Diphenylmethane - reagent grade,98%, high purity , CAS No.101-81-5

  • CP
  • ≥98%
Item Number
D105755
Grouped product items
SKUSizeAvailabilityPrice Qty
D105755-25g
25g
In stock
$30.90
D105755-50g
50g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$31.90
D105755-100g
100g
In stock
$51.90
D105755-250g
250g
In stock
$82.90
D105755-500g
500g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$133.90

Basic Description

SynonymsDTXCID9021891 | AI3-28021-X | EINECS 202-978-6 | EN300-21054 | Benzylbenzene | benzyl-benzene | Diphenylmethane, 99% | E75810 | Toluene, .alpha.-phenyl- | Diphenylmethan | Toluene, alpha-phenyl- | DTXSID1041891 | Tox21_301147 | alpha-phenyltoluene | CS-W0
Specifications & PurityCP, ≥98%
Shipped InNormal
GradeCP
Note50g卖完停产,不再备货

Associated Targets(Human)

CALM1 Tclin Calmodulin-1 (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

Mechanisms of Action

Mechanism of ActionAction Typetarget IDTarget NameTarget TypeTarget OrganismBinding Site NameReferences

Names and Identifiers

Pubchem Sid488180492
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488180492
IUPAC Name benzylbenzene
INCHI InChI=1S/C13H12/c1-3-7-12(8-4-1)11-13-9-5-2-6-10-13/h1-10H,11H2
InChi Key CZZYITDELCSZES-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)CC2=CC=CC=C2
Isomeric SMILES C1=CC=C(C=C1)CC2=CC=CC=C2
WGK Germany 2
RTECS DA4976500
PubChem CID 7580
Molecular Weight 168.23
Beilstein 1904982
Reaxy-Rn 1904982

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

8 results found

Lot NumberCertificate TypeDateItem
I2002018Certificate of AnalysisJun 06, 2024 D105755
F2016010Certificate of AnalysisApr 03, 2024 D105755
E2420015Certificate of AnalysisSep 23, 2022 D105755
I2215584Certificate of AnalysisSep 23, 2022 D105755
I2215585Certificate of AnalysisSep 23, 2022 D105755
I2215586Certificate of AnalysisSep 23, 2022 D105755
I2215587Certificate of AnalysisSep 23, 2022 D105755
G1825003Certificate of AnalysisMay 11, 2022 D105755

Chemical and Physical Properties

SolubilitySoluble in ethanol, ether, chloroform, etc.
Freezing Point(°C)25 °C
Refractive Index1.5753
Flash Point(°F)127℃
Flash Point(°C)127℃
Boil Point(°C)264.3°C
Melt Point(°C)22-24°C

Safety and Hazards(GHS)

Pictogram(s) GHS09
Signal Warning
Hazard Statements

H400:Very toxic to aquatic life

H410:Very toxic to aquatic life with long lasting effects

Precautionary Statements

P273:Avoid release to the environment.

P501:Dispose of contents/container to ...

P391:Collect spillage.

