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Triphenyl phosphite - reagent grade,95%, high purity , CAS No.101-02-0

  • CP
  • ≥95%
Item Number
T104037
Grouped product items
SKUSizeAvailabilityPrice Qty
T104037-100g
100g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$9.90
T104037-500g
500g
In stock
$30.90

Basic Description

SynonymsTRIPHENYL PHOSPHITE|101-02-0|Phosphorous acid, triphenyl ester|Advance TPP|Triphenoxyphosphine|Phenyl phosphite|Sumilizer TPP-R|Stabilizer P 36|Trifenoxyfosfin|Trifenylfosfit|Phosclere T 36|EFED|Mellite 310|Tris(phenoxy)phosphine|P 36 (stabilizer)|Weston
Specifications & PurityCP, ≥95%
Storage TempRoom temperature,Argon charged,Desiccated
Shipped InNormal
GradeCP

Associated Targets

AR Tclin Androgen receptor 0 Activities

Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

THRB Tclin Thyroid hormone receptor beta 0 Activities

Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

NFE2L2 Tchem Nuclear factor erythroid 2-related factor 2 0 Activities

Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

Names and Identifiers

IUPAC Name triphenyl phosphite
INCHI InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChi Key HVLLSGMXQDNUAL-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
Isomeric SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
WGK Germany 2
RTECS TH1575000
PubChem CID 7540
UN Number 2811
Packing Group I
Molecular Weight 310.28
Beilstein 1079456
Reaxy-Rn 1079456

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

4 results found

Lot NumberCertificate TypeDateItem
H2316031Certificate of AnalysisAug 21, 2023 T104037
B2308348Certificate of AnalysisFeb 18, 2023 T104037
J2211198Certificate of AnalysisOct 20, 2022 T104037
J2211199Certificate of AnalysisOct 20, 2022 T104037

Chemical and Physical Properties

SolubilityInsoluble in water, soluble in most organic solvents.
SensitivityAir & Moisture Sensitive
Freezing Point(°C)20 °C
Refractive Index1.59
Flash Point(°F)410 °F
Flash Point(°C)206℃
Boil Point(°C)360°C
Melt Point(°C)22-24°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H400:Very toxic to aquatic life

H410:Very toxic to aquatic life with long lasting effects

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

WGK Germany 2
RTECS TH1575000
Reaxy-Rn 1079456
Class 6.1
RIDADR UN 3077 9 / PGIII

