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Zirconocene chloride hydride - 95%, high purity , CAS No.37342-97-5

≥95%

CAS#: 37342-97-5
Formula: C₁₀H₁₁ClZr
Molecular Weight: 257.87
EC Number: 253-479-5
MDL number: MFCD02089401
PubChem CID: 53384630

Item Number

Z103200

Grouped product items
SKU	Size	Availability	Price
Z103200-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$25.90
Z103200-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$77.90
Z103200-25g	25g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$313.90

View related series

Element classified compounds Reduction reaction

Basic Description

Synonyms	Bis(cyclopentadienyl)zirconium Chloride hydride \| 37342-97-5 \| Schwartz's Reagent \| Zirconocene chloride hydride \| cyclopenta-1,3-diene;hydride;zirconium(4+);chloride \| Bis(cyclopentadienyl)zirconium(IV) chloride hydride \| UPZRXMLKDSCYCP-UHFFFAOYSA-M \| MFCD02089401 \| SC1
Specifications & Purity	95%
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	Reagent for the functionalization of olefins and alkynes;Conversion of amides to aldehydes.

Names and Identifiers

IUPAC Name	cyclopenta-1,3-diene;hydride;zirconium(4+);chloride
INCHI	InChI=1S/2C5H5.ClH.Zr.H/c21-2-4-5-3-1;;;/h21-5H;1H;;/q2*-1;;+4;-1/p-1
InChi Key	NKIVVMOIGINFTB-UHFFFAOYSA-M
Canonical SMILES	[H-].[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Zr+4]
Isomeric SMILES	[H-].[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Zr+4]
WGK Germany	3
PubChem CID	53384630
UN Number	3131
Molecular Weight	257.87

Certificates

Certificate of Analysis(COA)

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2 results found

Lot Number	Certificate Type	Date	Item
I1506143	Certificate of Analysis	Mar 08, 2024	Z103200
D2318463	Certificate of Analysis	Apr 23, 2023	Z103200

Sensitivity

Moisture & Light & Air & Heat sensitive

Melt Point(°C)

300°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS02
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H228:Flammable solid H261:In contact with water releases flammable gas
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas/... Protect from moisture. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P402+P404:Store in a dry place. Store in a closed container. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3
Merck Index	8396

References

1. Jared T Spletstoser,Jonathan M White,Ashok Rao Tunoori,Gunda I Georg. (2007-02-24) Mild and selective hydrozirconation of amides to aldehydes using Cp2Zr(H)Cl: scope and mechanistic insight.. Journal of the American Chemical Society, 129 ((11)): (3408-3419). [PMID:17315870]
2. Bruce Ganem,Roland R Franke. (2007-03-27) Paclitaxel from primary taxanes: a perspective on creative invention in organozirconium chemistry.. The Journal of organic chemistry, 72 ((11)): (3981-3987). [PMID:17381159]

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