Skip to the beginning of the images gallery

Triphenyl phosphite - reagent grade,95%, high purity , CAS No.101-02-0

15 Citations

≥95%

CAS#: 101-02-0
Formula: C₁₈H₁₅O₃P
Molecular Weight: 310.28
Beilstein Registry Number: 1079456
MDL number: MFCD00003032
PubChem CID: 7540

Item Number

T104037

Grouped product items
SKU	Size	Availability	Price	Qty
T104037-100g	100g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$9.90
T104037-500g	500g	In stock	$30.90

View related series

Element classified compounds Phosphorus compounds

Basic Description

Synonyms	TRIPHENYL PHOSPHITE \| 101-02-0 \| Phosphorous acid, triphenyl ester \| Advance TPP \| Triphenoxyphosphine \| Phenyl phosphite \| Sumilizer TPP-R \| Stabilizer P 36 \| Trifenoxyfosfin \| Trifenylfosfit \| Phosclere T 36 \| EFED \| Mellite 310 \| Tris(phenoxy)phosphine \| P 36 (stabilizer) \| Weston
Specifications & Purity	CP, ≥95%
Storage Temp	Room temperature,Argon charged,Desiccated
Shipped In	Normal
Grade	CP

Associated Targets(Human)

AR Tclin Androgen receptor (0 Activities)

Discover Target: AR

Activity Type	Activity Value -log(M)	Mechanism of Action	Activity Reference	Publications (PubMed IDs)

THRB Tclin Thyroid hormone receptor beta (0 Activities)

Discover Target: THRB

Activity Type	Activity Value -log(M)	Mechanism of Action	Activity Reference	Publications (PubMed IDs)

NFE2L2 Tchem Nuclear factor erythroid 2-related factor 2 (0 Activities)

Discover Target: NFE2L2

Activity Type	Activity Value -log(M)	Mechanism of Action	Activity Reference	Publications (PubMed IDs)

AR Tclin Androgen Receptor (11781 Activities)

Discover Target: AR

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

THRB Tclin Thyroid hormone receptor beta-1 (7926 Activities)

Discover Target: THRB

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Associated Targets(non-human)

Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 Activities)

Discover Target: Nfe2l2

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Names and Identifiers

IUPAC Name	triphenyl phosphite
INCHI	InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChi Key	HVLLSGMXQDNUAL-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
Isomeric SMILES	C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
WGK Germany	2
RTECS	TH1575000
PubChem CID	7540
UN Number	2811
Packing Group	I
Molecular Weight	310.28
Beilstein	1079456
Reaxy-Rn	1079456

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

4 results found

Lot Number	Certificate Type	Date	Item
H2316031	Certificate of Analysis	Aug 21, 2023	T104037
B2308348	Certificate of Analysis	Feb 18, 2023	T104037
J2211198	Certificate of Analysis	Oct 20, 2022	T104037
J2211199	Certificate of Analysis	Oct 20, 2022	T104037

Chemical and Physical Properties

Solubility	Insoluble in water, soluble in most organic solvents.
Sensitivity	Air & Moisture Sensitive
Freezing Point(°C)	20 °C
Refractive Index	1.59
Flash Point(°F)	410 °F
Flash Point(°C)	206℃
Boil Point(°C)	360°C
Melt Point(°C)	22-24°C

Safety and Hazards(GHS)

Pictogram(s)	GHS09, GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H400:Very toxic to aquatic life H410:Very toxic to aquatic life with long lasting effects
Precautionary Statements	P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help.
WGK Germany	2
RTECS	TH1575000
Reaxy-Rn	1079456
Class	6.1
RIDADR	UN 3077 9 / PGIII

