Triphenyl phosphite - reagent grade,95%, high purity , CAS No.101-02-0

  • CP
  • ≥95%
Item Number
T104037
Grouped product items
SKUSizeAvailabilityPrice Qty
T104037-100g
100g
In stock
$9.90
T104037-500g
500g
In stock
$30.90

Basic Description

SynonymsTrifenylfosfit [Czech] | Tris(phenoxy)phosphine | DTXSID0026252 | EINECS 202-908-4 | NSC-62219 | Mellite 310 | AI3-07866 | Trifenoxyfosfin | DTXCID306252 | Triphenyl Phosphite (TPPi) | Weston TPP | ADK Stab TPP | NCIOpen2_007800 | JP 360 | Trifenoxyfosfin
Specifications & PurityCP, ≥95%
Storage TempRoom temperature,Argon charged,Desiccated
Shipped InNormal
GradeCP

Associated Targets(Human)

AR Tclin Androgen receptor (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)
THRB Tclin Thyroid hormone receptor beta (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)
NFE2L2 Tchem Nuclear factor erythroid 2-related factor 2 (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)
AR Tclin Androgen Receptor (11781 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
THRB Tclin Thyroid hormone receptor beta-1 (7926 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Mechanisms of Action

Mechanism of ActionAction Typetarget IDTarget NameTarget TypeTarget OrganismBinding Site NameReferences

Names and Identifiers

IUPAC Name triphenyl phosphite
INCHI InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChi Key HVLLSGMXQDNUAL-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
Isomeric SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
WGK Germany 2
RTECS TH1575000
PubChem CID 7540
UN Number 2811
Packing Group I
Molecular Weight 310.28
Beilstein 1079456
Reaxy-Rn 1079456

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

7 results found

Lot NumberCertificate TypeDateItem
A2128041Certificate of AnalysisNov 11, 2024 T104037
J2410750Certificate of AnalysisApr 29, 2024 T104037
J2410752Certificate of AnalysisApr 29, 2024 T104037
H2316031Certificate of AnalysisAug 21, 2023 T104037
B2308348Certificate of AnalysisFeb 18, 2023 T104037
J2211198Certificate of AnalysisOct 20, 2022 T104037
J2211199Certificate of AnalysisOct 20, 2022 T104037

Chemical and Physical Properties

SolubilityInsoluble in water, soluble in most organic solvents.
SensitivityAir & Moisture Sensitive
Freezing Point(°C)20 °C
Refractive Index1.59
Flash Point(°F)410 °F
Flash Point(°C)206℃
Boil Point(°C)360°C
Melt Point(°C)22-24°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H400:Very toxic to aquatic life

H410:Very toxic to aquatic life with long lasting effects

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

WGK Germany 2
RTECS TH1575000
Reaxy-Rn 1079456
Class 6.1
RIDADR UN 3077 9 / PGIII

