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trans-2-Methyl-2-butenal - >95.0%(GC), high purity , CAS No.497-03-0

47 Citations
  • ≥95%(GC)
Item Number
T161495
Grouped product items
SKUSizeAvailabilityPrice Qty
T161495-5ml
5ml
In stock
$29.90
T161495-25ml
25ml
In stock
$87.90
T161495-100ml
100ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$314.90
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aldehyde Non heterocyclic block

Basic Description

SynonymsCrotonaldehyde, 2-methyl-, (E)- | 2-Methylcrotonaldehyde, (E)- | 2-Butenal, 2-methyl-, (E)- | 27ZVE2K81C | DTXCID0029264 | 2-Methylbut-2-en-1-al, (E)- | Tiglic aldehyde, >=96% | ACWQBUSCFPJUPN-HWKANZROSA- | 2-Butenal, 2-methyl-, (2E)- | 2-METHYL-2-BUTENAL
Specifications & Purity≥95%(GC)
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Tiglic aldehyde was used in the concise total synthesis of 7-demethylpiericidin A1[1]. It was used as starting reagent during the synthesis of: · alkyl-branched tetraene hydrocarbons, pheromone component for dried fruit beetle · E,E-2,4-dimethyl-2,4-hexa dienal, volatile constituents of the defensive secretions of Leiobunum nigripalpi · 4-methyl-2,4-hexadiene-1-ol

Associated Targets(non-human)

Oryza sativa (2923 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Brassica oleracea var. capitata (55 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Tetrahymena pyriformis (68 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Rattus norvegicus (775804 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Myzus persicae (1112 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Tetranychus urticae (2600 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Lactuca sativa (1092 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Vitis vinifera (99 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Brevicoryne brassicae (33 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Frankliniella occidentalis (90 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Malus domestica (19 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Brassica oleracea var. italica (9 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Pseudococcus affinis (11 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Citrus x paradisi (5 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Pseudococcus viburni (11 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Persea americana (5 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Bemisia (11 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Mechanisms of Action

Mechanism of ActionAction Typetarget IDTarget NameTarget TypeTarget OrganismBinding Site NameReferences

Names and Identifiers

Pubchem Sid488195344
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488195344
IUPAC Name (E)-2-methylbut-2-enal
INCHI InChI=1S/C5H8O/c1-3-5(2)4-6/h3-4H,1-2H3/b5-3+
InChi Key ACWQBUSCFPJUPN-HWKANZROSA-N
Canonical SMILES CC=C(C)C=O
Isomeric SMILES C/C=C(\C)/C=O
WGK Germany 3
PubChem CID 5321950
Molecular Weight 84.12
Reaxy-Rn 1698207

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

7 results found

Lot NumberCertificate TypeDateItem
K2110747Certificate of AnalysisAug 07, 2023 T161495
B23271081Certificate of AnalysisFeb 09, 2023 T161495
B23271084Certificate of AnalysisFeb 09, 2023 T161495
B23271085Certificate of AnalysisFeb 09, 2023 T161495
B23271087Certificate of AnalysisFeb 09, 2023 T161495
K2016065Certificate of AnalysisSep 19, 2022 T161495
K2016064Certificate of AnalysisSep 19, 2022 T161495

Chemical and Physical Properties

SolubilitySoluble in water
Sensitivityair sensitive
Refractive Index1.448
Flash Point(°F)64°F
Flash Point(°C)18℃
Boil Point(°C)117-119°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07,   GHS02
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H411:Toxic to aquatic life with long lasting effects

H225:Highly Flammable liquid and vapor

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
Reaxy-Rn 1698207

Related Documents

 SDS

 Specification Sheet

Citations of This Product

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2. Qihong Jiang, Lin Chen, Rui Wang, Yin Chen, Shanggui Deng, Guoxin Shen, Shulai Liu, Xingwei Xiang.  (2024)  Hypoglycemic mechanism of Tegillarca granosa polysaccharides on type 2 diabetic mice by altering gut microbiota and regulating the PI3K-akt signaling pathway.  Food Science and Human Wellness,  13  (5): (842).  [PMID:10025403]
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References

