Determine the necessary mass, volume, or concentration for preparing a solution.
Activity Type | Relation | Activity value | Units | Action Type | Journal | PubMed Id | doi | Assay Aladdin ID |
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SKU | Size | Availability | Price | Qty |
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T106827-5g | 5g | Available within 1-2 weeks(?) Item is derived from our semi-finished stock and is processed in 1-2 weeks. | $9.90 | |
T106827-10g | 10g | In stock | $14.90 | |
T106827-25g | 25g | Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience! | $18.90 | |
T106827-100g | 100g | Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience! | $39.90 | |
T106827-500g | 500g | Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience! | $163.90 |
Stable nitroxyl radical
Synonyms | 2,2,6,6-Tetramethylpiperidine 1-oxyl | TEMPO free radical | 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical |
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Specifications & Purity | ≥98% |
Biochemical and Physiological Mechanisms | Widely used as a radical trap, as a structural probe for biological systems in conjunction with electron spin resonance spectroscopy and as a catalyst for the oxidation of primary alcohols to aldehydes. |
Storage Temp | Store at 2-8°C,Argon charged |
Shipped In | Wet ice |
Note | Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20°C. Generally, these will be useable for up to one month. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour. Need more advice on solubility, usage and handling? Please visit our frequently asked questions (FAQ) page for more details. |
Product Description | Catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. TEMPO (2,2,6,6-Tetramethyl-1-piperidinyloxy) was used for trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene. TEMPO-mediated oxidation was employed for the carboxylation of water-resistant nanofibrillated cellulose (NFC) films. |
Activity Type | Relation | Activity value | Units | Action Type | Journal | PubMed Id | doi | Assay Aladdin ID |
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Mechanism of Action | Action Type | target ID | Target Name | Target Type | Target Organism | Binding Site Name | References |
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Pubchem Sid | 488192247 |
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Pubchem Sid Url | https://pubchem.ncbi.nlm.nih.gov/substance/488192247 |
INCHI | InChI=1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3 |
InChi Key | QYTDEUPAUMOIOP-UHFFFAOYSA-N |
Canonical SMILES | CC1(CCCC(N1[O])(C)C)C |
Isomeric SMILES | CC1(CCCC(N1[O])(C)C)C |
WGK Germany | 3 |
RTECS | TN8991900 |
PubChem CID | 2724126 |
UN Number | 3263 |
Molecular Weight | 156.25 |
Beilstein | 1422418 |
Reaxy-Rn | 1422418 |
Enter Lot Number to search for COA:
Find and download the COA for your product by matching the lot number on the packaging.
Lot Number | Certificate Type | Date | Item |
---|---|---|---|
G2431541 | Certificate of Analysis | Jul 12, 2024 | T106827 |
G2431540 | Certificate of Analysis | Jul 12, 2024 | T106827 |
G2431539 | Certificate of Analysis | Jul 12, 2024 | T106827 |
G2431529 | Certificate of Analysis | Jul 12, 2024 | T106827 |
D2409280 | Certificate of Analysis | Mar 27, 2024 | T106827 |
G2402035 | Certificate of Analysis | Mar 27, 2024 | T106827 |
D2409286 | Certificate of Analysis | Mar 27, 2024 | T106827 |
D2409285 | Certificate of Analysis | Mar 27, 2024 | T106827 |
D2409284 | Certificate of Analysis | Mar 27, 2024 | T106827 |
D2409283 | Certificate of Analysis | Mar 27, 2024 | T106827 |
D2409282 | Certificate of Analysis | Mar 27, 2024 | T106827 |
D2409281 | Certificate of Analysis | Mar 27, 2024 | T106827 |
H2304110 | Certificate of Analysis | Jul 20, 2023 | T106827 |
H2304109 | Certificate of Analysis | Jul 20, 2023 | T106827 |
