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Dess-Martin Periodinane - 96%, high purity , CAS No.87413-09-0

9 Citations

≥96%

CAS#: 87413-09-0
Formula: C₁₃H₁₃IO₈
Molecular Weight: 424.14
MDL number: MFCD00130127
PubChem CID: 159087

Item Number

D110230

Grouped product items
SKU	Size	Availability	Price
D110230-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$29.90
D110230-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$89.90
D110230-25g	25g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$269.90
D110230-100g	100g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$749.90
D110230-500g	500g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$2,999.90

View related series

Hypervalent iodine compounds Oxidizing agent

Basic Description

Synonyms	DMP \| 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxyl-3(1H)-one \| 1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro- \| ACETIC ACID, 1,1',1''-(3-OXO-1.LAMBDA.5-1,2-BENZIODOXOL-1(3H)-YLIDYNE) ESTER \| AKOS005146141 \| DessMartin periodinane \| Dess-Mar
Specifications & Purity	≥96%
Storage Temp	Store at -20°C,Argon charged
Shipped In	Ice chest + Ice pads
Note	1g，250g卖完停产，不再备货
Product Description	Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones. Application： Dess–Martin periodinane is used as an oxidizing agent: For 1° and 2° alcohols to aldehydes and ketones. In the synthesis of N-protected α-amino aldehydes from the corresponding N-protected β-amino alcohols. To synthesize alkynyl oxoaldehyde probe (AlkMGO). Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.

Associated Targets(non-human)

Ptpn1 Protein-tyrosine phosphatase 1B (270 Activities)

Discover Target: Ptpn1

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Names and Identifiers

IUPAC Name	(1,1-diacetyloxy-3-oxo-1λ5,2-benziodoxol-1-yl) acetate
INCHI	InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChi Key	NKLCNNUWBJBICK-UHFFFAOYSA-N
Canonical SMILES	CC(=O)OI1(C2=CC=CC=C2C(=O)O1)(OC(=O)C)OC(=O)C
Isomeric SMILES	CC(=O)OI1(C2=CC=CC=C2C(=O)O1)(OC(=O)C)OC(=O)C
WGK Germany	3
PubChem CID	159087
Molecular Weight	424.14
Reaxy-Rn	4548207

Certificates

Certificate of Analysis(COA)

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Find and download the COA for your product by matching the lot number on the packaging.

23 results found

Lot Number	Certificate Type	Date	Item
G2424276	Certificate of Analysis	Jul 05, 2024	D110230
G2424275	Certificate of Analysis	Jul 05, 2024	D110230
G2424274	Certificate of Analysis	Jul 05, 2024	D110230
G2424273	Certificate of Analysis	Jul 05, 2024	D110230
G1626010	Certificate of Analysis	Feb 19, 2024	D110230
F23151025	Certificate of Analysis	May 23, 2023	D110230
J2323250	Certificate of Analysis	May 23, 2023	D110230
J2323249	Certificate of Analysis	May 23, 2023	D110230
J2323248	Certificate of Analysis	May 23, 2023	D110230
J2323247	Certificate of Analysis	May 23, 2023	D110230
F23151042	Certificate of Analysis	May 23, 2023	D110230
F23151030	Certificate of Analysis	May 23, 2023	D110230
C2324283	Certificate of Analysis	Feb 07, 2023	D110230
C2324282	Certificate of Analysis	Feb 07, 2023	D110230
C2324281	Certificate of Analysis	Feb 07, 2023	D110230
C2324280	Certificate of Analysis	Feb 07, 2023	D110230
C2324279	Certificate of Analysis	Feb 07, 2023	D110230
C2212487	Certificate of Analysis	May 14, 2022	D110230
F2221355	Certificate of Analysis	Mar 11, 2022	D110230
F2221354	Certificate of Analysis	Mar 11, 2022	D110230
F2221353	Certificate of Analysis	Mar 11, 2022	D110230
F2221352	Certificate of Analysis	Mar 11, 2022	D110230
F2221351	Certificate of Analysis	Mar 11, 2022	D110230

