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N-Methylformamide - ≥99%, high purity , CAS No.123-39-7

14 Citations

≥99%

CAS#: 123-39-7
Formula: C₂H₅NO
Molecular Weight: 59.07
Beilstein Registry Number: 1098352
EC Number: 204-624-6
MDL number: MFCD00003280
PubChem CID: 31254

Item Number

M107591

Grouped product items
SKU	Size	Availability	Price
M107591-25g	25g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$13.90
M107591-100g	100g	In stock	$20.90
M107591-500g	500g	In stock	$37.90

View related series

amide Amine∩Aliphatic hydrocarbon Carbonyl compound Fatty chain compounds Non heterocyclic block Organic building blocks

Basic Description

Synonyms	Methylformamide \| Formamide, N-methyl- \| Monomethylformamide \| N-Formylmethylamine \| n-methyl-Formamide \| NSC 3051 \| N-Monomethylformamide \| EK 7011 \| HCONHCH3 \| X 188 \| Formamide, methyl- \| methylimidoformic acid \| NMF \| N-Methyl-formimidic acid
Specifications & Purity	≥99%
Shipped In	Normal
Note	25g卖完停产，不再备货
Product Description	N-Methylformamide (NMF), a formamide derivative, is widely employed as an organic solvent. NMF molecule contains C=O and N-H groups, so it can act as a proton donor and acceptor. Its antitumor activities in mice have been assessed. Optical-heterodyne-detected optical Kerr effect (OHD-OKE) spectroscopic evaluation of NMF has been reported. Due to its important physical properties such as high dielectric constant, high solubility, low conductivity and amphiprotic nature, it is suitable for use as a separation medium in capillary electrophoresis studies. N-Methylformamide may be employed in the preparation of the following: • Li2S-P2S5 solid electrolytes (SE) • interlayer-condensed materials of protonated layered silicate (magadiite) • Li3PS4 solid electrolyte Application N-Methylformamide is used to prepare methyl isocyanate. It is used as an extraction solvent for aromatic hydrocarbons and acts as a ligand in coordination chemistry. It is employed as a solvent in oil refineries and in aluminum electrolytic capacitors. Further, it is used as a reagent in organic synthesis. In addition to this, it is used as an investigational anticancer drug and an intermediate in the production of some pharmaceutical compounds.

Associated Targets(Human)

A498 (42825 Activities)

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ACHN (49357 Activities)

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CAKI-1 (44928 Activities)

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CCRF-CEM (65223 Activities)

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COLO 205 (50209 Activities)

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DLD-1 (17511 Activities)

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DMS-273 (14108 Activities)

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DU-145 (51482 Activities)

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HL-60 (67320 Activities)

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HT-29 (80576 Activities)

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K562 (73714 Activities)

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KM12 (47707 Activities)

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M14 (47487 Activities)

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MCF7 (126967 Activities)

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MOLT-4 (49676 Activities)

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OVCAR-3 (48710 Activities)

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OVCAR-4 (44535 Activities)

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OVCAR-5 (45555 Activities)

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OVCAR-8 (47708 Activities)

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PC-3 (62116 Activities)

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RPMI-8226 (44974 Activities)

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RXF 393 (41971 Activities)

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SF-295 (48000 Activities)

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SK-MEL-2 (46422 Activities)

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SK-MEL-28 (48833 Activities)

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SK-MEL-5 (47095 Activities)

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SK-OV-3 (52876 Activities)

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SN12C (47755 Activities)

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SNB-19 (46794 Activities)

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SNB-78 (14240 Activities)

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TK-10 (45540 Activities)

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U-251 (51189 Activities)

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UACC-257 (46019 Activities)

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UACC-62 (47335 Activities)

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UO-31 (46270 Activities)

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XF498 (12972 Activities)

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786-0 (47912 Activities)

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A549 (127892 Activities)

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NCI/ADR-RES (33767 Activities)

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T47D (39041 Activities)

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EKVX (44102 Activities)

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NCI-H322M (45589 Activities)

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HCC 2998 (41480 Activities)

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HCT-116 (91556 Activities)

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HOP-18 (11577 Activities)

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HOP-92 (41141 Activities)

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Hs-578T (29457 Activities)

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NCI-H460 (60772 Activities)

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SF-268 (49410 Activities)

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IGROV-1 (47897 Activities)

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Associated Targets(non-human)

Mus musculus (284745 Activities)

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P388 (20296 Activities)

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P388/ADR (1216 Activities)

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SARS-CoV-2 (38078 Activities)

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Names and Identifiers

IUPAC Name	N-methylformamide
INCHI	InChI=1S/C2H5NO/c1-3-2-4/h2H,1H3,(H,3,4)
InChi Key	ATHHXGZTWNVVOU-UHFFFAOYSA-N
Canonical SMILES	CNC=O
Isomeric SMILES	CNC=O
WGK Germany	1
RTECS	LQ3000000
PubChem CID	31254
Molecular Weight	59.07
Beilstein	1098352
Reaxy-Rn	1098352