WGK Germany 2
RTECS DA4976500
Reaxy-Rn 1904982
Merck Index 3328

Related Documents

Citations of This Product

1. Jisheng Zhang,Yujuan Wang,Nengchao Luo,Zhuqi Chen,Kangbing Wu,Guochuan Yin.  (2015-05-06)  Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases..  Dalton transactions (Cambridge, England : 2003),  44  ((21)): (9847-9859).  [PMID:25939391]
2. Qifeng Yang, Yiming Mo.  (2023)  Direct Electrochemical Oxidation of Benzylic C–H Bond by La2O3@C/CP Composite Electrode with Water as the Green Oxygen Source.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  62  (46): (19427–19436).  [PMID:2969919] [10.1021/acs.iecr.3c02229]
3. Haobo Xie, Mingu Zhou, Xiaorui Cui, Chao Li, Yongjun Wu, Xinjuan Luo, Mao-Sen Yuan.  (2024)  A metal-complex based chemosensor for the detection of riboflavin and folate.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,  304  (123321).  [PMID:37678046] [10.1016/j.saa.2023.123321]
4. Yang Feng, Min Sun, Mingxia Sun, Jiaqing Feng, Haili Sun, Juanjuan Feng.  (2022)  Extraction performance-structure relationship of polyamidoamine dendrimers on silica for online solid-phase extraction of organic pollutants.  JOURNAL OF CHROMATOGRAPHY A,  1673  (463132).  [PMID:35576765] [10.1016/j.chroma.2022.463132]
5. Chong Wang, Yuchen Hou, Jiajia Cheng, Mei-Jin Lin, Xinchen Wang.  (2021)  Biomimetic donor-acceptor motifs in carbon nitrides: Enhancing red-light photocatalytic selective oxidation by rational surface engineering.  APPLIED CATALYSIS B-ENVIRONMENTAL,  294  (120259).  [PMID:] [10.1016/j.apcatb.2021.120259]
6. Liyun Huang, Kui Wu, Qian He, Chao Xiong, Tao Gan, Xiaohui He, Hongbing Ji.  (2021)  Quasi-continuous synthesis of iron single atom catalysts via a microcapsule pyrolysis strategy.  AICHE JOURNAL,  67  (6): (e17197).  [PMID:] [10.1002/aic.17197]
7. Xingfei Tang, Wentao Ding, Hao Li.  (2021)  Improved hydrodeoxygenation of bio-oil model compounds with polymethylhydrosiloxane by Brønsted acidic zeolites.  FUEL,  290  (119883).  [PMID:] [10.1016/j.fuel.2020.119883]
8. Shanshan Jie, Congqiang Yang, Yuan Chen, Zhigang Liu.  (2018)  Facile synthesis of ultra-stable Co-N-C catalysts using cobalt porphyrin and peptides as precursors for selective oxidation of ethylbenzene.  Molecular Catalysis,  458  (1).  [PMID:] [10.1016/j.mcat.2018.08.007]
9. Yuan Chen, Shanshan Jie, Congqiang Yang, Zhigang Liu.  (2017)  Active and efficient Co-N/C catalysts derived from cobalt porphyrin for selective oxidation of alkylaromatics.  APPLIED SURFACE SCIENCE,  419  (98).  [PMID:] [10.1016/j.apsusc.2017.04.246]
10. Zhong-Qiu Liu, Xian-Yong Wei, Xiao Zhou, Yu-Chuan Xiao, Zhan-Ku Li, Xian-Hou Guo, Sheng-Kang Wang, Yang-Yang Zhang, Zhi-Min Zong, Feng-Yun Ma, Jing-Mei Liu.  (2017)  An acidic ionic liquid modified microfiber attapulgite-supported nickel for catalytic hydroconversion of α,ω-diarylalkanes.  FUEL PROCESSING TECHNOLOGY,  161  (85).  [PMID:] [10.1016/j.fuproc.2017.03.011]
11. Miao Luo, Sheng Wang, Meiling Wang, Shaorong Huang, Chengpeng Li, Lin Chen, Xiang Ma.  (2016)  Novel organogel harnessing Excited-State Intramolecular Proton Transfer process with aggregation induced emission and photochromism.  DYES AND PIGMENTS,  132  (48).  [PMID:] [10.1016/j.dyepig.2016.04.036]
12. MIAO LUO, XIE ZHOU, ZHENGUO CHI, CHUNPING MA, YI ZHANG, SIWEI LIU, JIARUI XU.  (2013)  SYNTHESIS AND PROPERTIES OF GELATORS DERIVED FROM TETRAPHENYLETHYLENE AND GALLIC ACID WITH AGGREGATION-INDUCED EMISSION.  Journal of Molecular and Engineering Materials,      [PMID:] [10.1142/S2251237313400078]