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Chemical and Physical Properties

Solubility	Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
Sensitivity	Light & Moisture & heat & Air Sensitive
Melt Point(°C)	130-133°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07, GHS03
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302:Harmful if swallowed H312:Harmful in contact with skin H332:Harmful if inhaled H272:May intensify fire; oxidizer
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P220:Keep away from clothing and other combustible materials. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	3
Reaxy-Rn	4548207
Merck Index	2933

Citations of This Product

1. Jiarong Qiu,Yueqi Zhang,Yaning Shi,Junwei Jiang,Shenglu Wu,Longxiang Li,Yuting Shao,Zhihong Xin. (2020-01-09) Identification and characterization of a novel phthalate-degrading hydrolase from a soil metagenomic library.. Ecotoxicology and environmental safety, 190 (110148-110148). [PMID:31911388]
2. Liuyan Gu,Haibo Yuan,Xueqin Lv,Guangsheng Li,Rigang Cong,Jianghua Li,Guocheng Du,Long Liu. (2020-02-12) High-yield and plasmid-free biocatalytic production of 5-methylpyrazine-2-carboxylic acid by combinatorial genetic elements engineering and genome engineering of Escherichia coli.. Enzyme and microbial technology, 134 (109488-109488). [PMID:32044035]
3. Mei Xu,Minhua Liu,Meirong Sun,Kun Chen,Xiujun Cao,Yaoming Hu. (2016-02-04) Magnetic solid-phase extraction of phthalate esters (PAEs) in apparel textile by core-shell structured Fe3O4@silica@triblock-copolymer magnetic microspheres.. Talanta, 150 (125-134). [PMID:26838390]
4. Shichao Yang,Jun Yang,Tao Wang,Liuqing Li,Siming Yu,Rong Jia,Ping Chen. (2020-04-02) Construction of a combined enzyme system of graphene oxide and manganese peroxidase for efficient oxidation of aromatic compounds.. Nanoscale, 12 ((14)): (7976-7985). [PMID:32232306]
5. Pengpeng Jia, Yu Zou, Jiang Jiang. (2023) Antibacterial, antioxidant and injectable hydrogels constructed using CuS and curcumin co-loaded micelles for NIR-enhanced infected wound healing. Journal of Materials Chemistry B, 11 (47): (11319-11334). [PMID:37990627]
6. Wenwen Shi, Dongqin Zhang, Luyao Han, Wanting Shao, Qimeng Liu, Bangyu Song, Guoqing Yan, Rupei Tang, Xuefeng Yang. (2024) Supramolecular chitin-based hydrogels with self-adapting and fast-degradation properties for enhancing wound healing. CARBOHYDRATE POLYMERS, 323 (26): (121374). [PMID:37940271]
7. Xi Yuan, Junlai Wan, Yang Yang, Long Huang, Chuankun Zhou, Jin Su, Shuaibin Hua, Hongxu Pu, Yi Zou, Hao Zhu, Xulin Jiang, Jun Xiao. (2023) Thermosensitive hydrogel for cartilage regeneration via synergistic delivery of SDF-1α like polypeptides and kartogenin. CARBOHYDRATE POLYMERS, 304 (120492). [PMID:36641179]
8. Xianqiang Zeng, Liguo Wang, Yan Cao, Chen Liu, Ziqiang Han, Peng He, Huiquan Li. (2022) Synthesis of poly(1,2-butylene oxide-stat-tetrahydrofuran) by controllable polymerization over Sc(OTf)3 for use in high-performance lubricating oil. EUROPEAN POLYMER JOURNAL, 179 (111483). [PMID:]
9. Li XS, Ren YC, Bao YZ, Liu J, Zhang XK, Zhang YW, Sun XL, Yao XS, Tang JS.. (2018) Synthesis of C3-Neoglycosides of digoxigenin and their anticancer activities.. Eur J Med Chem, 145 (252-262). [PMID:29329000]

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