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Sodium trifluoromethanesulfonate - 98%, high purity , CAS No.2926-30-9

19 Citations
  • ≥98%
Item Number
S102743
Grouped product items
SKUSizeAvailabilityPrice Qty
S102743-5g
5g
In stock
$9.90
S102743-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$12.90
S102743-25g
25g
In stock
$27.90
S102743-100g
100g
In stock
$99.90
S102743-500g
500g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$447.90
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Element classified compounds Non heterocyclic fluorine-containing block

Basic Description

SynonymsMethanesulfonic acid, trifluoro-, sodium salt | Sodium triflate | AKOS005063791 | CS-W017632 | MFCD00061607 | Methanesulfonic acid, 1,1,1-trifluoro-, sodium salt (1:1) | Trifluoromethanesulfonic acid sodium salt | Sodium trifluoromethanesulfonate, Trace m
Specifications & Purity≥98%
Storage TempArgon charged
Shipped InNormal
Product Description

Product Introduction

Sodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions.


Application

Sodium trifluoromethanesulfonate can be employed as a reagent for the preparation of:

• Aryl fluorides via silver-catalyzed fluorination of arylstannanes.

• Ionic liquids such as N, N -dialkylpyrrolidinium triflate, N,N-dialkylimidazolium triflate, and N-alkylpyridinium triflate.

It can be also used as supporting electrolyte in electrochemical O-glycosylation of primary alcohols with O-protected thioglycosides.

Associated Targets(Human)

CA2 Tclin Carbonic anhydrase II (17698 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
CA1 Tclin Carbonic anhydrase I (13240 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Associated Targets(non-human)

Carbonic anhydrase (69 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Mechanisms of Action

Mechanism of ActionAction Typetarget IDTarget NameTarget TypeTarget OrganismBinding Site NameReferences

Names and Identifiers

Pubchem Sid488200493
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488200493
IUPAC Name sodium;trifluoromethanesulfonate
INCHI InChI=1S/CHF3O3S.Na/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChi Key XGPOMXSYOKFBHS-UHFFFAOYSA-M
Canonical SMILES C(F)(F)(F)S(=O)(=O)[O-].[Na+]
Isomeric SMILES C(F)(F)(F)S(=O)(=O)[O-].[Na+]
WGK Germany 3
PubChem CID 23676748
Molecular Weight 172.06
Beilstein 3728797
Reaxy-Rn 3728797

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

26 results found

Lot NumberCertificate TypeDateItem
I2413252Certificate of AnalysisAug 31, 2024 S102743
I2413251Certificate of AnalysisAug 31, 2024 S102743
I2413250Certificate of AnalysisAug 31, 2024 S102743
I2413249Certificate of AnalysisAug 31, 2024 S102743
I2413248Certificate of AnalysisAug 31, 2024 S102743
K2418410Certificate of AnalysisJun 19, 2024 S102743
K2418409Certificate of AnalysisJun 19, 2024 S102743
K2418408Certificate of AnalysisJun 19, 2024 S102743
I2312633Certificate of AnalysisAug 14, 2023 S102743
I2312635Certificate of AnalysisAug 14, 2023 S102743
I2312634Certificate of AnalysisAug 14, 2023 S102743
E2414047Certificate of AnalysisAug 14, 2023 S102743
B2303964Certificate of AnalysisFeb 15, 2023 S102743
B2303965Certificate of AnalysisFeb 15, 2023 S102743
G2315034Certificate of AnalysisFeb 09, 2023 S102743
I2311063Certificate of AnalysisFeb 09, 2023 S102743
E23291166Certificate of AnalysisFeb 09, 2023 S102743
C23021180Certificate of AnalysisFeb 09, 2023 S102743
C23021179Certificate of AnalysisFeb 09, 2023 S102743
C23021178Certificate of AnalysisFeb 09, 2023 S102743
C23021174Certificate of AnalysisFeb 09, 2023 S102743
C23021173Certificate of AnalysisFeb 09, 2023 S102743
C23021172Certificate of AnalysisFeb 09, 2023 S102743
C23021171Certificate of AnalysisFeb 09, 2023 S102743
K2217240Certificate of AnalysisNov 09, 2021 S102743
K2217241Certificate of AnalysisNov 09, 2021 S102743

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Chemical and Physical Properties

SolubilitySoluble in water (1000g/L).
SensitivityHygroscopic.
Melt Point(°C)253-255°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
Reaxy-Rn 3728797

