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Tetrabutylammonium fluoride solution - 1.0 M in THF, high purity , CAS No.429-41-4(THF)

20 Citations

1.0 M in THF

CAS#: 429-41-4(THF)
MDL number: MFCD00011747
PubChem CID: 2724141

Item Number

T106821

Grouped product items
SKU	Size	Availability	Price
T106821-25ml	25ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$24.90
T106821-100ml	100ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$57.90
T106821-500ml	500ml	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$164.90

View related series

Ammonium salt Deprotection Derivatization Nucleophilic fluorinating agent Protection

Basic Description

Synonyms	tetrabutylammonium fluride \| 1-Butanaminium, N,N,N-tributyl-, fluoride \| 1-Butanaminium, N,N,N-tributyl-, fluoride (1:1) \| T1125 \| Tetrabutyammonium fluoride \| tetra butyl ammonium fluoride \| tetrabuthylammonium fluoride \| tetrabuthyl-ammonium fluoride \|
Specifications & Purity	1.0 M in THF
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	Reactant for preparation of: • Triple monoamine reuptake inhibitors as a new generation of antidepressants • Alcohols via hydrolysis of alkyl silyl ethers neutral pH in mixed organic-aqueous buffered solutions • Oligoribonucleotides with phosphonate-modified linkages • Aryl alkyl alcohols via Nozaki-Hiyama allylation catalyzed by chiral bipyridyldiol ligands and chromium trichloride • Conjugated dienoic acid esters using Suzuki coupling reactions • Macrocyclic o-aminobenzamide Hsp90 inhibitorwith antitumor activity • Phospshoinositide 3-kinase (PI3K)/mammalian target of rapamycin (mTOR) dual inhibitors • Anti-diabetic polyacetylenic glucosides Tetrabutylammonium fluoride (TBAF) can be used as a reagent: • For the deprotection of silyl and N-sulfonyl groups. • In the fluorination reactions. • To synthesize 2-substituted indoles by cyclization reaction of various 2-ethynylanilines with terminal alkynes using Pd catalyst. It can also be used as an activator in the synthesis of arylated or alkenylated alkynes by the coupling reaction of aryl and alkenyl halides with terminal alkynes in the presence of Pd catalyst.

Associated Targets(non-human)

Staphylococcus epidermidis (22802 Activities)

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Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Escherichia coli (133304 Activities)

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Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Names and Identifiers

INCHI	1S/C16H36N.FH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChi Key	FPGGTKZVZWFYPV-UHFFFAOYSA-M
Canonical SMILES	[F-].CCCC[N+](CCCC)(CCCC)CCCC
Isomeric SMILES	CCCC[N+](CCCC)(CCCC)CCCC.[F-]
PubChem CID	2724141
UN Number	2056
Packing Group	II

Certificates

Certificate of Analysis(COA)

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Find and download the COA for your product by matching the lot number on the packaging.

23 results found

Lot Number	Certificate Type	Date	Item
H2406656	Certificate of Analysis	Jul 19, 2024	T106821
H2406655	Certificate of Analysis	Jul 19, 2024	T106821
G2213546	Certificate of Analysis	Apr 07, 2024	T106821
G2213544	Certificate of Analysis	Apr 07, 2024	T106821
F2312781	Certificate of Analysis	May 30, 2023	T106821
L2327012	Certificate of Analysis	May 30, 2023	T106821
F2312780	Certificate of Analysis	May 30, 2023	T106821
F2312779	Certificate of Analysis	May 30, 2023	T106821
F2312778	Certificate of Analysis	May 30, 2023	T106821
C2330831	Certificate of Analysis	Mar 16, 2023	T106821
C2407299	Certificate of Analysis	Mar 16, 2023	T106821
C2330892	Certificate of Analysis	Mar 16, 2023	T106821
C2330836	Certificate of Analysis	Mar 16, 2023	T106821
C2330834	Certificate of Analysis	Mar 16, 2023	T106821
K2228760	Certificate of Analysis	Sep 07, 2022	T106821
K2228761	Certificate of Analysis	Sep 07, 2022	T106821
K2228762	Certificate of Analysis	Sep 07, 2022	T106821
K2228772	Certificate of Analysis	Sep 07, 2022	T106821
G2213194	Certificate of Analysis	Jun 13, 2022	T106821
G2213195	Certificate of Analysis	Jun 13, 2022	T106821
E2223221	Certificate of Analysis	Mar 11, 2022	T106821
E2223215	Certificate of Analysis	Mar 11, 2022	T106821
E2223211	Certificate of Analysis	Mar 11, 2022	T106821

