Zirconocene dichloride - 98%, high purity , CAS No.1291-32-3

  • ≥98%
Item Number
B124559
Grouped product items
SKUSizeAvailabilityPrice Qty
B124559-1g
1g
In stock
$9.90
B124559-5g
5g
In stock
$29.90
B124559-25g
25g
In stock
$90.90
B124559-100g
100g
In stock
$273.90

Basic Description

SynonymsBis(cyclopentadienyl)zirconium Dichloride
Specifications & Purity≥98%
Storage TempArgon charged
Shipped InNormal
Product Description

Useful in the synthesis of a wide range of early-transition-metal complexes and organometallic compounds. Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Names and Identifiers

Isomeric SMILES C1C=CC=[C-]1.[CH-]1C=CC=C1.Cl[Zr+2]Cl
WGK Germany 3
RTECS ZH7525000
PubChem CID 22833502
UN Number 3261
Packing Group I
Molecular Weight 292.31

Certificates

Certificate of Analysis(COA)

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21 results found

Lot NumberCertificate TypeDateItem
D2401016Certificate of AnalysisFeb 29, 2024 B124559
F2401112Certificate of AnalysisFeb 29, 2024 B124559
F2401081Certificate of AnalysisFeb 29, 2024 B124559
F2401099Certificate of AnalysisFeb 29, 2024 B124559
K2322302Certificate of AnalysisNov 03, 2023 B124559
K2322299Certificate of AnalysisNov 03, 2023 B124559
K2322298Certificate of AnalysisNov 03, 2023 B124559
K2322297Certificate of AnalysisNov 03, 2023 B124559
D1918015Certificate of AnalysisFeb 08, 2023 B124559
H2308255Certificate of AnalysisJul 12, 2022 B124559
J2227173Certificate of AnalysisJul 12, 2022 B124559
J2227174Certificate of AnalysisJul 12, 2022 B124559
J2227177Certificate of AnalysisJul 12, 2022 B124559
J2227178Certificate of AnalysisJul 12, 2022 B124559
H1830140Certificate of AnalysisJul 08, 2022 B124559
H1830139Certificate of AnalysisJul 08, 2022 B124559
F2209284Certificate of AnalysisMar 27, 2022 B124559
F2209264Certificate of AnalysisMar 27, 2022 B124559
F2209253Certificate of AnalysisMar 27, 2022 B124559
F2209166Certificate of AnalysisMar 27, 2022 B124559
D1402050Certificate of AnalysisFeb 18, 2022 B124559

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Chemical and Physical Properties

SolubilityIt is soluble in water.
SensitivityMoisture sensitive;Air sensitive
Boil Point(°C)124-125°/15mm
Melt Point(°C)242-245°C

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS07
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H290:May be corrosive to metals

H302+H312+H332:Harmful if swallowed, in contact with skin or if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

