphology on the densification and microstructure of a ZrO2-based nanocrystalline glass–ceramic. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 106 (1): (722-737). [PMID:]
14. Rui Huang, Hongye Wang, Cheng Tao, Hua Hao, Zhonghua Yao, Hanxing Liu, Minghe Cao. (2022) Synergistic Optimization in a 0.90BaTiO3–0.08Bi(Ni0.5Zr0.5)O3–0.02BiFeO3 Thin Film with High Breakdown Strength and Energy Density. ACS Sustainable Chemistry & Engineering, 10 (33): (11041–11049). [PMID:]
15. Le Fu, Bohan Wang, Wei Xia. (2022) New insights into the formation mechanism of zircon in a ZrO2–SiO2 nanocrystalline glass-ceramic: A TEM study. CERAMICS INTERNATIONAL, 48 (27097). [PMID:]
16. Jing Jiang, Xueyu Yuan, Kangle Xue, Ming Liu, Yudong Huang, Li Liu. (2022) Novel hybrid zirconium-silicone resin as high-temperature adhesive and an insight into the thermal resistance mechanism. CHEMICAL ENGINEERING JOURNAL, 446 (137350). [PMID:]
17. Hu Hongli, Xu Xin, Wang Yingying, Zhang Bo-xing. (2022) Fabricating porous monolithic ceramic materials via phase separations in solutions of poly(Vinyl alcohol) and sol nanoparticles. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 103 (2): (584-594). [PMID:]
18. Bohan Wang, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia, Le Fu. (2022) Effects of dopants with various valences on densification behavior and phase composition of a ZrO2–SiO2 nanocrystalline glass-ceramic. CERAMICS INTERNATIONAL, 48 (9495). [PMID:]
19. Le Fu, Fuqing Jiang, Bo Li, Yongxin Cheng, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia. (2022) Doping of tantalum, niobium, and hafnium in a translucent ZrO2-SiO2 nanocrystalline glass-ceramic. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 42 (1731). [PMID:]
20. Xiaomin Huang, Qinghao Qin, Xueqing Wang, Huijing Xiang, Jinlong Zheng, Yin Lu, Chaojie Lv, Kaili Wu, Lixia Yan, Ning Wang, Cao Xia, Zhong Lin Wang. (2021) Piezoelectric Nanogenerator for Highly Sensitive and Synchronous Multi-Stimuli Sensing. ACS Nano, 15 (12): (19783–19792). [PMID:34797042]
21. Xueli Luo, Gengli Huang, Xiaokai Chen, Jie Guo, Weixia Yang, Wenzhi Tang, Tianli Yue, Zhonghong Li. (2021) Ingenious ambient temperature fabrication zirconium-metal organic framework laden polysaccharide aerogel as an efficient glyphosate scavenger. Journal of Environmental Chemical Engineering, 9 (106808). [PMID:]
22. Changhao Yan, Shouteng Zheng, Na Chen, Shouqi Yuan, Yao Chen, Bing Li, Yunlei Zhang. (2021) Sulfated zirconia catalysts supported on mesoporous Mg-SBA-15 with different morphologies for highly efficient conversion of fructose to 5-hydroxymethylfurfural. MICROPOROUS AND MESOPOROUS MATERIALS, 328 (111507). [PMID:]