Related Documents

Citations of This Product

1. Hailong Wei, Fangwei Gu, Yongsheng Wang, Jinyuan Hao, Wei Zhu, Zhongbin Zhuang.  (2023)  Synthesis of Pure-Phase Ni2P Nanocatalysts via Phosphorus Ligand Selection for Efficient Hydrogen Evolution Reaction.  ChemElectroChem,    (e202300426).  [PMID:30538148] [10.1002/celc.202300426]
2. Chao Zeng, ShengMing Zhang, Peng Ji, ZhiCheng Qiu, ZhiYong Li, ChaoSheng Wang, HuaPing Wang.  (2023)  Facile Sustainable Synthesis of Polyester-Polycarbonate and Effects of the Carbonate on Thermal, Mechanical, and Transparency Properties.  ACS Sustainable Chemistry & Engineering,  11  (43): (15754–15764).  [PMID:28111074] [10.1021/acssuschemeng.3c05515]
3. Xiao Jing, Zhenyuan Hu, Jinpeng Qin, Xin Jiang, Mingyin Wang, Shikang Huo, Shuai Zhang, Jiatang Wang, Yunfeng Zhang.  (2023)  Highly conductive and mechanically robust single-ion conducting polymer electrolyte membranes with a high concentration of charge carriers for dendrite-proof lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  688  (122118).  [PMID:16906129] [10.1016/j.memsci.2023.122118]
4. Shouying Wu, Linping Zhang, Jianing Fan, Wei Wu, Bolin Ji, Xueling Feng, Bijia Wang, Yimeng Ma, Yi Zhong, Hong Xu, Zhiping Mao.  (2023)  Iron(III) complexes promote hydrogen peroxide activation for efficient degradation of dyeing wastewater.  COLORATION TECHNOLOGY,    (1):   [PMID:10648423] [10.1111/cote.12727]
5. Shaokang Su, Wei Zhang, Ying Xie, Lihong Qi, Song Wang, Limin An, Kai Pan.  (2023)  Synthesis of Fe Atom-Doped Monodisperse Co2P Nanorods with a Dual-Ligand Strategy for Excellent Electrocatalytic Hydrogen Evolution Performance.  INORGANIC CHEMISTRY,  62  (35): (14459–14468).  [PMID:37615389] [10.1021/acs.inorgchem.3c02438]
6. Jia Liu, Zhengchun Cai, Yongxin Ji.  (2023)  Synthesis of bio-based modified amphoteric acrylate epoxy emulsion surface sizing agent via RAFT polymerization.  JOURNAL OF APPLIED POLYMER SCIENCE,  140  (39): (e54462).  [PMID:] [10.1002/app.54462]
7. Chenglong Xie, Xinxin Zhang, Haitao Yu, Ying Xie.  (2023)  Monodispersed bi-metallic phosphide anchoring on CNTs with enhanced stability and electrocatalytic HER performance at a wide PH range.  JOURNAL OF ALLOYS AND COMPOUNDS,  965  (171256).  [PMID:] [10.1016/j.jallcom.2023.171256]
8. Enas A. Imam, Ahmed I Hashem, Ahmad A. Tolba, Mohammad G. Mahfouz, Ibrahim El-Tantawy El-Sayed, Hamada B. Hawash, Rana R. Neiber, Hamed I. Mira, Ahmed A. Galhoum, Eric Guibal.  (2023)  Aminophosphonate CuO nanocomposites for uranium(VI) removal: Sorption performance and mechanistic study.  SEPARATION AND PURIFICATION TECHNOLOGY,  323  (124466).  [PMID:] [10.1016/j.seppur.2023.124466]
9. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang.  (2023)  Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  664  (131181).  [PMID:] [10.1016/j.colsurfa.2023.131181]
10. Huihui Gao, Xiankun Wu, Yaowen Hu, Mang Wu, Wei Liu, Zhongkai Wang.  (2023)  The conversion of woody oils into E-octadec-9-enedioic acid and multiple-shape memory polyamides.  INDUSTRIAL CROPS AND PRODUCTS,  191  (115879).  [PMID:] [10.1016/j.indcrop.2022.115879]
11. Ran Yu, Chao Xu, Xiaopei Wu, Honglian Dai.  (2022)  Polyoxyethylene Diamine Modification of Poly(amide-imide)-polyethylene Glycol Exhibits Excellent Hydrophilicity, Degradability, and Biocompatibility.  Polymers,  14  (21): (4694).  [PMID:36365687] [10.3390/polym14214694]