Related Documents

 SDS

 Specification Sheet

FAQs and Articles

FAQ
Tert-Butyl Nitrite (TBN)
Categories: Technical articles
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Chemical synthesis OxidizingAgents TBN

Citations of This Product

How to Cite Aladdin Scientific Products?
1. Cholho Choe, Ling Yang, Zhanao Lv, Wanling Mo, Zhuqi Chen, Guangxin Li, Guochuan Yin,.  (2015-04-24)  Redox-inactive metal ions promoted the catalytic reactivity of non-heme manganese complexes towards oxygen atom transfer..  Dalton transactions (Cambridge, England : 2003),  44  ((19)): ( 9182-9192 ).  [PMID:25904197]
2. Jisheng Zhang,Yujuan Wang,Nengchao Luo,Zhuqi Chen,Kangbing Wu,Guochuan Yin.  (2015-05-06)  Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases..  Dalton transactions (Cambridge, England : 2003),  44  ((21)): (9847-9859).  [PMID:25939391]
3. Guoqing Wang, Miao Jiang, Zhao Sun, Leilei Qian, Guangjun Ji, Lei Ma, Cunyao Li, Hong Du, Li Yan, Yunjie Ding.  (2023)  Tandem Conversion of Fructose to Bio-diketones Using a Multifunctional Pd-POPs-CF3SO3H Catalyst.  ChemCatChem,  15  (20): (e202300793).  [PMID:] [10.1002/cctc.202300793]
4. Depeng Li, Qingqing Guan, Xiaoyun Hu, Yuhong Su, Zhen Su.  (2023)  Reversible and irreversible stimuli-responsive chromism of a square-planar platinum(II) salt.  RSC Advances,  13  (36): (24878-24886).  [PMID:37614796] [10.1039/D3RA03554A]
5. Dengfeng Yu, Bo Yang, Huimin Liang, Gongyuan Zhao, Hong Zhang, Yuanlin Wang, Ye Sun, Miao Yu.  (2022)  Fabrication of Co0.85Se@CN double-walled hollow cages to address the volume expansion of anode and enhance ion diffusion for sodium-ion storage.  ELECTROCHIMICA ACTA,  426  (140839).  [PMID:] [10.1016/j.electacta.2022.140839]
6. Jianghe Liu, Zijian Ye, Xingcheng Hu, Sultan Ahmed, Shenhua Song.  (2022)  High-Performance Na-Ion Conducting Polymer Gel Membrane for Supercapacitor Applications.  ACS Applied Polymer Materials,  4  (1): (280–288).  [PMID:] [10.1021/acsapm.1c01267]
7. Huang Zhaodong, Hou Yue, Wang Tairan, Zhao Yuwei, Liang Guojin, Li Xinliang, Guo Ying, Yang Qi, Chen Ze, Li Qing, Ma Longtao, Fan Jun, Zhi Chunyi.  (2021)  Manipulating anion intercalation enables a high-voltage aqueous dual ion battery.  Nature Communications,  12  (1): (1-11).  [PMID:34035250] [10.1038/s41467-021-23369-5]
8. Zhen Su, Yushu Li, Jiguang Li, Xincun Dou.  (2021)  Ultrasensitive luminescent turn-on detection of perchlorate particulates by triggering supramolecular self-assembly of platinum(II) complex in hydrogel matrix.  SENSORS AND ACTUATORS B-CHEMICAL,  336  (129728).  [PMID:] [10.1016/j.snb.2021.129728]
9. Yajun Zhao, Tao Sun, Qing Yin, Jian Zhang, Shuoxiao Zhang, Jianeng Luo, Hong Yan, Lirong Zheng, Jingbin Han, Min Wei.  (2019)  Discovery of a new intercalation-type anode for high-performance sodium ion batteries.  Journal of Materials Chemistry A,  7  (25): (15371-15377).  [PMID:] [10.1039/C9TA03753E]