Certificates

Certificate of Analysis(COA)

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17 results found

Lot Number	Certificate Type	Date	Item
E2423579	Certificate of Analysis	May 28, 2024	M107591
E2409280	Certificate of Analysis	May 24, 2024	M107591
E2411272	Certificate of Analysis	Apr 24, 2024	M107591
E2411273	Certificate of Analysis	Apr 24, 2024	M107591
E2411274	Certificate of Analysis	Apr 24, 2024	M107591
E2411325	Certificate of Analysis	Apr 24, 2024	M107591
C2018108	Certificate of Analysis	Jan 18, 2024	M107591
L2318036	Certificate of Analysis	Nov 01, 2022	M107591
L2301159	Certificate of Analysis	Nov 01, 2022	M107591
K2222068	Certificate of Analysis	Nov 01, 2022	M107591
K2222061	Certificate of Analysis	Nov 01, 2022	M107591
K2222055	Certificate of Analysis	Nov 01, 2022	M107591
G2311042	Certificate of Analysis	Nov 01, 2022	M107591
J2210288	Certificate of Analysis	Jan 07, 2022	M107591
I2221042	Certificate of Analysis	Jan 07, 2022	M107591
B2216456	Certificate of Analysis	Jan 07, 2022	M107591
B2216451	Certificate of Analysis	Jan 07, 2022	M107591

Chemical and Physical Properties

Solubility	Miscible with water, acetone and ethanol. Immiscible with ether.
Refractive Index	1.43
Flash Point(°F)	208 °F
Flash Point(°C)	98 °C
Boil Point(°C)	183°C
Melt Point(°C)	-5°C(lit.)

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS07
Signal	Danger
Hazard Statements	H312:Harmful in contact with skin H303:May be harmful if swallowed H360:May damage fertility or the unborn child
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P201:Obtain special instructions before use. P362+P364:Take off contaminated clothing and wash it before reuse. P202:Do not handle until all safety precautions have been read and understood. P203:Obtain, read and follow all safety instructions before use. P318:if exposed or concerned, get medical advice. P317:Get emergency medical help.
WGK Germany	1
RTECS	LQ3000000
Reaxy-Rn	1098352
Merck Index	6076