Related Documents

References

1. E D Levin,N C Christopher,M B Abou-Donia.  (1995-04-01)  Triphenyl phosphite-induced impairment of spatial alternation learning..  Journal of toxicology and environmental health,  44  ((4)): (461-467).  [PMID:7723078]
2. K Katoh.  (1995-09-01)  [A review of studies of the delayed neurotoxicity induced by organophosphorus esters]..  Sangyo eiseigaku zasshi = Journal of occupational health,  37  ((5)): (309-319).  [PMID:8528948]
3. F Fioroni,A Moretto,M Lotti.  (1995-01-01)  Triphenylphosphite neuropathy in hens..  Archives of toxicology,  69  ((10)): (705-711).  [PMID:8572929]
4. U Wormser,I Raibstein,J S Kritzler,A Nyska.  (1998-12-09)  High-molecular weight serum cytotoxic factor in rats treated with triphenyl phosphite: an approach for biological monitoring..  Journal of pharmacological and toxicological methods,  39  ((4)): (241-243).  [PMID:9845304]
5. R D Pike,W H Starnes,G B Carpenter.  (1999-03-11)  Cubane tetrameric complexes of copper(I) chloride and bromide with triphenyl phosphite..  Acta crystallographica. Section C, Crystal structure communications,  55   (( Pt 2)): (162-165).  [PMID:10071845]
6. Alberto Spaggiari,Larry C Blaszczak,Fabio Prati.  (2004-10-22)  Low-temperature deacylation of N-monosubstituted amides..  Organic letters,  ((22)): (3885-3888).  [PMID:15496055]
7. Kersti B Nilsson,Ingmar Persson,Vadim G Kessler.  (2006-08-15)  Coordination chemistry of the solvated AgI and AuI ions in liquid and aqueous ammonia, trialkyl and triphenyl phosphite, and tri-n-butylphosphine solutions..  Inorganic chemistry,  45  ((17)): (6912-6921).  [PMID:16903749]
8. Faramarz Rostami Charati,Malek Taher Maghsoodlou,Sayyed Mostafa Habibi-Khorassani,Nourallah Hazeri,Ali Ebrahimi,Zinatossadat Hossaini,Pouneh Ebrahimi,Nariman Maleki,Sayyed Reza Adhamdoust,Fatemeh Vasheghani Farahani,Ghasem Marandi,Alexandre Sobolev,Mohamed Makha.  (2010-08-03)  Efficient synthesis of stable phosphonate ylides and \u200ephosphonate esters: reaction between activated acetylenes and triphenylphosphite in the presence of sulfonamide and heterocyclic NH-acids..  Combinatorial chemistry & high throughput screening,  14  ((1)): (2-8).  [PMID:20673221]
9. Ken-ichiro Murata,Hajime Tanaka.  (2010-10-27)  Surface-wetting effects on the liquid-liquid transition of a single-component molecular liquid..  Nature communications,  (16-16).  [PMID:20975680]
10. Yi-Xuan Lu,Zhu-Ming Shi,Zhan-Ting Li,Zhibin Guan.  (2010-11-09)  Helical polymers based on intramolecularly hydrogen-bonded aromatic polyamides..  Chemical communications (Cambridge, England),  46  ((47)): (9019-9021).  [PMID:21057673]
11. Katri Suuronen,Maria Pesonen,Maj-Len Henriks-Eckerman,Kristiina Aalto-Korte.  (2012-09-22)  Triphenyl phosphite, a new allergen in polyvinylchloride gloves..  Contact dermatitis,  68  ((1)): (42-49).  [PMID:22994308]
12. Alix Vandevenne,Katrien Ghys,Jacob Dahlin,An Pontén,Stefan Kerre.  (2013-02-21)  Allergic contact dermatitis caused by triphenyl phosphite in poly(vinyl chloride) gloves..  Contact dermatitis,  68  ((3)): (181-182).  [PMID:23421460]
13. Adrian Tlahuext-Aca, Oscar Hernández-Fajardo, Alma Arévalo, Juventino J García,.  (2014-09-19)  Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines..  Dalton transactions (Cambridge, England : 2003),  43  ((42)): ( 15997-16005 ).  [PMID:25232889]
14. Evgeni Eltzov,Avital Cohen,Robert S Marks.  (2015-03-17)  Bioluminescent liquid light guide pad biosensor for indoor air toxicity monitoring..  Analytical chemistry,  87  ((7)): (3655-3661).  [PMID:25775008]
15. R G Varghese,S J Bursian,C Tobias,D Tanaka.  (1995-01-01)  Organophosphorus-induced delayed neurotoxicity: a comparative study of the effects of tri-ortho-tolyl phosphate and triphenyl phosphite on the central nervous system of the Japanese quail..  Neurotoxicology,  16  ((1)): (45-54).  [PMID:7603644]
16. E J Lehning,D Tanaka,S J Bursian.  (1996-01-01)  Triphenyl phosphite and diisopropylphosphorofluoridate produce separate and distinct axonal degeneration patterns in the central nervous system of the rat..  Fundamental and applied toxicology : official journal of the Society of Toxicology,  29  ((1)): (110-118).  [PMID:8838646]
17. H Kinebuchi,K Akimaru,S Noda,K Yamamoto.  (1998-11-12)  Cholinesterase activity in quails of neuropathy caused by organophosphates..  Industrial health,  36  ((4)): (376-379).  [PMID:9810153]
18. D Tanaka,M Lin,D Powell,M Morgan,L Lipsitz,R J Aulerich,S J Bursian.  (1999-12-11)  Effects of dark-rearing on triphenyl phosphate-induced neuropathy in the visual system of the developing European ferret (Mustela putorius furo)..  Journal of toxicology and environmental health. Part A,  58  ((4)): (215-231).  [PMID:10591489]
19. Lee Lipsitz,Arthur J Weber,Steven J Bursian,Richard J Aulerich,David T Ramsey,Tanaka Duke.  (2002-08-08)  A quantitative assessment of TPP-induced delayed neuropathy in the retina and lateral geniculate nucleus of the European ferret (Mustela putorius furo)..  Neurotoxicology,  23  ((1)): (33-42).  [PMID:12164546]
20. C Torresani,E Zendri,V Vescovi,G De Panfilis.  (2003-06-06)  Contact urticaria syndrome from occupational triphenyl phosphite exposure..  Contact dermatitis,  48  ((4)): (237-238).  [PMID:12786744]
21. Y Mao,W Chen,G Xia,Z Yang,L Zhang,Y Sun,S Weng,J Wu.  (2003-08-27)  [Influence on luminescence of Tb o-aminobenzolate complexes by second ligand]..  Guang pu xue yu guang pu fen xi = Guang pu,  20  ((6)): (869-871).  [PMID:12938499]
22. Catherine R Holden,Kid Wan Shum,David J Gawkrodger.  (2006-05-13)  Contact allergy to triphenyl phosphate: probable cross-reactivity to triphenyl phosphite present in an EN46001 System 22 clear oxygen facemask..  Contact dermatitis,  54  ((5)): (299-300).  [PMID:16689819]
23. John D Meeker,Heather M Stapleton.  (2010-03-03)  House dust concentrations of organophosphate flame retardants in relation to hormone levels and semen quality parameters..  Environmental health perspectives,  118  ((3)): (318-323).  [PMID:20194068]
24. Shadpour Mallakpour,Fatemeh Mirkarimi.  (2010-03-31)  Synthesis and characterization of novel, optically active polyamides derived from S-valine natural amino acid and bulky anthracenic side chain..  Amino acids,  39  ((5)): (1255-1263).  [PMID:20352462]

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