WGK Germany 3
RTECS ZH7525000
Class 8

Related Documents

Citations of This Product

1. Qian Wang, Xu Li, Jinxiang Dong.  (2023)  Synthesis and surface properties of branched-chain tertiary fatty alcohol sulfate surfactants.  TENSIDE SURFACTANTS DETERGENTS,  60  (6): (569-587).  [PMID:12386158] [10.1515/tsd-2023-2534]
2. Juan Zhu, Shuang-Bao Li, Bao-Xu Jiang, Yu-Teng Zhang.  (2023)  Incorporation of Zr-based metal-organic polyhedron into the PDA/PVDF adsorptive membrane for rapid removal of Cr(VI).  APPLIED SURFACE SCIENCE,  640  (158331).  [PMID:] [10.1016/j.apsusc.2023.158331]
3. Jing Gao, Jinghua Hao, Yuan Gao, Xiaolin Sun, Yuan Zhang, Depeng Song, Qing Zhao, Fuhua Zhao, Wenyan Si, Kun Wang, Takeo Ohsaka, Futoshi Matsumoto, Jianfei Wu, Haijiao Xie.  (2023)  Scalable wet-slurry fabrication of sheet-type electrodes for sulfide all-solid-state batteries and performance enhancement via optimization of Ni-rich cathode coating layer.  eTransportation,  17  (100252).  [PMID:] [10.1016/j.etran.2023.100252]
4. Yang Lyu, Yuan Cheng, Guangdong Zhao, Mengyu Wang, Guiqing Chen, Xinghong Zhang, Wenbo Han.  (2023)  Modification of SiBCN by Zr atom and its effect on ablative resistance of Cf/SiBCN(Zr) composites.  COMPOSITES PART B-ENGINEERING,  253  (110511).  [PMID:] [10.1016/j.compositesb.2023.110511]
5. Xu Li, Jiaqi Li, Xiaohong Wang, Lijun Yang, Hong Xu, Jinxiang Dong.  (2023)  Novel branched-chain sulfonate surfactants based on α-olefins from Fischer–Tropsch synthesis via reaction-separation-utilization integrated process.  FUEL,  339  (126961).  [PMID:] [10.1016/j.fuel.2022.126961]
6. Yanghuan Huang, Haocheng Zhang, Lou Gao, Tianlan Yan, Yueer Yan, Yahong Zhang, Yi Tang.  (2022)  Direct grafting synthesis of bi-functional Zr–Al-MWW zeolites and their catalytic characteristics in Lewis-Brønsted cascade reaction.  MICROPOROUS AND MESOPOROUS MATERIALS,  341  (112110).  [PMID:] [10.1016/j.micromeso.2022.112110]
7. Fuwen Tan, Xu Li, Jinxiang Dong.  (2022)  Synthesis of alkylbenzenes via the alkylation of benzene using α-olefin dimers and the surfactant properties of their sulfonates.  TENSIDE SURFACTANTS DETERGENTS,  59  (1): (39-50).  [PMID:] [10.1515/tsd-2021-2371]
8. He Huang, Zhao-Yang Liu, Shuang-Bao Li, Juan Zhu, Bao-Xu Jiang, Yu-Teng Zhang.  (2022)  Amino-functionalized Zr (IV) metal-organic polyhedron as water-stable catalyst for the photocatalytic degradation of tetracycline.  JOURNAL OF SOLID STATE CHEMISTRY,  307  (122821).  [PMID:] [10.1016/j.jssc.2021.122821]
9. Bin-Cheng Wang, Zhi-Ying Feng, Biao-Biao Hao, Chen-Xi Zhang, Qing-Lun Wang.  (2021)  Promotion of Proton Conductivity by Encapsulation of Metal-Organic Polyhedra in Metal-Organic Frameworks.  CHEMISTRY-A EUROPEAN JOURNAL,  27  (47): (12137-12143).  [PMID:34164856] [10.1002/chem.202101213]
10. Yirong Feng, Jie Wang, Haomiao Zhang, Jingdai Wang, Yongrong Yang.  (2021)  A 3D-printed continuous flow platform for the synthesis of methylaluminoxane.  GREEN CHEMISTRY,  23  (11): (4087-4094).  [PMID:] [10.1039/D1GC01015H]
11. Shujie Liang, Xiaohui Zhong, Zuqi Zhong, Bin Han, Weiyi Chen, Kainan Song, Hong Deng, Zhang Lin.  (2021)  Biomimetic inspired porphyrin-based nanoframes for highly efficient photocatalytic CO2 reduction.  CHEMICAL ENGINEERING JOURNAL,  411  (128414).  [PMID:] [10.1016/j.cej.2021.128414]

