Butyltriphenylphosphonium bromide - 98%, high purity , CAS No.1779-51-7

  • ≥98%
Item Number
B107826
Grouped product items
SKUSizeAvailabilityPrice Qty
B107826-25g
25g
In stock
$23.90
B107826-100g
100g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$85.90
B107826-250g
250g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$175.90
B107826-500g
500g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$316.90

Basic Description

SynonymsTBP | Q-200774 | (1-BUTYL)TRIPHENYLPHOSPHONIUM BROMIDE;BUTYL TRIPHENYL PHOSPHINE BROMIDE;BUTYL TRIPHENYL PHOSPHOROUS BROMIDE;BUTYLTRIPHENYLPHOSPHONIUM BROMIDE;N-BUTYLTRIPHENYLPHOSPHONIUM BROMIDE;TBP | butyl(triphenyl)phosphonium bromide | NSC59684 | Phosp
Specifications & Purity≥98%
Storage TempArgon charged
Shipped InNormal
Product Description

Reactant for: Free radical 5-exo-dig cyclization Intramolecular hydroacylalkoxylation Wittig reactions for stereoselective synthesis of alkenes Dimerization of α-olefins Alkylidenation of hydrazides for synthesis of indoles Tandem cyclization and 1,2-thiolate shift of nitrogen ylides

Associated Targets(Human)

MCF-10A (2462 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
MCF7 (126967 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
SK-BR-3 (5175 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Mechanisms of Action

Mechanism of ActionAction Typetarget IDTarget NameTarget TypeTarget OrganismBinding Site NameReferences

Names and Identifiers

Pubchem Sid488188297
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488188297
IUPAC Name butyl(triphenyl)phosphanium;bromide
INCHI InChI=1S/C22H24P.BrH/c1-2-3-19-23(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,2-3,19H2,1H3;1H/q+1;/p-1
InChi Key IKWKJIWDLVYZIY-UHFFFAOYSA-M
Canonical SMILES CCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
Isomeric SMILES CCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
WGK Germany 3
RTECS TA1855200
PubChem CID 159628
Molecular Weight 399.3
Beilstein 3580224
Reaxy-Rn 3580224

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

8 results found

Lot NumberCertificate TypeDateItem
G2419077Certificate of AnalysisJun 11, 2024 B107826
G2419078Certificate of AnalysisJun 11, 2024 B107826
G2419079Certificate of AnalysisJun 11, 2024 B107826
K2124334Certificate of AnalysisAug 04, 2023 B107826
K2124335Certificate of AnalysisAug 04, 2023 B107826
K2124336Certificate of AnalysisAug 04, 2023 B107826
K2124372Certificate of AnalysisAug 04, 2023 B107826
C2310684Certificate of AnalysisMar 16, 2023 B107826

Chemical and Physical Properties

SensitivityMoisture sensitive
Melt Point(°C)243 °C

Safety and Hazards(GHS)

Pictogram(s) GHS06
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H301:Toxic if swallowed

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310:IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P302+P352:IF ON SKIN: wash with plenty of water.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P270:Do not eat, drink or smoke when using this product.

P337+P313:IF eye irritation persists: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P332+P313:IF SKIN irritation occurs: Get medical advice/attention.

P330:Rinse mouth.

WGK Germany 3
RTECS TA1855200
Reaxy-Rn 3580224

Related Documents

Citations of This Product

1. Weidong Zhou, Tao Xu, Xiaowei Wang, Erjuan Zhi, Jun Liu, Wei Zhang, Junhui Ji.  (2012)  In situ polymerized nanocomposites of poly(butylene succinate)/Tio2 nanofibers: molecular weight, morphology, and thermal properties.  JOURNAL OF APPLIED POLYMER SCIENCE,  127  (1): (733-739).  [PMID:] [10.1002/app.37724]

References

1. A P Singh,P Nicholls.  (1986-03-01)  Membrane potentials in reconstituted cytochrome c oxidase proteoliposomes determined by butyltriphenyl phosphonium cation distribution..  Archives of biochemistry and biophysics,  245  ((2)): (436-445).  [PMID:3006593]
2. A J Clark,J B Jackson.  (1981-11-15)  The measurement of membrane potential during photosynthesis and during respiration in intact cells of Rhodopseudomonas capsulata by both electrochromism and by permeant ion redistribution..  The Biochemical journal,  200  ((2)): (389-397).  [PMID:7340838]
3. Jing Wang,Jie Zhang,Brian Arbogast,Claudia S Maier.  (2011-09-29)  Tandem mass spectrometric characterization of thiol peptides modified by the chemoselective cationic sulfhydryl reagent (4-iodobutyl)triphenylphosphonium--effects of a cationic thiol derivatization on peptide fragmentation..  Journal of the American Society for Mass Spectrometry,  22  ((10)): (1771-1783).  [PMID:21952891]
4. C W Keevil,I R Hamilton.  (1984-05-15)  Comparison of polyvinyl chloride membrane electrodes sensitive to alkylphosphonium ions for the determination of the electrical difference (delta psi) of Streptococcus mutans and Lactobacillus casei..  Analytical biochemistry,  139  ((1)): (228-236).  [PMID:6430121]
5. J E McCarthy,S J Ferguson,D B Kell.  (1981-04-15)  Estimation with an ion-selective electrode of the membrane potential in cells of Paracoccus denitrificans from the uptake of the butyltriphenylphosphonium cation during aerobic and anaerobic respiration..  The Biochemical journal,  196  ((1)): (311-321).  [PMID:7306073]
6. M Makrinich,M Sambol,A Goldbourt.  (2020-07-24)  Distance measurements between carbon and bromine using a split-pulse PM-RESPDOR solid-state NMR experiment..  Physical chemistry chemical physics : PCCP,  22  ((37)): (21022-21030).  [PMID:32700697]
7. Weidong Zhou, Tao Xu, Xiaowei Wang, Erjuan Zhi, Jun Liu, Wei Zhang, Junhui Ji.  (2012)  In situ polymerized nanocomposites of poly(butylene succinate)/Tio2 nanofibers: molecular weight, morphology, and thermal properties.  JOURNAL OF APPLIED POLYMER SCIENCE,  127  (1): (733-739).  [PMID:] [10.1002/app.37724]

Solution Calculators