Grouped product items

SKU

Size

Availability

Price

Qty

X107227-25ml

25ml

Available within 4-8 weeks(?)

$41.90

X107227-100ml

100ml

Available within 4-8 weeks(?)

$78.90

X107227-500ml

500ml

In stock

$274.90

Basic Description

Synonyms	m-Xylylenediamine \| 1477-55-0 \| 1,3-BENZENEDIMETHANAMINE \| 1,3-Bis(aminomethyl)benzene \| 1,3-phenylenedimethanamine \| 1,3-Xylylenediamine \| m-Xylylendiamin \| m-Phenylenebis(methylamine) \| Methylamine, m-phenylenebis- \| alpha,alpha'-Diamino-m-xylene \| MXDA \| [3-(aminomethyl)phe
Specifications & Purity	≥99%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	m-Xylylenediamine can be used: As a monomer for the synthesis of poly(vinylogous urethane) vitrimers. As a starting material for the synthesis of carbamate-protected multisubstituted bis-guanidine. For the synthesis of polyamides by catalytic dehydrogenation with diols.

Associated Targets(Human)

AOC3 Tchem Membrane primary amine oxidase (0 Activities)

Discover Target: AOC3

Activity Type	Activity Value -log(M)	Mechanism of Action	Activity Reference	Publications (PubMed IDs)

Associated Targets(non-human)

AOC3 Amine oxidase, copper containing (44 Activities)

Discover Target: AOC3

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Names and Identifiers

IUPAC Name	[3-(aminomethyl)phenyl]methanamine
INCHI	InChI=1S/C8H12N2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6,9-10H2
InChi Key	FDLQZKYLHJJBHD-UHFFFAOYSA-N
Canonical SMILES	C1=CC(=CC(=C1)CN)CN
Isomeric SMILES	C1=CC(=CC(=C1)CN)CN
WGK Germany	2
RTECS	PF8970000
PubChem CID	15133
UN Number	3267
Packing Group	I
Molecular Weight	136.19
Beilstein	1099911
Reaxy-Rn	1099911

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

10 results found

Lot Number	Certificate Type	Date	Item
H2402288	Certificate of Analysis	Jun 12, 2024	X107227
H2402658	Certificate of Analysis	Jun 12, 2024	X107227
A2424296	Certificate of Analysis	Sep 06, 2022	X107227
B2427257	Certificate of Analysis	Sep 06, 2022	X107227
I2219245	Certificate of Analysis	Sep 06, 2022	X107227
I2219246	Certificate of Analysis	Sep 06, 2022	X107227
I2219247	Certificate of Analysis	Sep 06, 2022	X107227
I2219248	Certificate of Analysis	Sep 06, 2022	X107227
B2223631	Certificate of Analysis	Feb 09, 2022	X107227
B2223634	Certificate of Analysis	Feb 09, 2022	X107227

Chemical and Physical Properties

Solubility	Easily soluble in ether, alcohol, and water completely miscible
Sensitivity	Hygroscopic
Freezing Point(°C)	14 °C
Refractive Index	1.57-1.572
Flash Point(°F)	235.4 °F
Flash Point(°C)	113℃
Boil Point(°C)	274°C
Melt Point(°C)	14°C

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS05, GHS07
Signal	Danger
Hazard Statements	H331:Toxic if inhaled H314:Causes severe skin burns and eye damage H412:Harmful to aquatic life with long lasting effects H302:Harmful if swallowed H318:Causes serious eye damage H317:May cause an allergic skin reaction H312:Harmful in contact with skin H332:Harmful if inhaled H330:Fatal if inhaled
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P284:[In case of inadequate ventilation] Wear respiratory protection. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P320:Specific treatment is urgent (see ... on this label). P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	2
RTECS	PF8970000
Reaxy-Rn	1099911
Class	8