H2304105 | Certificate of Analysis | Jul 20, 2023 | T106827 |
H2304106 | Certificate of Analysis | Jul 20, 2023 | T106827 |
H2304107 | Certificate of Analysis | Jul 20, 2023 | T106827 |
H2304108 | Certificate of Analysis | Jul 20, 2023 | T106827 |
L2214433 | Certificate of Analysis | Nov 24, 2022 | T106827 |
L2214431 | Certificate of Analysis | Nov 24, 2022 | T106827 |
L2214426 | Certificate of Analysis | Nov 24, 2022 | T106827 |
L2214425 | Certificate of Analysis | Nov 24, 2022 | T106827 |
L2214424 | Certificate of Analysis | Nov 24, 2022 | T106827 |
D2318455 | Certificate of Analysis | Nov 24, 2022 | T106827 |
G2322032 | Certificate of Analysis | Nov 24, 2022 | T106827 |
G2304019 | Certificate of Analysis | Nov 24, 2022 | T106827 |
E2330089 | Certificate of Analysis | Nov 24, 2022 | T106827 |
E23291168 | Certificate of Analysis | Nov 24, 2022 | T106827 |
E2312227 | Certificate of Analysis | Nov 24, 2022 | T106827 |
I2202145 | Certificate of Analysis | Mar 20, 2021 | T106827 |
I2226235 | Certificate of Analysis | Mar 20, 2021 | T106827 |
J2215170 | Certificate of Analysis | Mar 20, 2021 | T106827 |
J2218303 | Certificate of Analysis | Mar 20, 2021 | T106827 |
K2229861 | Certificate of Analysis | Mar 20, 2021 | T106827 |
G2115362 | Certificate of Analysis | Mar 20, 2021 | T106827 |
Solubility | Soluble in all organic solvents. Insoluble in water. |
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Sensitivity | heat sensitive;Air sensitive |
Flash Point(°F) | 152.6 °F |
Flash Point(°C) | 67℃ |
Boil Point(°C) | 193°C |
Melt Point(°C) | 39°C |
Pictogram(s) | GHS05, GHS07 |
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Signal | Danger |
Hazard Statements | H335:May cause respiratory irritation H314:Causes severe skin burns and eye damage H412:Harmful to aquatic life with long lasting effects H318:Causes serious eye damage |
Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P271:Use only outdoors or in a well-ventilated area. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. P319:Get medical help if you feel unwell. |
WGK Germany | 3 |
RTECS | TN8991900 |
Reaxy-Rn | 1422418 |
Merck Index | 9140 |
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27. Axel Rydevik,Ulf Bondesson,Mario Thevis,Mikael Hedeland. (2013-07-23) Mass spectrometric characterization of glucuronides formed by a new concept, combining Cunninghamella elegans with TEMPO.. Journal of pharmaceutical and biomedical analysis, 84 (278-284). [PMID:23867089] |
28. Jing-Kun Yan,Pan-Fu Cai,Xiao-Qiang Cao,Hai-Le Ma,Qi Zhang,Nan-Zi Hu,Yi-Zhang Zhao. (2013-08-06) Green synthesis of silver nanoparticles using 4-acetamido-TEMPO-oxidized curdlan.. Carbohydrate polymers, 97 ((2)): (391-397). [PMID:23911462] |
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34. Benjamin J Bergner,Adrian Schürmann,Klaus Peppler,Arnd Garsuch,Jürgen Janek. (2014-09-26) TEMPO: a mobile catalyst for rechargeable Li-O₂ batteries.. Journal of the American Chemical Society, 136 ((42)): (15054-15064). [PMID:25255228] |
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44. Rui Yu,Yongquan Lai,Hadley J Hartwell,Benjamin C Moeller,Melanie Doyle-Eisele,Dean Kracko,Wanda M Bodnar,Thomas B Starr,James A Swenberg. (2015-04-24) Formation, Accumulation, and Hydrolysis of Endogenous and Exogenous Formaldehyde-Induced DNA Damage.. Toxicological sciences : an official journal of the Society of Toxicology, 146 ((1)): (170-182). [PMID:25904104] |
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47. María Pilar Sánchez-Bailón,Annarica Calcabrini,Víctor Mayoral-Varo,Agnese Molinari,Kay-Uwe Wagner,Jesús Pérez Losada,Sergio Ciordia,Juan Pablo Albar,Jorge Martín-Pérez. (2015-05-20) Cyr61 as mediator of Src signaling in triple negative breast cancer cells.. Oncotarget, 6 ((15)): (13520-13538). [PMID:25980494] |
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