Citations of This Product

1. Yijiang Chen, Shan Yu, Yunqian Zhong, Yi Wang, Jiale Ye, Ying Zhou. (2023) Study of Indium Phosphide Quantum Dots/Carbon Quantum Dots System for Enhanced Photocatalytic Hydrogen Production from Hydrogen Sulfide. Processes, 11 (11): (3160). [PMID:2511201]
2. Qu Hongxiao, Liu Tong, Hu Ruijue, Qu Hao, Zhang Yichi, Yang Hui, Su Haiquan, Su Yue. (2023) Delaminated and Pit-rich Nano-kaolinites obtained via an Intercalation-etching Method and their Application to Fischer–Tropsch Synthesis. CLAYS AND CLAY MINERALS, 71 (4): (448-460). [PMID:]
3. Jianhang Qi, Jiale Liu, Kai Chen, Yongming Ma, Yanjie Cheng, Wei Wang, Zhaozhen Cui, Chaoyang Wang, Yaqiong Su, Anyi Mei, Hongwei Han. (2023) Dissolution Modulation of Formamidinium-Based Perovskite for Regulated Crystallinity in Printable Mesoscopic Solar Cells. Solar RRL, 7 (18): (2300370). [PMID:]
4. Anqiang Jiang, Heng Guo, Shan Yu, Fengying Zhang, Tingyu Shuai, Yubin Ke, Peng Yang, Ying Zhou. (2023) Dual charge-accepting engineering modified AgIn5S8/CdS quantum dots for efficient photocatalytic hydrogen evolution overall H2S splitting. APPLIED CATALYSIS B-ENVIRONMENTAL, 332 (122747). [PMID:]
5. Yinglong Zhang, Jiajing Tang, Wei Fang, Qing Zhao, Xiaoyu Lei, Jinzheng Zhang, Jieqiong Chen, Yubao Li, Yi Zuo. (2023) Synergetic Effect of Electrical and Topographical Cues in Aniline Trimer-Based Polyurethane Fibrous Scaffolds on Tissue Regeneration. Journal of Functional Biomaterials, 14 (4): (185). [PMID:37103277]
6. Cun Gao, Xiao-Bing Mu, Wen-Yu Yuan, Peng Zhang, Ying Wang, Quan-Guo Zhai. (2023) Construction of new multi-cage-based MOFs using flexible triangular ligands for efficient gas adsorption and separation. JOURNAL OF SOLID STATE CHEMISTRY, 322 (123994). [PMID:]
7. Feifan Chen, Yadong Zhang, Lijun Hu, Lifang Zheng, Feiyue Ge, Changsheng Feng, Dan Xu, Chen-Lei Tao, Xue-Jun Wu. (2023) Single-precursor phase-controlled synthesis of copper selenide nanocrystals and their conversion to amorphous hollow nanostructures. SmartMat, 4 (3): (e1193). [PMID:]
8. Xinxu Wang, Chenghan Wang, Yichen Xu, Yuxin Li, Haotian Li, Bingjun Fan, Fan Yang, Liping Li. (2022) The multifunctional Prussian blue/graphitic carbon nitride nanocomposites for fluorescence imaging-guided photothermal and photodynamic combination therapy. RSC Advances, 13 (1): (335-343). [PMID:36605658]
9. Zhifang Tu, Fei Han, Chao Liu, Yingxue Wang, Jianwen Wei, Xiaobin Zhou. (2023) 2-Amino-2-methyl-1-propanol regulated triethylenetetramine-based nonaqueous absorbents for solid-liquid phase-change CO2 capture: Formation of crystalline powder products and mechanism analysis. SEPARATION AND PURIFICATION TECHNOLOGY, 307 (122722). [PMID:]
10. Yangyi Huang, Yuning Zhang, Haoran Liu, Weiping Luo. (2022) Measurement and Correlation of Solubilities of Isophthalic Acid and m-Toluic Acid in Different Organic Solvents from 287.65 to 347.45 K. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 67 (1): (231–244). [PMID:]
11. Xiaoyi Gao, Xin Li, Siyi Cheng, Bihong Lv, Guohua Jing, Zuoming Zhou. (2022) A novel solid–liquid ‘phase controllable’ biphasic amine absorbent for CO2 capture. CHEMICAL ENGINEERING JOURNAL, 430 (132932). [PMID:]
12. Aocong Guan, Yucong Nie, Yue Shen, Sile Shi, Weiping Luo. (2021) Solubility of Phthalic Acid and o-Toluic Acid in Seven Organic Solvents: Experimental Measurement and Thermodynamic Modeling. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 66 (12): (4273–4285). [PMID:]
13. Siru Ren,Song Xue,Xiaodong Sun,Mengjie Rui,Li Wang,Qi Zhang. (2019-09-16) Investigation of the synergistic effect of chiral ionic liquids as additives in non-aqueous capillary electrophoresis for enantioseparation.. Journal of chromatography. A, 1609 (460519-460519). [PMID:31521379]
14. Siru Ren,Qi Zhang,Song Xue,Siyao Liu,Mengjie Rui. (2020-04-25) Use of Gamithromycin as a Chiral Selector in Capillary Electrophoresis.. Journal of chromatography. A, 1624 (461099-461099). [PMID:32327223]

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12. Jun He,Jing-ping Zhou,Pei Wang. (2009-04-09) [High performance liquid chromatography for determination of N-acetyl-S-(N-methylformamide) cysteine in human urine derivative oscillopolarography for determination of urine arsenic].. Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 27 ((2)): (103-104). [PMID:19351480]
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17. Xing-Guo Zhang,Hui-Xiong Dai,Masayuki Wasa,Jin-Quan Yu. (2012-07-12) Pd(II)-catalyzed ortho trifluoromethylation of arenes and insights into the coordination mode of acidic amide directing groups.. Journal of the American Chemical Society, 134 ((29)): (11948-11951). [PMID:22780303]
18. A Nakazawa,I Nishii. (2012-07-25) Amidic and acetonic cryoprotectants improve cryopreservation of volvocine green algae.. Cryo letters, 33 ((3)): (202-213). [PMID:22825787]
19. Rachel Crespo-Otero,Artur Mardyukov,Elsa Sanchez-Garcia,Mario Barbatti,Wolfram Sander. (2012-10-04) Photochemistry of N-methylformamide: matrix isolation and nonadiabatic dynamics.. Chemphyschem : a European journal of chemical physics and physical chemistry, 14 ((4)): (827-836). [PMID:23033207]
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21. Hideki Igisu,Takafumi Ezaki. (2005-01-22) [N-methylformamide in urine].. Nihon rinsho. Japanese journal of clinical medicine, 62 Suppl 12 (488-490). [PMID:15658371]
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31. Yijiang Chen, Shan Yu, Yunqian Zhong, Yi Wang, Jiale Ye, Ying Zhou. (2023) Study of Indium Phosphide Quantum Dots/Carbon Quantum Dots System for Enhanced Photocatalytic Hydrogen Production from Hydrogen Sulfide. Processes, 11 (11): (3160). [PMID:2511201]
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