Citations of This Product

1. Ruiyin Liu, Zepei Yan, Ming Liu, Hanbing Lu, Xiaoyun Han, Luyao Su, Shugao Zhao, He Wang. (2023) Nylon 66 fibers coated with environmentally friendly dopamine-modified adhesives and their interfacial adhesion with neoprene rubber. POLYMER COMPOSITES, (2): [PMID:31375563]
2. Xuejie Wang, Chongwen Yu, Jiaqi Sun, Chenzhong Mu, Yujie Song. (2023) A novel isocyanate-free strategy towards preparation of polyurea by a ring-opening reaction. Polymer Chemistry, 14 (41): (4719-4725). [PMID:27524201]
3. Xu-Chen Jiang, Ping Li, Yun Liu, Yuan-Wei Yan, Ping Zhu. (2023) Preparation and properties of APP flame-retardant ramie fabric reinforced epoxy resin composites. INDUSTRIAL CROPS AND PRODUCTS, 197 (116611). [PMID:]
4. Xiao-bo Fu, Jia-cao Yang, Gang Zhang, Mei-lin Zhang, Xiao-jun Wang, Jie Yang. (2023) Tough and Excellent Heat-Resistant Semiaromatic Polyamide Elastomer Containing Hierarchical Bonds: Synthesis and Synergistic Molecular Design. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 62 (7): (3165–3175). [PMID:]
5. Ruisen Shi, Xueru Sheng, Haiyuan Jia, Jian Zhang, Na Li, Haiqiang Shi, Meihong Niu, Qingwei Ping. (2023) Preparation of sustainable transparent wood with glucose and phenol derived resin. INDUSTRIAL CROPS AND PRODUCTS, 193 (116234). [PMID:]
6. Chang Liu, Ping Li, Ying-Jun Xu, Yun Liu, Ping Zhu. (2022) Nickel alginate-enhanced fire safety of aluminum diethylphosphinate on epoxy resin. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (9): (e53552). [PMID:]
7. Mingbin He, Lijing Zou, Zhaohui Chen, Ruoming Huang. (2022) Comparative study of different bis-citraconimides as anti-reversion agents in natural rubber. JOURNAL OF ELASTOMERS AND PLASTICS, [PMID:]
8. Guilin Hu, Junfei Ou, Xinzuo Fang, Sheng Lei, Fajun Wang, Changquan Li, Wen Li, Yating Hu, Alidad Amirfazli. (2023) Robust superhydrophobic and wrinkle-recovering fabric based on shape memory epoxy. MATERIALS LETTERS, 331 (133480). [PMID:]
9. Yu Fan, Xiaomu Wang, Junying Zhang, Jue Cheng, Qingsong Lian. (2023) Relationship between cross-linking network structure and phase change performances toward multifunctional epoxy/bio-based wax form-stable phase change materials. CHEMICAL ENGINEERING JOURNAL, 454 (140221). [PMID:]
10. Chang Liu, Ping Li, Ying-Jun Xu, Yun Liu, Ping Zhu. (2022) Synergistic Effects of Iron Alginate on Improving the Fire Safety and Mechanical Properties of Epoxy Resin/Ammonium Polyphosphate Composites. MACROMOLECULAR MATERIALS AND ENGINEERING, 308 (3): (2200516). [PMID:]
11. Yinglu Sun, Xinxin Tian, Haopu Xie, Biru Shi, Jiahui Zhong, Xiangdong Liu, Yuming Yang. (2022) Reprocessable and degradable bio-based polyurethane by molecular design engineering with extraordinary mechanical properties for recycling carbon fiber. POLYMER, 258 (125313). [PMID:]
12. Liu Chang, Li Ping, Xu Ying-Jun, Liu Yun, Zhu Ping, Wang Yu-Zhong. (2022) Epoxy/iron alginate composites with improved fire resistance, smoke suppression and mechanical properties. JOURNAL OF MATERIALS SCIENCE, 57 (4): (2567-2583). [PMID:]