References

1. B Kedjouar,S Daunes,B J Vilner,W D Bowen,A Klaebe,J C Faye,M Poirot.  (1999-12-11)  Structural similitudes between cytotoxic antiestrogen-binding site (AEBS) ligands and cytotoxic sigma receptor ligands. Evidence for a relationship between cytotoxicity and affinity for AEBS or sigma-2 receptor but not for sigma-1 receptor..  Biochemical pharmacology,  58  ((12)): (1927-1939).  [PMID:10591147]
2. S G Bell,C F Harford-Cross,L L Wong.  (2001-12-12)  Engineering the CYP101 system for in vivo oxidation of unnatural substrates..  Protein engineering,  14  ((10)): (797-802).  [PMID:11739899]
3. F Chen,F He,J Li,J Luo,Z Wu,H Yu,L Wang,J Lin.  (2003-02-18)  [Analysis of essential oil from Artemisia annul L. by extraction of different methods]..  Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials,  24  ((3)): (176-178).  [PMID:12587172]
4. N Doukyu,K Toyoda,R Aono.  (2003-03-29)  Indigo production by Escherichia coli carrying the phenol hydroxylase gene from Acinetobacter sp strain ST-550 in a water-organic solvent two-phase system..  Applied microbiology and biotechnology,  60  ((6)): (720-725).  [PMID:12664152]
5. T Mishra,A K De,S Chattopadhyay,P K Mallick,P Sett.  (2005-01-15)  Electronic and vibrational spectra of diphenylmethane..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  61  ((4)): (767-776).  [PMID:15649813]
6. Markus A Lill,Fabienne Winiger,Angelo Vedani,Beat Ernst.  (2005-09-02)  Impact of induced fit on ligand binding to the androgen receptor: a multidimensional QSAR study to predict endocrine-disrupting effects of environmental chemicals..  Journal of medicinal chemistry,  48  ((18)): (5666-5674).  [PMID:16134935]
7. Masahiko Kainuma,Jun-ichi Kasuga,Shinnosuke Hosoda,Ken-ichi Wakabayashi,Aya Tanatani,Kazuo Nagasawa,Hiroyuki Miyachi,Makoto Makishima,Yuichi Hashimoto.  (2006-04-18)  Diphenylmethane skeleton as a multi-template for nuclear receptor ligands: preparation of FXR and PPAR ligands..  Bioorganic & medicinal chemistry letters,  16  ((12)): (3213-3218).  [PMID:16617018]
8. Sang-Woo Kang,Chris M Gothard,Santanu Maitra,Atia-Tul-Wahab,James S Nowick.  (2007-01-25)  A new class of macrocyclic receptors from iota-peptides..  Journal of the American Chemical Society,  129  ((6)): (1486-1487).  [PMID:17243690]
9. Toshiki Nokami,Kousuke Ohata,Masafumi Inoue,Hiroaki Tsuyama,Akito Shibuya,Kazuya Soga,Masayuki Okajima,Seiji Suga,Jun-ichi Yoshida.  (2008-07-30)  Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules..  Journal of the American Chemical Society,  130  ((33)): (10864-10865).  [PMID:18661982]
10. Louis S Chupak,Joanna P Wolkowski,Yves A Chantigny.  (2008-12-23)  Palladium-catalyzed cross-coupling reactions of benzyl indium reagents with aryl iodides..  The Journal of organic chemistry,  74  ((3)): (1388-1390).  [PMID:19099410]
11. Mohammed T A Salim,Mika Okamoto,Shinnosuke Hosoda,Hiroshi Aoyama,Yuichi Hashimoto,Masanori Baba.  (2010-04-24)  Anti-bovine viral diarrhoea virus activity of novel diphenylmethane derivatives..  Antiviral chemistry & chemotherapy,  20  ((5)): (193-200).  [PMID:20413826]
12. Camille Cau,Sergey I Nikitenko.  (2011-11-08)  Mechanism of W(CO)6 sonolysis in diphenylmethane..  Ultrasonics sonochemistry,  19  ((3)): (498-502).  [PMID:22054911]
13. Ben Nebgen,Frank Lee Emmert,Lyudmila V Slipchenko.  (2012-09-04)  Vibronic coupling in asymmetric bichromophores: theory and application to diphenylmethane..  The Journal of chemical physics,  137  ((8)): (084112-084112).  [PMID:22938223]