10. Haibin Wang, Shaodong Liu, Tingting Sun, Zhanao Lv, Zhen Zhan, Guochuan Yin, Zhuqi Chen.  (2019)  Lewis acid promoted double bond migration in O-allyl to Z-products by Ru-H complexes.  Molecular Catalysis,  469  (10).  [PMID:] [10.1016/j.mcat.2019.02.007]
11. Bingcheng Ge, Yangyang Wang, Yong Sun, Yunping Li, Jianyu Huang, Qiuming Peng.  (2019)  A proof-of-concept of Na-N2 rechargeable battery.  Energy Storage Materials,  23  (733).  [PMID:] [10.1016/j.ensm.2019.02.018]
12. Suli Chen, Fan Feng, Yimei Yin, Haiying Che, Xiao-Zhen Liao, Zi-Feng Ma.  (2018)  A solid polymer electrolyte based on star-like hyperbranched β-cyclodextrin for all-solid-state sodium batteries.  JOURNAL OF POWER SOURCES,  399  (363).  [PMID:] [10.1016/j.jpowsour.2018.07.096]
13. Jianguang Qi, Yufeng Hu, Weiting Ma, Haiyan Wang, Siqi Jiang, Liuyi Yin, Xianming Zhang, Zhenyu Yang, Yichuan Wang.  (2018)  The reactions that determine the yield and selectivity of 1,3,5-trioxane.  CHEMICAL ENGINEERING JOURNAL,  331  (311).  [PMID:] [10.1016/j.cej.2017.08.101]
14. Zhanao Lv, Zhuqi Chen, Yue Hu, Wenrui Zheng, Haibin Wang, Wanling Mo, Guochuan Yin.  (2017)  A General Strategy for Open-Flask Alkene Isomerization by Ruthenium Hydride Complexes with Non-Redox Metal Salts.  ChemCatChem,  9  (20): (3849-3859).  [PMID:] [10.1002/cctc.201700687]
15. Zhanao Lv, Haibin Wang, Zhuqi Chen, Shuhua Zou, Shuaishuai Zhu, Chenlin Lou, Guochuan Yin.  (2017)  Non-redox metal ions promoted dehydrogenation of saturated C–C bond by a ruthenium catalyst with dioxygen activation.  Molecular Catalysis,  432  (259).  [PMID:] [10.1016/j.mcat.2016.12.027]
16. Na Li, Dan Xu, Di Bao, Jinling Ma, Xinbo Zhang.  (2016)  A binder-free, flexible cathode for rechargeable Na-O2 batteries.  CHINESE JOURNAL OF CATALYSIS,  37  (1172).  [PMID:] [10.1016/S1872-2067(15)61089-0]
17. Shuhao Qin, Lei Dong, Zhuqi Chen, Sicheng Zhang, Guochuan Yin.  (2015)  Non-redox metal ions can promote Wacker-type oxidations even better than copper(II): a new opportunity in catalyst design.  DALTON TRANSACTIONS,  44  (40): (17508-17515).  [PMID:26390300] [10.1039/C5DT02612A]
18. Jun Yang, Zan Hua, Tao Wang, Bo Wu, Guangming Liu, Guangzhao Zhang.  (2015)  Counterion-Specific Protein Adsorption on Polyelectrolyte Brushes.  LANGMUIR,  31  (22): (6078–6084).  [PMID:25985929] [10.1021/acs.langmuir.5b01145]
19. Lei Dong, Yujuan Wang, Yanzong Lv, Zhuqi Chen, Fuming Mei, Hui Xiong, Guochuan Yin.  (2013)  Lewis-Acid-Promoted Stoichiometric and Catalytic Oxidations by Manganese Complexes Having Cross-Bridged Cyclam Ligand: A Comprehensive Study.  INORGANIC CHEMISTRY,  52  (9): (5418–5427).  [PMID:23600453] [10.1021/ic400361s]

