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Zirconocene chloride hydride - 95%, high purity , CAS No.37342-97-5

≥95%

CAS#: 37342-97-5
Formula: C₁₀H₁₁ClZr
Molecular Weight: 257.87
EC Number: 253-479-5
MDL number: MFCD02089401
PubChem CID: 53384630

Item Number

Z103200

Grouped product items
SKU	Size	Availability	Price
Z103200-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$25.90
Z103200-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$77.90
Z103200-25g	25g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$313.90

View related series

Element classified compounds Reduction reaction

Basic Description

Synonyms	MFCD02089401 \| cyclopenta-1,3-diene;hydride;zirconium(4+);chloride \| Bis(cyclopentadienyl)zirconium (IV) chloride hydride \| Z0010 \| Bis(cyclopentadienyl)zirconium(IV) chloride hydride \| Bis(cyclopentadienyl)zirconium Chloride hydride \| SC10902 \| Zirconoce
Specifications & Purity	≥95%
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	Reagent for the functionalization of olefins and alkynes;Conversion of amides to aldehydes.

Names and Identifiers

IUPAC Name	cyclopenta-1,3-diene;hydride;zirconium(4+);chloride
INCHI	InChI=1S/2C5H5.ClH.Zr.H/c21-2-4-5-3-1;;;/h21-5H;1H;;/q2*-1;;+4;-1/p-1
InChi Key	NKIVVMOIGINFTB-UHFFFAOYSA-M
Canonical SMILES	[H-].[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Zr+4]
Isomeric SMILES	[H-].[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Zr+4]
WGK Germany	3
PubChem CID	53384630
UN Number	3131
Molecular Weight	257.87

Certificates

Certificate of Analysis(COA)

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4 results found

Lot Number	Certificate Type	Date	Item
I2409336	Certificate of Analysis	Jun 22, 2024	Z103200
I2409337	Certificate of Analysis	Jun 22, 2024	Z103200
I1506143	Certificate of Analysis	Mar 08, 2024	Z103200
D2318463	Certificate of Analysis	Apr 23, 2023	Z103200

Sensitivity

Moisture & Light & Air & Heat sensitive

Melt Point(°C)

300°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS02
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H228:Flammable solid H261:In contact with water releases flammable gas
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas/... Protect from moisture. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P402+P404:Store in a dry place. Store in a closed container. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	3
Merck Index	8396

References

1. Jared T Spletstoser,Jonathan M White,Ashok Rao Tunoori,Gunda I Georg. (2007-02-24) Mild and selective hydrozirconation of amides to aldehydes using Cp2Zr(H)Cl: scope and mechanistic insight.. Journal of the American Chemical Society, 129 ((11)): (3408-3419). [PMID:17315870]
2. Bruce Ganem,Roland R Franke. (2007-03-27) Paclitaxel from primary taxanes: a perspective on creative invention in organozirconium chemistry.. The Journal of organic chemistry, 72 ((11)): (3981-3987). [PMID:17381159]

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