References

1. G Richter,H Kadner. (1990-07-01) [Allergic contact eczema caused by m-xylylene-diamine in the polyurethane silk production].. Dermatosen in Beruf und Umwelt. Occupation and environment, 38 ((4)): (117-120). [PMID:2148720]
2. P Paseiro-Losada,J Simal-Gándara,P Sanmartin-Fenollera,C Pérez-Lamela,F López-Fabal. (1998-11-13) m-Xylylenediamine determination in the official EU aqueous food simulants.. Journal of chromatographic science, 36 ((11)): (554-560). [PMID:9812390]
3. K D Rice,A R Gangloff,E Y Kuo,J M Dener,V R Wang,R Lum,W S Newcomb,C Havel,D Putnam,L Cregar,M Wong,R L Warne. (2000-10-31) Dibasic inhibitors of human mast cell tryptase. Part 1: synthesis and optimization of a novel class of inhibitors.. Bioorganic & medicinal chemistry letters, 10 ((20)): (2357-2360). [PMID:11055355]
4. Johannes Geier,Holger Lessmann,Uwe Hillen,Uta Jappe,Heinrich Dickel,Patrick Koch,Peter J Frosch,Axel Schnuch,Wolfgang Uter. (2004-12-21) An attempt to improve diagnostics of contact allergy due to epoxy resin systems. First results of the multicentre study EPOX 2002.. Contact dermatitis, 51 ((5-6)): (263-272). [PMID:15606651]
5. Francesc Yraola, Silvia García-Vicente, Juan Fernandez-Recio, Fernando Albericio, Antonio Zorzano, Luc Marti, Miriam Royo,. (2006-10-13) New efficient substrates for semicarbazide-sensitive amine oxidase/VAP-1 enzyme: analysis by SARs and computational docking.. Journal of medicinal chemistry, 49 ((21)): ( 6197-6208 ). [PMID:17034126]
6. Saverio Cellamare,Angela Stefanachi,Diana A Stolfa,Teodora Basile,Marco Catto,Francesco Campagna,Eddy Sotelo,Pasquale Acquafredda,Angelo Carotti. (2008-04-15) Design, synthesis, and biological evaluation of glycine-based molecular tongs as inhibitors of Abeta1-40 aggregation in vitro.. Bioorganic & medicinal chemistry, 16 ((9)): (4810-4822). [PMID:18406152]
7. Eva Helaskoski,Hille Suojalehto,Outi Kuuliala,Kristiina Aalto-Korte. (2014-10-08) Prick testing with chemicals in the diagnosis of occupational contact urticaria and respiratory diseases.. Contact dermatitis, 72 ((1)): (20-32). [PMID:25289485]
8. S Sommer,S M Wilkinson. (2001-06-22) Occupational contact dermatitis due to the epoxy hardener m-xylylenediamine.. Contact dermatitis, 44 ((6)): (374-374). [PMID:11417528]
9. Yongmei Zhao,Jianhui Zhu,Weijiang He,Zhen Yang,Yangguang Zhu,Yizhi Li,Junfeng Zhang,Zijian Guo. (2006-06-07) Oxidative DNA cleavage promoted by multinuclear copper complexes: activity dependence on the complex structure.. Chemistry (Weinheim an der Bergstrasse, Germany), 12 ((25)): (6621-6629). [PMID:16755636]
10. Yoshinobu Ishikawa,Naoki Yamakawa,Tadayuki Uno. (2008-12-17) Binding of cationic bis-porphyrins linked with p- or m-xylylenediamine and their zinc(II) complexes to duplex DNA.. Molecules (Basel, Switzerland), 13 ((12)): (3117-3128). [PMID:19078853]
11. Alvaro Gomez-Lopez,Bruno Grignard,Iñigo Calvo,Christophe Detrembleur,Haritz Sardon. (2020-11-28) Synergetic Effect of Dopamine and Alkoxysilanes in Sustainable Non-Isocyanate Polyurethane Adhesives.. Macromolecular rapid communications, 42 ((3)): (e2000538-e2000538). [PMID:33244816]