14. Jisheng Zhang,Yujuan Wang,Nengchao Luo,Zhuqi Chen,Kangbing Wu,Guochuan Yin.  (2015-05-06)  Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases..  Dalton transactions (Cambridge, England : 2003),  44  ((21)): (9847-9859).  [PMID:25939391]
15. S H Safe,L Pallaroni,K Yoon,K Gaido,S Ross,B Saville,D McDonnellc.  (2002-01-22)  Toxicology of environmental estrogens..  Reproduction, fertility, and development,  13  ((4)): (307-315).  [PMID:11800169]
16. Carsten Uerpmann,Jaroslav Malina,Mirela Pascu,Guy J Clarkson,Virtudes Moreno,Alison Rodger,Anna Grandas,Michael J Hannon.  (2005-01-26)  Design and DNA binding of an extended triple-stranded metallo-supramolecular cylinder..  Chemistry (Weinheim an der Bergstrasse, Germany),  11  ((6)): (1750-1756).  [PMID:15669033]
17. Nathan R Pillsbury,Jaime A Stearns,Christian W Müller,David F Plusquellic,Timothy S Zwier.  (2008-12-03)  State-specific studies of internal mixing in a prototypical flexible bichromophore: Diphenylmethane..  The Journal of chemical physics,  129  ((11)): (114301-114301).  [PMID:19044954]
18. Jaime A Stearns,Nathan R Pillsbury,Kevin O Douglass,Christian W Müller,Timothy S Zwier,David F Plusquellic.  (2008-12-17)  Rotationally resolved studies of S0 and the exciton coupled S1/S2 origin regions of diphenylmethane and the d(12) isotopologue..  The Journal of chemical physics,  129  ((22)): (224305-224305).  [PMID:19071914]
19. Shinnosuke Hosoda,Hiroshi Aoyama,Yukinori Goto,Mohammed T A Salim,Mika Okamoto,Mariko Hashimoto,Masanori Baba,Yuichi Hashimoto.  (2009-05-19)  Discovery of diphenylmethane analogs as anti-bovine diarrhea viral agents..  Bioorganic & medicinal chemistry letters,  19  ((12)): (3157-3161).  [PMID:19447037]
20. Halis Türker Balaydin,Ílhami Gülçin,Abdullah Menzek,Süleyman Göksu,Ertan Şahin.  (2010-02-02)  Synthesis and antioxidant properties of diphenylmethane derivative bromophenols including a natural product..  Journal of enzyme inhibition and medicinal chemistry,  25  ((5)): (685-695).  [PMID:20113195]
21. Gregor Hoffmann,Kathrin Bönsch,Thomas Greiner-Stöffele,Meike Ballschmiter.  (2011-01-29)  Changing the substrate specificity of P450cam towards diphenylmethane by semi-rational enzyme engineering..  Protein engineering, design & selection : PEDS,  24  ((5)): (439-446).  [PMID:21273340]
22. Adelfo Reyes-Ramírez,Martha Leyte-Lugo,Mario Figueroa,Trinidad Serrano-Alba,Martín González-Andrade,Rachel Mata.  (2011-04-26)  Synthesis, biological evaluation, and docking studies of gigantol analogs as calmodulin inhibitors..  European journal of medicinal chemistry,  46  ((7)): (2699-2708).  [PMID:21514702]
23. Shin Grace Chou,Chirantha P Rodrigo,Christian W Müller,Kevin O Douglass,Timothy S Zwier,David F Plusquellic.  (2011-06-07)  Rotationally resolved C2 symmetric conformers of bis-(4-hydroxyphenyl)methane: prototypical examples of excitonic coupling in the S1 and S2 electronic states..  The journal of physical chemistry. A,  115  ((34)): (9643-9652).  [PMID:21639083]
24. Amarajothi Dhakshinamoorthy,Mercedes Alvaro,Young Kyu Hwang,You-Kyong Seo,Avelino Corma,Hermenegildo Garcia.  (2011-09-01)  Intracrystalline diffusion in metal organic framework during heterogeneous catalysis: influence of particle size on the activity of MIL-100 (Fe) for oxidation reactions..  Dalton transactions (Cambridge, England : 2003),  40  ((40)): (10719-10724).  [PMID:21879084]
25. Jiadi Zhang,Ana Bellomo,Andrea D Creamer,Spencer D Dreher,Patrick J Walsh.  (2012-07-24)  Palladium-catalyzed C(sp3)-H arylation of diarylmethanes at room temperature: synthesis of triarylmethanes via deprotonative-cross-coupling processes..  Journal of the American Chemical Society,  134  ((33)): (13765-13772).  [PMID:22816972]