References

1. Yuelong Fu, Zhangwei Chen, Gang Xu, Yen Wei, Changshi Lao. (2019) Preparation and stereolithography 3D printing of ultralight and ultrastrong ZrOC porous ceramics. Journal of Alloys and Compounds, (789): (867-873). [PMID:]
2. Zhen Xu, Fan Wu, Kai Pan, Yalong Liao, Fei Wang, Longdi Cheng, Jianyong Yu, Yi-Tao Liu, Bin Ding. (2024) Ceramic aerogels constructed from dense, non-porous ceramic nanofibers with robust and elastic properties up to 1300 °C. CERAMICS INTERNATIONAL, 50 (6381). [PMID:16467868]
3. Xiaoxia Ye, Rixin Huang, Zhihong Zheng, Juan Liu, Jie Chen, Yuancai Lv. (2023) Anti-abrasion collagen fiber-based membrane functionalized by UiO-66-NH2 with ultra-high efficiency and stability for oil-in-water emulsions separation. CHINESE JOURNAL OF CHEMICAL ENGINEERING, [PMID:10854409]
4. Jing Jiang, Xueyu Yuan, Xi He, Shengjie Guan, Qian Wu, Ming Liu, Li Liu, Yudong Huang. (2023) Effects of cross-linking degree and steric hindrance on the thermal degradation behavior of novel hybrid zirconium-silicone resin. POLYMER, 284 (126306). [PMID:]
5. Jian-Li Chen, Xiao-Hui Jia, Xinyue Xia, Xuan Wu, Yan-Neng Xu, Gang Yuan, Ze-Yun Gu, Kathy Qian Luo, Ming-Heng Yuan, Ruibin Jiang, Jianfang Wang, Xiao-Ming Zhu. (2023) Codelivery of vorinostat and chloroquine by autophagy-inhibitory hollow ZrO2 nanoshells for synergistic combination chemotherapy. CHEMICAL ENGINEERING JOURNAL, 471 (144740). [PMID:]
6. Zhuoli Xu, Fuping Li, Yan Zhang, Sixuan Zhang, Kang Zhao, Yufei Tang. (2023) Ultralight ZrB2/ZrC nanofiber aerogels with excellent elasticity and ultra-low thermal conductivity. MATERIALS LETTERS, 344 (134393). [PMID:]
7. Di Zhang, Hongli Hu, Ji-an Wei, Xin Xu, Lei Chen, Xiaohui Wu, Qianqian Yu, Bo-xing Zhang, LinGe Wang. (2023) Zr-doped TiO2 ceramic nanofibrous membranes for enhancing photocatalytic organic pollutants degradation and antibacterial activity. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 665 (131231). [PMID:]
8. Jinfeng Tian, Liwei Yan, Hao Zhang, Yuan Wang, Yuanbo Cai, Yisen Huang, Zhaohui Lu, Shuang Xia, Yang Chen, Zhengguang Heng, Huawei Zou, Mei Liang. (2023) Enhanced flexibility and ablative performance of silicone rubber by constructing an interpenetrating zirconium-containing polysiloxane double network. POLYMER, 270 (125749). [PMID:]
9. Bohan Wang, Wenjun Yu, Le Fu. (2023) Bioactive porous ZrO2-based ceramics with a hierarchical porosity for artificial bone scaffolds. CERAMICS INTERNATIONAL, 49 (13752). [PMID:]
10. Le Fu, Bohan Wang, Ying Deng, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia. (2022) Liquid-phase sintering of ZrO2-based nanocrystalline glass–ceramics achieved by multielement co-doping. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 106 (4): (2702-2715). [PMID:]
11. Shuai Wang, Leilei Song, Shengkai Liu, Xiaoyuan Pei, Yufen Zhao, Chunying Min, Ruiqi Shao, Tianshuai Ma, Yue Yin, Zhiwei Xu, Chunhong Wang. (2023) Metal-organic framework nanoparticles as a free radical scavenger improving the stability of epoxy under high dose gamma irradiation. POLYMER DEGRADATION AND STABILITY, 207 (110231). [PMID:]
12. Rui Huang, Hongye Wang, Cheng Tao, Hua Hao, Zhonghua Yao, Hanxing Liu, Minghe Cao. (2023) Multivariant Me ions design of Bi(Ni0.5Zr0.5)O3 amorphous thin film with high energy storage capability. SCRIPTA MATERIALIA, 226 (115194). [PMID:]
13. Wei-Lian Xie, Xiao-Min Li, Jiao-Min Lin, Long-zhang Dong, Yu Chen, Ning Li, Jing-Wen Shi, Jing-Jing Liu, Jiang Liu, Shun-Li Li, Ya-Qian Lan. (2022) Keeping Superprotonic Conductivity over a Wide Temperature Region via Sulfate Hopping Sites-Decorated Zirconium-Oxo Clusters. Small, 18 (48): (2205444). [PMID:36284496]
14. Le Fu, Lei Li, Yongxin Cheng, Bohan Wang, Hui Wu. (2022) Influences of powder morphology on the densification and microstructure of a ZrO2-based nanocrystalline glass–ceramic. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 106 (1): (722-737). [PMID:]
15. Rui Huang, Hongye Wang, Cheng Tao, Hua Hao, Zhonghua Yao, Hanxing Liu, Minghe Cao. (2022) Synergistic Optimization in a 0.90BaTiO3–0.08Bi(Ni0.5Zr0.5)O3–0.02BiFeO3 Thin Film with High Breakdown Strength and Energy Density. ACS Sustainable Chemistry & Engineering, 10 (33): (11041–11049). [PMID:]
16. Le Fu, Bohan Wang, Wei Xia. (2022) New insights into the formation mechanism of zircon in a ZrO2–SiO2 nanocrystalline glass-ceramic: A TEM study. CERAMICS INTERNATIONAL, 48 (27097). [PMID:]
17. Jing Jiang, Xueyu Yuan, Kangle Xue, Ming Liu, Yudong Huang, Li Liu. (2022) Novel hybrid zirconium-silicone resin as high-temperature adhesive and an insight into the thermal resistance mechanism. CHEMICAL ENGINEERING JOURNAL, 446 (137350). [PMID:]
18. Hu Hongli, Xu Xin, Wang Yingying, Zhang Bo-xing. (2022) Fabricating porous monolithic ceramic materials via phase separations in solutions of poly(Vinyl alcohol) and sol nanoparticles. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 103 (2): (584-594). [PMID:]
19. Bohan Wang, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia, Le Fu. (2022) Effects of dopants with various valences on densification behavior and phase composition of a ZrO2–SiO2 nanocrystalline glass-ceramic. CERAMICS INTERNATIONAL, 48 (9495). [PMID:]
20. Le Fu, Fuqing Jiang, Bo Li, Yongxin Cheng, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia. (2022) Doping of tantalum, niobium, and hafnium in a translucent ZrO2-SiO2 nanocrystalline glass-ceramic. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 42 (1731). [PMID:]
21. Xiaomin Huang, Qinghao Qin, Xueqing Wang, Huijing Xiang, Jinlong Zheng, Yin Lu, Chaojie Lv, Kaili Wu, Lixia Yan, Ning Wang, Cao Xia, Zhong Lin Wang. (2021) Piezoelectric Nanogenerator for Highly Sensitive and Synchronous Multi-Stimuli Sensing. ACS Nano, 15 (12): (19783–19792). [PMID:34797042]
22. Xueli Luo, Gengli Huang, Xiaokai Chen, Jie Guo, Weixia Yang, Wenzhi Tang, Tianli Yue, Zhonghong Li. (2021) Ingenious ambient temperature fabrication zirconium-metal organic framework laden polysaccharide aerogel as an efficient glyphosate scavenger. Journal of Environmental Chemical Engineering, 9 (106808). [PMID:]
23. Changhao Yan, Shouteng Zheng, Na Chen, Shouqi Yuan, Yao Chen, Bing Li, Yunlei Zhang. (2021) Sulfated zirconia catalysts supported on mesoporous Mg-SBA-15 with different morphologies for highly efficient conversion of fructose to 5-hydroxymethylfurfural. MICROPOROUS AND MESOPOROUS MATERIALS, 328 (111507). [PMID:]

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