12. Ruiyin Liu, Zepei Yan, Ming Liu, Hanbing Lu, Xiaoyun Han, Luyao Su, Shugao Zhao, He Wang. (2023) Nylon 66 fibers coated with environmentally friendly dopamine-modified adhesives and their interfacial adhesion with neoprene rubber. POLYMER COMPOSITES, (2): [PMID:31375563]
13. Xuejie Wang, Chongwen Yu, Jiaqi Sun, Chenzhong Mu, Yujie Song. (2023) A novel isocyanate-free strategy towards preparation of polyurea by a ring-opening reaction. Polymer Chemistry, 14 (41): (4719-4725). [PMID:27524201]
14. Xu-Chen Jiang, Ping Li, Yun Liu, Yuan-Wei Yan, Ping Zhu. (2023) Preparation and properties of APP flame-retardant ramie fabric reinforced epoxy resin composites. INDUSTRIAL CROPS AND PRODUCTS, 197 (116611). [PMID:]
15. Xiao-bo Fu, Jia-cao Yang, Gang Zhang, Mei-lin Zhang, Xiao-jun Wang, Jie Yang. (2023) Tough and Excellent Heat-Resistant Semiaromatic Polyamide Elastomer Containing Hierarchical Bonds: Synthesis and Synergistic Molecular Design. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 62 (7): (3165–3175). [PMID:]
16. Ruisen Shi, Xueru Sheng, Haiyuan Jia, Jian Zhang, Na Li, Haiqiang Shi, Meihong Niu, Qingwei Ping. (2023) Preparation of sustainable transparent wood with glucose and phenol derived resin. INDUSTRIAL CROPS AND PRODUCTS, 193 (116234). [PMID:]
17. Chang Liu, Ping Li, Ying-Jun Xu, Yun Liu, Ping Zhu. (2022) Nickel alginate-enhanced fire safety of aluminum diethylphosphinate on epoxy resin. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (9): (e53552). [PMID:]
18. Mingbin He, Lijing Zou, Zhaohui Chen, Ruoming Huang. (2022) Comparative study of different bis-citraconimides as anti-reversion agents in natural rubber. JOURNAL OF ELASTOMERS AND PLASTICS, [PMID:]
19. Guilin Hu, Junfei Ou, Xinzuo Fang, Sheng Lei, Fajun Wang, Changquan Li, Wen Li, Yating Hu, Alidad Amirfazli. (2023) Robust superhydrophobic and wrinkle-recovering fabric based on shape memory epoxy. MATERIALS LETTERS, 331 (133480). [PMID:]
20. Yu Fan, Xiaomu Wang, Junying Zhang, Jue Cheng, Qingsong Lian. (2023) Relationship between cross-linking network structure and phase change performances toward multifunctional epoxy/bio-based wax form-stable phase change materials. CHEMICAL ENGINEERING JOURNAL, 454 (140221). [PMID:]
21. Chang Liu, Ping Li, Ying-Jun Xu, Yun Liu, Ping Zhu. (2022) Synergistic Effects of Iron Alginate on Improving the Fire Safety and Mechanical Properties of Epoxy Resin/Ammonium Polyphosphate Composites. MACROMOLECULAR MATERIALS AND ENGINEERING, 308 (3): (2200516). [PMID:]
22. Yinglu Sun, Xinxin Tian, Haopu Xie, Biru Shi, Jiahui Zhong, Xiangdong Liu, Yuming Yang. (2022) Reprocessable and degradable bio-based polyurethane by molecular design engineering with extraordinary mechanical properties for recycling carbon fiber. POLYMER, 258 (125313). [PMID:]
23. Liu Chang, Li Ping, Xu Ying-Jun, Liu Yun, Zhu Ping, Wang Yu-Zhong. (2022) Epoxy/iron alginate composites with improved fire resistance, smoke suppression and mechanical properties. JOURNAL OF MATERIALS SCIENCE, 57 (4): (2567-2583). [PMID:]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.

m-Xylylenediamine - 99%, high purity , CAS No.1477-55-0