Citations of This Product

1. Hailong Wei, Fangwei Gu, Yongsheng Wang, Jinyuan Hao, Wei Zhu, Zhongbin Zhuang. (2023) Synthesis of Pure-Phase Ni2P Nanocatalysts via Phosphorus Ligand Selection for Efficient Hydrogen Evolution Reaction. ChemElectroChem, (e202300426). [PMID:30538148]
2. Chao Zeng, ShengMing Zhang, Peng Ji, ZhiCheng Qiu, ZhiYong Li, ChaoSheng Wang, HuaPing Wang. (2023) Facile Sustainable Synthesis of Polyester-Polycarbonate and Effects of the Carbonate on Thermal, Mechanical, and Transparency Properties. ACS Sustainable Chemistry & Engineering, 11 (43): (15754–15764). [PMID:28111074]
3. Xiao Jing, Zhenyuan Hu, Jinpeng Qin, Xin Jiang, Mingyin Wang, Shikang Huo, Shuai Zhang, Jiatang Wang, Yunfeng Zhang. (2023) Highly conductive and mechanically robust single-ion conducting polymer electrolyte membranes with a high concentration of charge carriers for dendrite-proof lithium metal batteries. JOURNAL OF MEMBRANE SCIENCE, 688 (122118). [PMID:16906129]
4. Shouying Wu, Linping Zhang, Jianing Fan, Wei Wu, Bolin Ji, Xueling Feng, Bijia Wang, Yimeng Ma, Yi Zhong, Hong Xu, Zhiping Mao. (2023) Iron(III) complexes promote hydrogen peroxide activation for efficient degradation of dyeing wastewater. COLORATION TECHNOLOGY, (1): [PMID:10648423]
5. Shaokang Su, Wei Zhang, Ying Xie, Lihong Qi, Song Wang, Limin An, Kai Pan. (2023) Synthesis of Fe Atom-Doped Monodisperse Co2P Nanorods with a Dual-Ligand Strategy for Excellent Electrocatalytic Hydrogen Evolution Performance. INORGANIC CHEMISTRY, 62 (35): (14459–14468). [PMID:37615389]
6. Jia Liu, Zhengchun Cai, Yongxin Ji. (2023) Synthesis of bio-based modified amphoteric acrylate epoxy emulsion surface sizing agent via RAFT polymerization. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (39): (e54462). [PMID:]
7. Chenglong Xie, Xinxin Zhang, Haitao Yu, Ying Xie. (2023) Monodispersed bi-metallic phosphide anchoring on CNTs with enhanced stability and electrocatalytic HER performance at a wide PH range. JOURNAL OF ALLOYS AND COMPOUNDS, 965 (171256). [PMID:]
8. Enas A. Imam, Ahmed I Hashem, Ahmad A. Tolba, Mohammad G. Mahfouz, Ibrahim El-Tantawy El-Sayed, Hamada B. Hawash, Rana R. Neiber, Hamed I. Mira, Ahmed A. Galhoum, Eric Guibal. (2023) Aminophosphonate CuO nanocomposites for uranium(VI) removal: Sorption performance and mechanistic study. SEPARATION AND PURIFICATION TECHNOLOGY, 323 (124466). [PMID:]
9. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang. (2023) Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 664 (131181). [PMID:]
10. Huihui Gao, Xiankun Wu, Yaowen Hu, Mang Wu, Wei Liu, Zhongkai Wang. (2023) The conversion of woody oils into E-octadec-9-enedioic acid and multiple-shape memory polyamides. INDUSTRIAL CROPS AND PRODUCTS, 191 (115879). [PMID:]
11. Ran Yu, Chao Xu, Xiaopei Wu, Honglian Dai. (2022) Polyoxyethylene Diamine Modification of Poly(amide-imide)-polyethylene Glycol Exhibits Excellent Hydrophilicity, Degradability, and Biocompatibility. Polymers, 14 (21): (4694). [PMID:36365687]
12. Xingfeng Lei, Guo Xiong, Yuyang Xiao, Tianhao Huang, Xiangze Xin, Shuyu Xue, Qiuyu Zhang. (2022) High temperature shape memory poly(amide-imide)s with strong mechanical robustness. Polymer Chemistry, 13 (35): (5082-5093). [PMID:]
13. Shaokang Su, Chenfeng Guo, Li Li, Ying Xie, Song Wang, Kai Pan. (2022) Monodispersed nickel phosphide nanocrystals in situ grown on reduced graphene oxide matrix with excellent performance as the anode for lithium-ion batteries. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 920 (116616). [PMID:]
14. Lichao Chen, Bo Wang, Haohao Ren, Yanan Wu, Defu Lyu, Yanan Ouyang, Qiyi Zhang, Yonggang Yan. (2022) Arg−Gly−Asp peptide functionalized poly-amino acid/ poly (p-benzamide) copolymer with enhanced mechanical properties and osteogenicity. Biomaterials Advances, 133 (112627). [PMID:35527153]
15. Shikang Huo, Yang He, Zhenyuan Hu, Wei Bao, Weijie Chen, Yaying Wang, Danli Zeng, Hansong Cheng, Yunfeng Zhang. (2022) New insights into designation of single-ion conducting gel polymer electrolyte for high-performance lithium metal batteries. JOURNAL OF MEMBRANE SCIENCE, 647 (120287). [PMID:]