References

1. Cholho Choe, Ling Yang, Zhanao Lv, Wanling Mo, Zhuqi Chen, Guangxin Li, Guochuan Yin,.  (2015-04-24)  Redox-inactive metal ions promoted the catalytic reactivity of non-heme manganese complexes towards oxygen atom transfer..  Dalton transactions (Cambridge, England : 2003),  44  ((19)): ( 9182-9192 ).  [PMID:25904197]
2. Jisheng Zhang,Yujuan Wang,Nengchao Luo,Zhuqi Chen,Kangbing Wu,Guochuan Yin.  (2015-05-06)  Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases..  Dalton transactions (Cambridge, England : 2003),  44  ((21)): (9847-9859).  [PMID:25939391]
3. Laura Mortara,Filipe da Silva Lima,Iolanda Midea Cuccovia,Andreas Nazet,Dominik Horinek,Richard Buchner,Hernan Chaimovich.  (2018-08-22)  Specific Ion Effects on Zwitterionic Micelles Are Independent of Interfacial Hydration Changes..  Langmuir : the ACS journal of surfaces and colloids,  34  ((37)): (11049-11057).  [PMID:30126270]
4. Chiwon Kang,Yongwoo Lee,Ilhwan Kim,Seungmin Hyun,Tae Hoon Lee,Soyeong Yun,Won-Sub Yoon,Youngkwang Moon,Jinkee Lee,Sunkook Kim,Hoo-Jeong Lee.  (2019-04-26)  Highly Efficient Nanocarbon Coating Layer on the Nanostructured Copper Sulfide-Metal Organic Framework Derived Carbon for Advanced Sodium-Ion Battery Anode..  Materials (Basel, Switzerland),  12  ((8)):   [PMID:31018566]
5. Willem Delabie,Wim Maes,Rosalie Devloo,Michelle R Van den Hauwe,Karen Vanhoorelbeke,Veerle Compernolle,Hendrik B Feys.  (2019-10-28)  The senotherapeutic nicotinamide riboside raises platelet nicotinamide adenine dinucleotide levels but cannot prevent storage lesion..  Transfusion,  60  ((1)): (165-174).  [PMID:31652008]
6. Giuseppe Paglia,Giuseppe Astarita.  (2017-03-17)  Metabolomics and lipidomics using traveling-wave ion mobility mass spectrometry..  Nature protocols,  12  ((4)): (797-813).  [PMID:28301461]
7. Bing Sun,Katja Kretschmer,Xiuqiang Xie,Paul Munroe,Zhangquan Peng,Guoxiu Wang.  (2017-04-05)  Hierarchical Porous Carbon Spheres for High-Performance Na-O.  Advanced materials (Deerfield Beach, Fla.),  29  ((48)):   [PMID:28374959]
8. Chenjuan Liu,Marco Carboni,William R Brant,Ruijun Pan,Jonas Hedman,Jiefang Zhu,Torbjörn Gustafsson,Reza Younesi.  (2018-04-05)  On the Stability of NaO2 in Na-O2 Batteries..  ACS applied materials & interfaces,  10  ((16)): (13534-13541).  [PMID:29616791]
9. Risa Iima,Shigehiko Takegami,Atsuko Konishi,Shiori Tajima,Nao Minematsu,Tatsuya Kitade.  (2018-06-27)  Thermal Behavior of 19F Nuclear Magnetic Resonance Signal of 19F-Containing Compound in Lipid Nano-Emulsion for Potential Tumor Diagnosis..  AAPS PharmSciTech,  19  ((6)): (2679-2686).  [PMID:29943279]
10. Guoqing Wang, Miao Jiang, Zhao Sun, Leilei Qian, Guangjun Ji, Lei Ma, Cunyao Li, Hong Du, Li Yan, Yunjie Ding.  (2023)  Tandem Conversion of Fructose to Bio-diketones Using a Multifunctional Pd-POPs-CF3SO3H Catalyst.  ChemCatChem,  15  (20): (e202300793).  [PMID:] [10.1002/cctc.202300793]
11. Depeng Li, Qingqing Guan, Xiaoyun Hu, Yuhong Su, Zhen Su.  (2023)  Reversible and irreversible stimuli-responsive chromism of a square-planar platinum(II) salt.  RSC Advances,  13  (36): (24878-24886).  [PMID:37614796] [10.1039/D3RA03554A]
12. Dengfeng Yu, Bo Yang, Huimin Liang, Gongyuan Zhao, Hong Zhang, Yuanlin Wang, Ye Sun, Miao Yu.  (2022)  Fabrication of Co0.85Se@CN double-walled hollow cages to address the volume expansion of anode and enhance ion diffusion for sodium-ion storage.  ELECTROCHIMICA ACTA,  426  (140839).  [PMID:] [10.1016/j.electacta.2022.140839]
13. Jianghe Liu, Zijian Ye, Xingcheng Hu, Sultan Ahmed, Shenhua Song.  (2022)  High-Performance Na-Ion Conducting Polymer Gel Membrane for Supercapacitor Applications.  ACS Applied Polymer Materials,  4  (1): (280–288).  [PMID:] [10.1021/acsapm.1c01267]