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Chemical and Physical Properties

Solubility	Miscible with terahydrofuran, acetonitrile, dimethyl sulfoxide and organic solvents.
Sensitivity	Air and moisture sensitive
Flash Point(°F)	1.4 °F
Flash Point(°C)	-17 °C

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS07, GHS02
Signal	Danger
Hazard Statements	H319:Causes serious eye irritation H335:May cause respiratory irritation H351:Suspected of causing cancer H302:Harmful if swallowed H225:Highly Flammable liquid and vapor H336:May cause drowsiness or dizziness
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P201:Obtain special instructions before use. P308+P313:IF exposed or concerned: Get medical advice/attention. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P337+P313:IF eye irritation persists: Get medical advice/attention. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P202:Do not handle until all safety precautions have been read and understood. P330:Rinse mouth. P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge.
Class	3

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Trifluoromethyl in organic synthesis

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Citations of This Product

1. Chao Zhong,Chunming Wang,Fan Huang,Honghua Jia,Ping Wei. (2013-04-03) Wheat straw cellulose dissolution and isolation by tetra-n-butylammonium hydroxide.. Carbohydrate polymers, 94 ((1)): (38-45). [PMID:23544507]
2. Anning Chen, Zhengao Wang, Hailun Chen, Bo Pang, He Cai, Ziheng Chen, Chengyun Ning, Dong Ma, Jie Tang, Hongzheng Zhang. (2023) Zwitterion modified cochlear implants resist postoperative infection and inflammation. Materials Today Bio, 23 (18): (100856). [PMID:38075255]
3. Jianquan Xu, Xiaojin Guo, Hongkai Guo, Yizhi Zhang, Xinping Wang. (2023) Exploring the Molecular Origin for the Long-Range Propagation of the Substrate Effect in Unentangled Poly(methyl methacrylate) Films. Polymers, 15 (24): (4655). [PMID:38139907]
4. Yiyang Chen, Hao Ren, Xiangyu Kong, Hao Wu, Zhenmei Lu. (2023) A multicomponent propane monooxygenase catalyzes the initial degradation of methyl tert-butyl ether in Mycobacterium vaccae JOB5. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, (1): [PMID:37823642]
5. Dongxia Li, Qiong Lin, Lingli Liu, Xuan Song, Zhongxin Wang, Xiangfeng Sun, Yuxin Xue, Yulin Fu, Yuanhao Shi, Zhiqi Li, Xuefeng Gui, Kai Xu. (2023) Intercalation of silsesquioxane surfactant in layered double hydroxide for silicone rubber composites: Enhancing interfacial interactions toward improvement of mechanical, thermal, and gas barrier properties. POLYMER COMPOSITES, 44 (12): (8389-8402). [PMID:]
6. Jingwei Li, Zhengyi Huang, Cong Wang, Lei Tian, Xiaoqing Yang, Rongfu Zhou, Mohamed Nawfal Ghazzal, Zhao-Qing Liu. (2024) Linkage effect in the bandgap-broken V2O5-GdCrO3 heterojunction by carbon allotropes for boosting photocatalytic H2 production. APPLIED CATALYSIS B-ENVIRONMENTAL, 340 (123181). [PMID:]
7. Pengzhi Bi, Xiuzhong Zhu, Jinbang Han, Li Tian, Wanbin Zhang. (2023) Synthesis and Comparative Study of Polyether-b-polybutadiene-b-polyether Triblock Copolymers for Use as Polyurethanes. Polymers, 15 (16): (3486). [PMID:37631543]
8. Maohua Chen, Menghuan Li, Xijiao Ren, Fei Zhou, Yanan Li, Lu Tan, Zhong Luo, Kaiyong Cai, Yan Hu. (2023) DNAzyme Nanoconstruct-Integrated Autonomously-Adaptive Coatings Enhance Titanium-Implant Osteointegration by Cooperative Angiogenesis and Vessel Remodeling. ACS Nano, [PMID:37566558]
