Determine the necessary mass, volume, or concentration for preparing a solution.
Basic Description
| Synonyms | TEMPO|2564-83-2|2,2,6,6-Tetramethyl-1-piperidinyloxy|2,2,6,6-Tetramethylpiperidine 1-oxyl|2,2,6,6-Tetramethylpiperidoxyl|1-Piperidinyloxy, 2,2,6,6-tetramethyl-|2,2,6,6-Tetramethylpiperidinyloxy|VQN7359ICQ|(2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl|CHEBI: |
|---|---|
| Specifications & Purity | sublimed grade, ≥99% |
| Storage Temp | Store at 2-8°C |
| Shipped In | Wet ice |
| Grade | sublimed grade |
| Product Description | Description For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit ourtechnology spotlight.TEMPO (2,2,6,6-Tetramethyl-1-piperidinyloxy) was used for trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene. TEMPO-mediated oxidation was employed for the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.Stable nitroxide radical useful in controlling living polymerizations |
Names and Identifiers
| INCHI | InChI=1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3 |
|---|---|
| InChi Key | QYTDEUPAUMOIOP-UHFFFAOYSA-N |
| Canonical SMILES | CC1(CCCC(N1[O])(C)C)C |
| Isomeric SMILES | CC1(CCCC(N1[O])(C)C)C |
| WGK Germany | 3 |
| RTECS | TN8991900 |
| PubChem CID | 2724126 |
| UN Number | 3263 |
| Molecular Weight | 156.25 |
| Beilstein | 1422418 |
| Reaxy-Rn | 1422418 |
Certificates
Certificate of Analysis(COA)
Enter Lot Number to search for COA:
To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
 C2427087 | Certificate of Analysis | Jul 05, 2023 | T478495 |
| F2325034 | Certificate of Analysis | Jul 05, 2023 | T478495 |
| H2406012 | Certificate of Analysis | Jul 05, 2023 | T478495 |
| F2325054 | Certificate of Analysis | Jun 29, 2023 | T478495 |
Chemical and Physical Properties
| Flash Point(°F) | 152.6 °F |
|---|---|
| Flash Point(°C) | 67℃ |
| Boil Point(°C) | 193°C |
| Melt Point(°C) | 39°C |
Safety and Hazards(GHS)
| Pictogram(s) | GHS05, GHS07 |
|---|---|
| Signal | Danger |
| Hazard Statements | H335:May cause respiratory irritation H314:Causes severe skin burns and eye damage H412:Harmful to aquatic life with long lasting effects H318:Causes serious eye damage |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P271:Use only outdoors or in a well-ventilated area. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. P319:Get medical help if you feel unwell. |
| WGK Germany | 3 |
| RTECS | TN8991900 |
| Reaxy-Rn | 1422418 |
| Merck Index | 9140 |
Related Documents
FAQs and Articles
References
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