14. Huang Zhaodong, Hou Yue, Wang Tairan, Zhao Yuwei, Liang Guojin, Li Xinliang, Guo Ying, Yang Qi, Chen Ze, Li Qing, Ma Longtao, Fan Jun, Zhi Chunyi.  (2021)  Manipulating anion intercalation enables a high-voltage aqueous dual ion battery.  Nature Communications,  12  (1): (1-11).  [PMID:34035250] [10.1038/s41467-021-23369-5]
15. Zhen Su, Yushu Li, Jiguang Li, Xincun Dou.  (2021)  Ultrasensitive luminescent turn-on detection of perchlorate particulates by triggering supramolecular self-assembly of platinum(II) complex in hydrogel matrix.  SENSORS AND ACTUATORS B-CHEMICAL,  336  (129728).  [PMID:] [10.1016/j.snb.2021.129728]
16. Yajun Zhao, Tao Sun, Qing Yin, Jian Zhang, Shuoxiao Zhang, Jianeng Luo, Hong Yan, Lirong Zheng, Jingbin Han, Min Wei.  (2019)  Discovery of a new intercalation-type anode for high-performance sodium ion batteries.  Journal of Materials Chemistry A,  7  (25): (15371-15377).  [PMID:] [10.1039/C9TA03753E]
17. Haibin Wang, Shaodong Liu, Tingting Sun, Zhanao Lv, Zhen Zhan, Guochuan Yin, Zhuqi Chen.  (2019)  Lewis acid promoted double bond migration in O-allyl to Z-products by Ru-H complexes.  Molecular Catalysis,  469  (10).  [PMID:] [10.1016/j.mcat.2019.02.007]
18. Bingcheng Ge, Yangyang Wang, Yong Sun, Yunping Li, Jianyu Huang, Qiuming Peng.  (2019)  A proof-of-concept of Na-N2 rechargeable battery.  Energy Storage Materials,  23  (733).  [PMID:] [10.1016/j.ensm.2019.02.018]
19. Suli Chen, Fan Feng, Yimei Yin, Haiying Che, Xiao-Zhen Liao, Zi-Feng Ma.  (2018)  A solid polymer electrolyte based on star-like hyperbranched β-cyclodextrin for all-solid-state sodium batteries.  JOURNAL OF POWER SOURCES,  399  (363).  [PMID:] [10.1016/j.jpowsour.2018.07.096]
20. Jianguang Qi, Yufeng Hu, Weiting Ma, Haiyan Wang, Siqi Jiang, Liuyi Yin, Xianming Zhang, Zhenyu Yang, Yichuan Wang.  (2018)  The reactions that determine the yield and selectivity of 1,3,5-trioxane.  CHEMICAL ENGINEERING JOURNAL,  331  (311).  [PMID:] [10.1016/j.cej.2017.08.101]
21. Zhanao Lv, Zhuqi Chen, Yue Hu, Wenrui Zheng, Haibin Wang, Wanling Mo, Guochuan Yin.  (2017)  A General Strategy for Open-Flask Alkene Isomerization by Ruthenium Hydride Complexes with Non-Redox Metal Salts.  ChemCatChem,  9  (20): (3849-3859).  [PMID:] [10.1002/cctc.201700687]
22. Zhanao Lv, Haibin Wang, Zhuqi Chen, Shuhua Zou, Shuaishuai Zhu, Chenlin Lou, Guochuan Yin.  (2017)  Non-redox metal ions promoted dehydrogenation of saturated C–C bond by a ruthenium catalyst with dioxygen activation.  Molecular Catalysis,  432  (259).  [PMID:] [10.1016/j.mcat.2016.12.027]
23. Na Li, Dan Xu, Di Bao, Jinling Ma, Xinbo Zhang.  (2016)  A binder-free, flexible cathode for rechargeable Na-O2 batteries.  CHINESE JOURNAL OF CATALYSIS,  37  (1172).  [PMID:] [10.1016/S1872-2067(15)61089-0]
24. Shuhao Qin, Lei Dong, Zhuqi Chen, Sicheng Zhang, Guochuan Yin.  (2015)  Non-redox metal ions can promote Wacker-type oxidations even better than copper(II): a new opportunity in catalyst design.  DALTON TRANSACTIONS,  44  (40): (17508-17515).  [PMID:26390300] [10.1039/C5DT02612A]
25. Jun Yang, Zan Hua, Tao Wang, Bo Wu, Guangming Liu, Guangzhao Zhang.  (2015)  Counterion-Specific Protein Adsorption on Polyelectrolyte Brushes.  LANGMUIR,  31  (22): (6078–6084).  [PMID:25985929] [10.1021/acs.langmuir.5b01145]
26. Lei Dong, Yujuan Wang, Yanzong Lv, Zhuqi Chen, Fuming Mei, Hui Xiong, Guochuan Yin.  (2013)  Lewis-Acid-Promoted Stoichiometric and Catalytic Oxidations by Manganese Complexes Having Cross-Bridged Cyclam Ligand: A Comprehensive Study.  INORGANIC CHEMISTRY,  52  (9): (5418–5427).  [PMID:23600453] [10.1021/ic400361s]

Solution Calculators

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