9. Xiao-Wei Qu, Qing Li, Shuzhen Yu, Haixia Shen, Su Chen. (2023) Frontal Polymerization for Decomposable Lignin-Loaded Polymer Materials towards Water Purification. ChemistrySelect, 8 (29): (e202302046). [PMID:]
10. Guiquan Liu, Guorong Wang, Zhiliang Jin. (2023) Subtly synthesized graphdiyne nano-lamellas as stable electrode material for supercapacitors. ELECTROCHIMICA ACTA, 464 (142866). [PMID:]
11. Yifan Yu, Meng Lei, Decheng Li, Chilin Li. (2023) Near-Room-Temperature Quasi-Solid-State F-Ion Batteries with High Conversion Reversibility Based on Layered Structured Electrolyte. Advanced Energy Materials, 13 (12): (2203168). [PMID:]
12. Yang-Yang Hou, Wan-Zhen Xie, Ke-Jing Huang, Jing Xu. (2023) AuNPs/graphdiyne self-powered sensing platform for sensitive detection of microRNA with DNAzyme walker for signal amplification. ANALYTICA CHIMICA ACTA, 1240 (340754). [PMID:36641150]
13. Li Chen, Xiang Li, Mengmeng Xiong, Yimei Zhao, Suyi Liu, Cao Li, Kai Wang. (2023) Development of novel nanoporphyrin biomaterials for NIR-II activated photothermal therapy against tumor in vivo. MATERIALS & DESIGN, 225 (111532). [PMID:]
14. Qi Zhang, Qingxin Cui. (2023) Target protein identification of andrographolide based on isomer approach. JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 222 (115111). [PMID:36279844]
15. Shengyuan Yao, Yan Lv, Qing Wang, Jinhui Yang, Hongmei Li, Ningning Gao, Furu Zhong, Jihong Fu, Jun Tang, Tao Wang, Dianzeng Jia. (2023) Facile preparation of highly sensitive SERS substrates based on gold nanoparticles modified graphdiyne/carbon cloth. APPLIED SURFACE SCIENCE, 609 (155098). [PMID:]
16. Anning Chen, Dongxiu Chen, Kai Lv, Guowei Li, Jing Pan, Dong Ma, Jie Tang, Hongzheng Zhang. (2022) Zwitterionic Polymer/Polydopamine Coating of Electrode Arrays Reduces Fibrosis and Residual Hearing Loss after Cochlear Implantation. Advanced Healthcare Materials, 12 (1): (2200807). [PMID:36177664]
17. Chen Xiuqiong, Zhu Qingmei, Liu Zhaowen, Zhang Tong, Gong Cuiyu, Li Juan, Yan Huiqiong, Lin Qiang. (2023) Self-aggregate performance of hexyl alginate ester derivative synthesized via SN2 reaction for controlled release of λ-cyhalothrin. POLYMER BULLETIN, 80 (1): (495-514). [PMID:]
18. Na Liang, Xueyan Wu, Yan Lv, Jixi Guo, Xiuli Zhang, Yingfu Zhu, Huibiao Liu, Dianzeng Jia. (2022) A graphdiyne oxide composite membrane for active electrolyte enhanced supercapacitors with super long self-discharge time. Journal of Materials Chemistry C, 10 (7): (2821-2827). [PMID:]
19. Hang Xiao, Tao Li, Xiao-Li Sun, Wen-Ming Wan, Hongli Bao, Qingrong Qian, Qinghua Chen. (2022) Unpredicted Concentration-Dependent Sensory Properties of Pyrene-Containing NBN-Doped Polycyclic Aromatic Hydrocarbons. MOLECULES, 27 (1): (327). [PMID:35011557]
20. Xuejing Song,Lingqian Kong,Hongmei Du,Xiangyu Li,Hanlin Feng,Jinsheng Zhao,Yu Xie. (2018-10-27) Effects of Pyrazine Derivatives and Substituted Positions on the Photoelectric Properties and Electromemory Performance of D⁻A⁻D Series Compounds.. Materials (Basel, Switzerland), 11 ((10)): [PMID:30360424]

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42. Jianquan Xu, Xiaojin Guo, Hongkai Guo, Yizhi Zhang, Xinping Wang. (2023) Exploring the Molecular Origin for the Long-Range Propagation of the Substrate Effect in Unentangled Poly(methyl methacrylate) Films. Polymers, 15 (24): (4655). [PMID:38139907]
43. Yiyang Chen, Hao Ren, Xiangyu Kong, Hao Wu, Zhenmei Lu. (2023) A multicomponent propane monooxygenase catalyzes the initial degradation of methyl tert-butyl ether in Mycobacterium vaccae JOB5. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, (1): [PMID:37823642]
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