References

1. Qian Wang, Xu Li, Jinxiang Dong.  (2023)  Synthesis and surface properties of branched-chain tertiary fatty alcohol sulfate surfactants.  TENSIDE SURFACTANTS DETERGENTS,  60  (6): (569-587).  [PMID:12386158] [10.1515/tsd-2023-2534]
2. Juan Zhu, Shuang-Bao Li, Bao-Xu Jiang, Yu-Teng Zhang.  (2023)  Incorporation of Zr-based metal-organic polyhedron into the PDA/PVDF adsorptive membrane for rapid removal of Cr(VI).  APPLIED SURFACE SCIENCE,  640  (158331).  [PMID:] [10.1016/j.apsusc.2023.158331]
3. Jing Gao, Jinghua Hao, Yuan Gao, Xiaolin Sun, Yuan Zhang, Depeng Song, Qing Zhao, Fuhua Zhao, Wenyan Si, Kun Wang, Takeo Ohsaka, Futoshi Matsumoto, Jianfei Wu, Haijiao Xie.  (2023)  Scalable wet-slurry fabrication of sheet-type electrodes for sulfide all-solid-state batteries and performance enhancement via optimization of Ni-rich cathode coating layer.  eTransportation,  17  (100252).  [PMID:] [10.1016/j.etran.2023.100252]
4. Yang Lyu, Yuan Cheng, Guangdong Zhao, Mengyu Wang, Guiqing Chen, Xinghong Zhang, Wenbo Han.  (2023)  Modification of SiBCN by Zr atom and its effect on ablative resistance of Cf/SiBCN(Zr) composites.  COMPOSITES PART B-ENGINEERING,  253  (110511).  [PMID:] [10.1016/j.compositesb.2023.110511]
5. Xu Li, Jiaqi Li, Xiaohong Wang, Lijun Yang, Hong Xu, Jinxiang Dong.  (2023)  Novel branched-chain sulfonate surfactants based on α-olefins from Fischer–Tropsch synthesis via reaction-separation-utilization integrated process.  FUEL,  339  (126961).  [PMID:] [10.1016/j.fuel.2022.126961]
6. Yanghuan Huang, Haocheng Zhang, Lou Gao, Tianlan Yan, Yueer Yan, Yahong Zhang, Yi Tang.  (2022)  Direct grafting synthesis of bi-functional Zr–Al-MWW zeolites and their catalytic characteristics in Lewis-Brønsted cascade reaction.  MICROPOROUS AND MESOPOROUS MATERIALS,  341  (112110).  [PMID:] [10.1016/j.micromeso.2022.112110]
7. Fuwen Tan, Xu Li, Jinxiang Dong.  (2022)  Synthesis of alkylbenzenes via the alkylation of benzene using α-olefin dimers and the surfactant properties of their sulfonates.  TENSIDE SURFACTANTS DETERGENTS,  59  (1): (39-50).  [PMID:] [10.1515/tsd-2021-2371]
8. He Huang, Zhao-Yang Liu, Shuang-Bao Li, Juan Zhu, Bao-Xu Jiang, Yu-Teng Zhang.  (2022)  Amino-functionalized Zr (IV) metal-organic polyhedron as water-stable catalyst for the photocatalytic degradation of tetracycline.  JOURNAL OF SOLID STATE CHEMISTRY,  307  (122821).  [PMID:] [10.1016/j.jssc.2021.122821]
9. Bin-Cheng Wang, Zhi-Ying Feng, Biao-Biao Hao, Chen-Xi Zhang, Qing-Lun Wang.  (2021)  Promotion of Proton Conductivity by Encapsulation of Metal-Organic Polyhedra in Metal-Organic Frameworks.  CHEMISTRY-A EUROPEAN JOURNAL,  27  (47): (12137-12143).  [PMID:34164856] [10.1002/chem.202101213]
10. Yirong Feng, Jie Wang, Haomiao Zhang, Jingdai Wang, Yongrong Yang.  (2021)  A 3D-printed continuous flow platform for the synthesis of methylaluminoxane.  GREEN CHEMISTRY,  23  (11): (4087-4094).  [PMID:] [10.1039/D1GC01015H]
11. Shujie Liang, Xiaohui Zhong, Zuqi Zhong, Bin Han, Weiyi Chen, Kainan Song, Hong Deng, Zhang Lin.  (2021)  Biomimetic inspired porphyrin-based nanoframes for highly efficient photocatalytic CO2 reduction.  CHEMICAL ENGINEERING JOURNAL,  411  (128414).  [PMID:] [10.1016/j.cej.2021.128414]

Solution Calculators