1. Katie A Keaton,Andrew J Phillips.  (2006-01-13)  Titanium(II)-mediated cyclizations of (silyloxy)enynes: a total synthesis of (-)-7-demethylpiericidin A1..  Journal of the American Chemical Society,  128  ((2)): (408-409).  [PMID:16402817]
2. Pingxi Xu,Young-Moo Choo,Alyssa De La Rosa,Walter S Leal.  (2014-10-29)  Mosquito odorant receptor for DEET and methyl jasmonate..  Proceedings of the National Academy of Sciences of the United States of America,  111  ((46)): (16592-16597).  [PMID:25349401]
3. Hasmik Grigoryan,William M B Edmands,Qing Lan,Henrik Carlsson,Roel Vermeulen,Luoping Zhang,Song-Nian Yin,Gui-Lan Li,Martyn T Smith,Nathaniel Rothman,Stephen M Rappaport.  (2018-03-15)  Adductomic signatures of benzene exposure provide insights into cancer induction..  Carcinogenesis,  39  ((5)): (661-668).  [PMID:29538615]
4. Yue Yao, Hao Tang, Haiqiong Ma, Zidong Liu, Jinwen Huang, Xiufen Yang, Longyan Zhao, Qingxia Yuan.  (2024)  Chondroitin Sulfate/Dermatan Sulfate Hybrid Chains from Swim Bladder: Isolation, Structural Analysis, and Anticoagulant Activity.  Marine Drugs,  22  (1): (9).  [PMID:38276647]
5. Qihong Jiang, Lin Chen, Rui Wang, Yin Chen, Shanggui Deng, Guoxin Shen, Shulai Liu, Xingwei Xiang.  (2024)  Hypoglycemic mechanism of Tegillarca granosa polysaccharides on type 2 diabetic mice by altering gut microbiota and regulating the PI3K-akt signaling pathway.  Food Science and Human Wellness,  13  (5): (842).  [PMID:10025403]
6. Xin-Yang Jiang, Cai-Wei Wang, Jun Zhang, Pei-Pei Xu, Yi-Ting Xue, Qian Wang.  (2023)  Effects of Different Extraction Methods on Physicochemical Characteristics and Bioactivities of Fig (Ficus carica L.) Leaves Polysaccharides.  Arabian Journal of Chemistry,    (16): (105319).  [PMID:29144452]
7. Lin Ding, Minli Liang, Yuanyuan Li, Mei Zeng, Meiting Liu, Wei Ma, Fuming Chen, Chenchen Li, Rui L. Reis, Fu-Rong Li, Yanli Wang.  (2023)  Zinc-Organometallic Framework Vaccine Controlled-Release Zn2+ Regulates Tumor Extracellular Matrix Degradation Potentiate Efficacy of Immunotherapy.  Advanced Science,    (2302967).  [PMID:37439462]
8. Yang Liu, Limei Ran, Yahong Wang, Peng Wan, Hongli Zhou.  (2023)  Basic characterization, antioxidant and immunomodulatory activities of polysaccharides from sea buckthorn leaves.  FITOTERAPIA,  169  (105592).  [PMID:37343686]
9. Jing Yongshuai, Su Ziteng, Zhang Shilin, Han Qiyuan, Wang Ziying, Hu Beibei, Zhang Danshen, Sun Shiguo, Wu Lanfang.  (2023)  Structural Characterization, Simulated Digestion and Anti-Aging Activities of an Acidic Polysaccharide from Salvia Miltiorrhiza.  PLANT FOODS FOR HUMAN NUTRITION,  78  (2): (390-398).  [PMID:37249735]
10. Hao Tang, Jinwen Huang, Qingxia Yuan, Kunling Lv, Haiqiong Ma, Tingting Li, Yonghong Liu, Shunli Mi, Longyan Zhao.  (2023)  A regular Chlorella mannogalactan and its sulfated derivative as a promising anticoagulant: Structural characterization and anticoagulant activity.  CARBOHYDRATE POLYMERS,  314  (120956).  [PMID:37173047]
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20. Zhengyu Hu, Jiaming Wang, Long Jin, Tieqiang Zong, Yuanqi Duan, Jinfeng Sun, Wei Zhou, Gao Li.  (2022)  Preparation, Characterization and Anti-Complementary Activity of Three Novel Polysaccharides from Cordyceps militaris.  Polymers,  14  (21): (4636).  [PMID:36365633]
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23. Qingxia Yuan, Hong Li, Qian Wang, Shujing Sun, Ziyu Fang, Hao Tang, Xiaohuo Shi, Jing Wen, Lianghua Huang, Meng Bai, Shengping Zhong, Yonghong Liu, Chenghai Gao, Longyan Zhao.  (2022)  Deaminative-cleaved S. monotuberculatus fucosylated glycosaminoglycan: Structural elucidation and anticoagulant activity.  CARBOHYDRATE POLYMERS,  298  (120072).  [PMID:36241268]
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27. Chunjing Guo, Yanguo Su, Bingjie Wang, Qiang Chen, Huimin Guo, Ming Kong, Daquan Chen.  (2022)  Novel polysaccharide building hybrid nanoparticles: remodelling TAMs to target ERα-positive breast cancer.  JOURNAL OF DRUG TARGETING,  30  (4): (450-462).  [PMID:34927506]
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31. Xiang Shi, Ruowei Guan, Lutan Zhou, Zhichuang Zuo, Xuelin Tao, Pin Wang, Yanrong Zhou, Ronghua Yin, Longyan Zhao, Na Gao, Jinhua Zhao.  (2021)  Structural Characterization and Heparanase Inhibitory Activity of Fucosylated Glycosaminoglycan from Holothuria floridana.  Marine Drugs,  19  (3): (162).  [PMID:33803892]
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