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(R)-(-)-2-Phenylglycinol - 98%, high purity , CAS No.56613-80-0
Basic Description Synonyms 56613-80-0 | (R)-(-)-2-Phenylglycinol | D-Phenylglycinol | (R)-2-Phenylglycinol | (R)-2-Amino-2-phenylethanol | (2R)-2-amino-2-phenylethanol | (2R)-2-Amino-2-Phenylethan-1-Ol | (-)-phenylglycinol | (R)-(-)-2-Amino-2-phenylethanol | (r)-phenylglycinol | h-d-phg-ol | (R)-beta-Am Specifications & Purity ≥98% Storage Temp Store at 2-8°C,Argon charged Shipped In Wet ice Product Description Amino alcohol used to prepare a chiral imine or oxazolidine from ethyl trifluoropyruvate. These intermediates were then employed in a synthesis of both enantiomers of α-trifluoromethylproline. Chiral β?amino alcohol used as a synthetic building block.
Associated Targets(Human) Associated Targets(non-human) Names and Identifiers IUPAC Name (2R)-2-amino-2-phenylethanol INCHI InChI=1S/C8H11NO/c9-8(6-10)7-4-2-1-3-5-7/h1-5,8,10H,6,9H2/t8-/m0/s1 InChi Key IJXJGQCXFSSHNL-QMMMGPOBSA-N Canonical SMILES C1=CC=C(C=C1)C(CO)N Isomeric SMILES C1=CC=C(C=C1)[C@H](CO)N WGK Germany 3 PubChem CID 2724025 Molecular Weight 137.18 Beilstein 2935848 Reaxy-Rn 2935848
Chemical and Physical Properties Solubility Slightly soluble in water. Sensitivity heat & air sensitive Specific Rotation[α] -29.5 ° (C=1, EtOH) Melt Point(°C) 76-79°C
Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P362+P364: Take off contaminated clothing and wash it before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P337+P317: If eye irritation persists: Get medical help.
P332+P317: If skin irritation occurs: Get medical help.
P319: Get medical help if you feel unwell.
WGK Germany 3 Reaxy-Rn 2935848
References 1. Grégory Chaume, Marie-Céline Van Severen, Sinisa Marinkovic, Thierry Brigaud,. (2006-12-15) Straightforward synthesis of (S)- and (R)-alpha-trifluoromethyl proline from chiral oxazolidines derived from ethyl trifluoropyruvate.. Organic letters, 8 ((26)): ( 6123-6126 ). [PMID:17165945 ]
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H2011082