26. P Morvillo.  (2013-08-02)  Multi adducts of diphenylmethanofullerenes as electron acceptors for polymer solar cells: a quantum chemical study..  Journal of nanoscience and nanotechnology,  13  ((7)): (5221-5226).  [PMID:23901556]
27. Qifeng Yang, Yiming Mo.  (2023)  Direct Electrochemical Oxidation of Benzylic C–H Bond by La2O3@C/CP Composite Electrode with Water as the Green Oxygen Source.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  62  (46): (19427–19436).  [PMID:2969919] [10.1021/acs.iecr.3c02229]
28. Haobo Xie, Mingu Zhou, Xiaorui Cui, Chao Li, Yongjun Wu, Xinjuan Luo, Mao-Sen Yuan.  (2024)  A metal-complex based chemosensor for the detection of riboflavin and folate.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,  304  (123321).  [PMID:37678046] [10.1016/j.saa.2023.123321]
29. Yang Feng, Min Sun, Mingxia Sun, Jiaqing Feng, Haili Sun, Juanjuan Feng.  (2022)  Extraction performance-structure relationship of polyamidoamine dendrimers on silica for online solid-phase extraction of organic pollutants.  JOURNAL OF CHROMATOGRAPHY A,  1673  (463132).  [PMID:35576765] [10.1016/j.chroma.2022.463132]
30. Chong Wang, Yuchen Hou, Jiajia Cheng, Mei-Jin Lin, Xinchen Wang.  (2021)  Biomimetic donor-acceptor motifs in carbon nitrides: Enhancing red-light photocatalytic selective oxidation by rational surface engineering.  APPLIED CATALYSIS B-ENVIRONMENTAL,  294  (120259).  [PMID:] [10.1016/j.apcatb.2021.120259]
31. Liyun Huang, Kui Wu, Qian He, Chao Xiong, Tao Gan, Xiaohui He, Hongbing Ji.  (2021)  Quasi-continuous synthesis of iron single atom catalysts via a microcapsule pyrolysis strategy.  AICHE JOURNAL,  67  (6): (e17197).  [PMID:] [10.1002/aic.17197]
32. Xingfei Tang, Wentao Ding, Hao Li.  (2021)  Improved hydrodeoxygenation of bio-oil model compounds with polymethylhydrosiloxane by Brønsted acidic zeolites.  FUEL,  290  (119883).  [PMID:] [10.1016/j.fuel.2020.119883]
33. Shanshan Jie, Congqiang Yang, Yuan Chen, Zhigang Liu.  (2018)  Facile synthesis of ultra-stable Co-N-C catalysts using cobalt porphyrin and peptides as precursors for selective oxidation of ethylbenzene.  Molecular Catalysis,  458  (1).  [PMID:] [10.1016/j.mcat.2018.08.007]
34. Yuan Chen, Shanshan Jie, Congqiang Yang, Zhigang Liu.  (2017)  Active and efficient Co-N/C catalysts derived from cobalt porphyrin for selective oxidation of alkylaromatics.  APPLIED SURFACE SCIENCE,  419  (98).  [PMID:] [10.1016/j.apsusc.2017.04.246]
35. Zhong-Qiu Liu, Xian-Yong Wei, Xiao Zhou, Yu-Chuan Xiao, Zhan-Ku Li, Xian-Hou Guo, Sheng-Kang Wang, Yang-Yang Zhang, Zhi-Min Zong, Feng-Yun Ma, Jing-Mei Liu.  (2017)  An acidic ionic liquid modified microfiber attapulgite-supported nickel for catalytic hydroconversion of α,ω-diarylalkanes.  FUEL PROCESSING TECHNOLOGY,  161  (85).  [PMID:] [10.1016/j.fuproc.2017.03.011]
36. Miao Luo, Sheng Wang, Meiling Wang, Shaorong Huang, Chengpeng Li, Lin Chen, Xiang Ma.  (2016)  Novel organogel harnessing Excited-State Intramolecular Proton Transfer process with aggregation induced emission and photochromism.  DYES AND PIGMENTS,  132  (48).  [PMID:] [10.1016/j.dyepig.2016.04.036]
37. MIAO LUO, XIE ZHOU, ZHENGUO CHI, CHUNPING MA, YI ZHANG, SIWEI LIU, JIARUI XU.  (2013)  SYNTHESIS AND PROPERTIES OF GELATORS DERIVED FROM TETRAPHENYLETHYLENE AND GALLIC ACID WITH AGGREGATION-INDUCED EMISSION.  Journal of Molecular and Engineering Materials,      [PMID:] [10.1142/S2251237313400078]

Solution Calculators