12. Xingfeng Lei, Guo Xiong, Yuyang Xiao, Tianhao Huang, Xiangze Xin, Shuyu Xue, Qiuyu Zhang.  (2022)  High temperature shape memory poly(amide-imide)s with strong mechanical robustness.  Polymer Chemistry,  13  (35): (5082-5093).  [PMID:] [10.1039/D2PY00739H]
13. Shaokang Su, Chenfeng Guo, Li Li, Ying Xie, Song Wang, Kai Pan.  (2022)  Monodispersed nickel phosphide nanocrystals in situ grown on reduced graphene oxide matrix with excellent performance as the anode for lithium-ion batteries.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,  920  (116616).  [PMID:] [10.1016/j.jelechem.2022.116616]
14. Lichao Chen, Bo Wang, Haohao Ren, Yanan Wu, Defu Lyu, Yanan Ouyang, Qiyi Zhang, Yonggang Yan.  (2022)  Arg−Gly−Asp peptide functionalized poly-amino acid/ poly (p-benzamide) copolymer with enhanced mechanical properties and osteogenicity.  Biomaterials Advances,  133  (112627).  [PMID:35527153] [10.1016/j.msec.2021.112627]
15. Shikang Huo, Yang He, Zhenyuan Hu, Wei Bao, Weijie Chen, Yaying Wang, Danli Zeng, Hansong Cheng, Yunfeng Zhang.  (2022)  New insights into designation of single-ion conducting gel polymer electrolyte for high-performance lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  647  (120287).  [PMID:] [10.1016/j.memsci.2022.120287]
16. Xing-Zhou Lu, Chao Gu, Qi Zhang, Lei Shi, Shi-Kui Han, Guan-Ping Jin.  (2021)  Regioselective Construction of Chemically Transformed Phosphide–Metal Nanoheterostructures for Enhanced Hydrogen Evolution Catalysis.  INORGANIC CHEMISTRY,  60  (10): (7269–7275).  [PMID:33764054] [10.1021/acs.inorgchem.1c00348]
17. Yanyu Gao, Wei Zhang, Dongxu Li, Xiaoxue Lin, Xin Qiao, Haijun Niu, Wen Wang.  (2021)  Novel polyamides containing asymmetric diamine designed and synthesized towards electrochromic and resistance memory device.  SYNTHETIC METALS,  274  (116732).  [PMID:] [10.1016/j.synthmet.2021.116732]
18. Pan Zhaoqun, Chen Mianfeng, Zeng Keling, Kang Yingzi.  (2022)  Synthesis of Epoxy-Modified Methyl Phenyl Silicone Resins for LED Encapsulation.  Silicon,  14  (3): (1159-1167).  [PMID:] [10.1007/s12633-020-00868-6]
19. Canhuang Li, Siyong Wu, Yijing Qiu, Dongsheng Lu.  (2020)  Phosphorus-Containing C12H27O4P as Functional Electrolyte Additives for High-Voltage LiNi0.5Mn1.5O4/Graphite Li-Ion Batteries with Excellent Electrochemical Performance.  Advanced Materials Interfaces,  (3): (2001588).  [PMID:] [10.1002/admi.202001588]
20. Xinqiang Xu, Fuyan He, Wenke Yang, Jinshui Yao.  (2020)  Effect of Homochirality of Dipeptide to Polymers’ Degradation.  Polymers,  12  (9): (2164).  [PMID:32971890] [10.3390/polym12092164]
21. Yawen Fang, Yanbin Wang, Yongchao Li, Huang Yu, Changlong Zhuang, Zhonglin Luo, Zicheng Fan, Biaobing Wang.  (2020)  Conductivity enhancement of poly(amide-imide) composites based on the synergistic effect of poly(o-methoxyaniline) and functionalized multiwalled carbon nanotube.  POLYMERS & POLYMER COMPOSITES,      [PMID:] [10.1177/0967391120930970]
22. Yuan Zhao, Chongxing Huang, Xingqiang Huang, Haohe Huang, Hui Zhao, Shuangfei Wang, Shijie Liu.  (2020)  Effectiveness of PECVD deposited nano-silicon oxide protective layer for polylactic acid film: Barrier and surface properties.  Food Packaging and Shelf Life,  25  (100513).  [PMID:] [10.1016/j.fpsl.2020.100513]
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24. Fuhan Liu, Yaxin Zhang, Guang Yu, Yanjun Hou, Haijun Niu.  (2018)  Electrochromism of novel triphenylamine-containing polyamide polymers.  JOURNAL OF APPLIED POLYMER SCIENCE,  136  (15): (47264).  [PMID:] [10.1002/app.47264]
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References

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3. F Fioroni,A Moretto,M Lotti.  (1995-01-01)  Triphenylphosphite neuropathy in hens..  Archives of toxicology,  69  ((10)): (705-711).  [PMID:8572929]
4. U Wormser,I Raibstein,J S Kritzler,A Nyska.  (1998-12-09)  High-molecular weight serum cytotoxic factor in rats treated with triphenyl phosphite: an approach for biological monitoring..  Journal of pharmacological and toxicological methods,  39  ((4)): (241-243).  [PMID:9845304]
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12. Alix Vandevenne,Katrien Ghys,Jacob Dahlin,An Pontén,Stefan Kerre.  (2013-02-21)  Allergic contact dermatitis caused by triphenyl phosphite in poly(vinyl chloride) gloves..  Contact dermatitis,  68  ((3)): (181-182).  [PMID:23421460]
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20. C Torresani,E Zendri,V Vescovi,G De Panfilis.  (2003-06-06)  Contact urticaria syndrome from occupational triphenyl phosphite exposure..  Contact dermatitis,  48  ((4)): (237-238).  [PMID:12786744]
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22. Catherine R Holden,Kid Wan Shum,David J Gawkrodger.  (2006-05-13)  Contact allergy to triphenyl phosphate: probable cross-reactivity to triphenyl phosphite present in an EN46001 System 22 clear oxygen facemask..  Contact dermatitis,  54  ((5)): (299-300).  [PMID:16689819]
23. John D Meeker,Heather M Stapleton.  (2010-03-03)  House dust concentrations of organophosphate flame retardants in relation to hormone levels and semen quality parameters..  Environmental health perspectives,  118  ((3)): (318-323).  [PMID:20194068]
24. Shadpour Mallakpour,Fatemeh Mirkarimi.  (2010-03-31)  Synthesis and characterization of novel, optically active polyamides derived from S-valine natural amino acid and bulky anthracenic side chain..  Amino acids,  39  ((5)): (1255-1263).  [PMID:20352462]
25. Hailong Wei, Fangwei Gu, Yongsheng Wang, Jinyuan Hao, Wei Zhu, Zhongbin Zhuang.  (2023)  Synthesis of Pure-Phase Ni2P Nanocatalysts via Phosphorus Ligand Selection for Efficient Hydrogen Evolution Reaction.  ChemElectroChem,    (e202300426).  [PMID:30538148] [10.1002/celc.202300426]
26. Chao Zeng, ShengMing Zhang, Peng Ji, ZhiCheng Qiu, ZhiYong Li, ChaoSheng Wang, HuaPing Wang.  (2023)  Facile Sustainable Synthesis of Polyester-Polycarbonate and Effects of the Carbonate on Thermal, Mechanical, and Transparency Properties.  ACS Sustainable Chemistry & Engineering,  11  (43): (15754–15764).  [PMID:28111074] [10.1021/acssuschemeng.3c05515]
27. Xiao Jing, Zhenyuan Hu, Jinpeng Qin, Xin Jiang, Mingyin Wang, Shikang Huo, Shuai Zhang, Jiatang Wang, Yunfeng Zhang.  (2023)  Highly conductive and mechanically robust single-ion conducting polymer electrolyte membranes with a high concentration of charge carriers for dendrite-proof lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  688  (122118).  [PMID:16906129] [10.1016/j.memsci.2023.122118]
28. Shouying Wu, Linping Zhang, Jianing Fan, Wei Wu, Bolin Ji, Xueling Feng, Bijia Wang, Yimeng Ma, Yi Zhong, Hong Xu, Zhiping Mao.  (2023)  Iron(III) complexes promote hydrogen peroxide activation for efficient degradation of dyeing wastewater.  COLORATION TECHNOLOGY,    (1):   [PMID:10648423] [10.1111/cote.12727]
29. Shaokang Su, Wei Zhang, Ying Xie, Lihong Qi, Song Wang, Limin An, Kai Pan.  (2023)  Synthesis of Fe Atom-Doped Monodisperse Co2P Nanorods with a Dual-Ligand Strategy for Excellent Electrocatalytic Hydrogen Evolution Performance.  INORGANIC CHEMISTRY,  62  (35): (14459–14468).  [PMID:37615389] [10.1021/acs.inorgchem.3c02438]
30. Jia Liu, Zhengchun Cai, Yongxin Ji.  (2023)  Synthesis of bio-based modified amphoteric acrylate epoxy emulsion surface sizing agent via RAFT polymerization.  JOURNAL OF APPLIED POLYMER SCIENCE,  140  (39): (e54462).  [PMID:] [10.1002/app.54462]
31. Chenglong Xie, Xinxin Zhang, Haitao Yu, Ying Xie.  (2023)  Monodispersed bi-metallic phosphide anchoring on CNTs with enhanced stability and electrocatalytic HER performance at a wide PH range.  JOURNAL OF ALLOYS AND COMPOUNDS,  965  (171256).  [PMID:] [10.1016/j.jallcom.2023.171256]
32. Enas A. Imam, Ahmed I Hashem, Ahmad A. Tolba, Mohammad G. Mahfouz, Ibrahim El-Tantawy El-Sayed, Hamada B. Hawash, Rana R. Neiber, Hamed I. Mira, Ahmed A. Galhoum, Eric Guibal.  (2023)  Aminophosphonate CuO nanocomposites for uranium(VI) removal: Sorption performance and mechanistic study.  SEPARATION AND PURIFICATION TECHNOLOGY,  323  (124466).  [PMID:] [10.1016/j.seppur.2023.124466]
33. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang.  (2023)  Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  664  (131181).  [PMID:] [10.1016/j.colsurfa.2023.131181]
34. Huihui Gao, Xiankun Wu, Yaowen Hu, Mang Wu, Wei Liu, Zhongkai Wang.  (2023)  The conversion of woody oils into E-octadec-9-enedioic acid and multiple-shape memory polyamides.  INDUSTRIAL CROPS AND PRODUCTS,  191  (115879).  [PMID:] [10.1016/j.indcrop.2022.115879]
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Solution Calculators