References

1. E D Levin,N C Christopher,M B Abou-Donia. (1995-04-01) Triphenyl phosphite-induced impairment of spatial alternation learning.. Journal of toxicology and environmental health, 44 ((4)): (461-467). [PMID:7723078]
2. K Katoh. (1995-09-01) [A review of studies of the delayed neurotoxicity induced by organophosphorus esters].. Sangyo eiseigaku zasshi = Journal of occupational health, 37 ((5)): (309-319). [PMID:8528948]
3. F Fioroni,A Moretto,M Lotti. (1995-01-01) Triphenylphosphite neuropathy in hens.. Archives of toxicology, 69 ((10)): (705-711). [PMID:8572929]
4. U Wormser,I Raibstein,J S Kritzler,A Nyska. (1998-12-09) High-molecular weight serum cytotoxic factor in rats treated with triphenyl phosphite: an approach for biological monitoring.. Journal of pharmacological and toxicological methods, 39 ((4)): (241-243). [PMID:9845304]
5. R D Pike,W H Starnes,G B Carpenter. (1999-03-11) Cubane tetrameric complexes of copper(I) chloride and bromide with triphenyl phosphite.. Acta crystallographica. Section C, Crystal structure communications, 55 (( Pt 2)): (162-165). [PMID:10071845]
6. Alberto Spaggiari,Larry C Blaszczak,Fabio Prati. (2004-10-22) Low-temperature deacylation of N-monosubstituted amides.. Organic letters, 6 ((22)): (3885-3888). [PMID:15496055]
7. Kersti B Nilsson,Ingmar Persson,Vadim G Kessler. (2006-08-15) Coordination chemistry of the solvated AgI and AuI ions in liquid and aqueous ammonia, trialkyl and triphenyl phosphite, and tri-n-butylphosphine solutions.. Inorganic chemistry, 45 ((17)): (6912-6921). [PMID:16903749]
8. Faramarz Rostami Charati,Malek Taher Maghsoodlou,Sayyed Mostafa Habibi-Khorassani,Nourallah Hazeri,Ali Ebrahimi,Zinatossadat Hossaini,Pouneh Ebrahimi,Nariman Maleki,Sayyed Reza Adhamdoust,Fatemeh Vasheghani Farahani,Ghasem Marandi,Alexandre Sobolev,Mohamed Makha. (2010-08-03) Efficient synthesis of stable phosphonate ylides and \u200ephosphonate esters: reaction between activated acetylenes and triphenylphosphite in the presence of sulfonamide and heterocyclic NH-acids.. Combinatorial chemistry & high throughput screening, 14 ((1)): (2-8). [PMID:20673221]
9. Ken-ichiro Murata,Hajime Tanaka. (2010-10-27) Surface-wetting effects on the liquid-liquid transition of a single-component molecular liquid.. Nature communications, 1 (16-16). [PMID:20975680]
10. Yi-Xuan Lu,Zhu-Ming Shi,Zhan-Ting Li,Zhibin Guan. (2010-11-09) Helical polymers based on intramolecularly hydrogen-bonded aromatic polyamides.. Chemical communications (Cambridge, England), 46 ((47)): (9019-9021). [PMID:21057673]
11. Katri Suuronen,Maria Pesonen,Maj-Len Henriks-Eckerman,Kristiina Aalto-Korte. (2012-09-22) Triphenyl phosphite, a new allergen in polyvinylchloride gloves.. Contact dermatitis, 68 ((1)): (42-49). [PMID:22994308]
12. Alix Vandevenne,Katrien Ghys,Jacob Dahlin,An Pontén,Stefan Kerre. (2013-02-21) Allergic contact dermatitis caused by triphenyl phosphite in poly(vinyl chloride) gloves.. Contact dermatitis, 68 ((3)): (181-182). [PMID:23421460]
13. Adrian Tlahuext-Aca, Oscar Hernández-Fajardo, Alma Arévalo, Juventino J García,. (2014-09-19) Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.. Dalton transactions (Cambridge, England : 2003), 43 ((42)): ( 15997-16005 ). [PMID:25232889]
14. Evgeni Eltzov,Avital Cohen,Robert S Marks. (2015-03-17) Bioluminescent liquid light guide pad biosensor for indoor air toxicity monitoring.. Analytical chemistry, 87 ((7)): (3655-3661). [PMID:25775008]
15. R G Varghese,S J Bursian,C Tobias,D Tanaka. (1995-01-01) Organophosphorus-induced delayed neurotoxicity: a comparative study of the effects of tri-ortho-tolyl phosphate and triphenyl phosphite on the central nervous system of the Japanese quail.. Neurotoxicology, 16 ((1)): (45-54). [PMID:7603644]
16. E J Lehning,D Tanaka,S J Bursian. (1996-01-01) Triphenyl phosphite and diisopropylphosphorofluoridate produce separate and distinct axonal degeneration patterns in the central nervous system of the rat.. Fundamental and applied toxicology : official journal of the Society of Toxicology, 29 ((1)): (110-118). [PMID:8838646]
17. H Kinebuchi,K Akimaru,S Noda,K Yamamoto. (1998-11-12) Cholinesterase activity in quails of neuropathy caused by organophosphates.. Industrial health, 36 ((4)): (376-379). [PMID:9810153]
18. D Tanaka,M Lin,D Powell,M Morgan,L Lipsitz,R J Aulerich,S J Bursian. (1999-12-11) Effects of dark-rearing on triphenyl phosphate-induced neuropathy in the visual system of the developing European ferret (Mustela putorius furo).. Journal of toxicology and environmental health. Part A, 58 ((4)): (215-231). [PMID:10591489]
19. Lee Lipsitz,Arthur J Weber,Steven J Bursian,Richard J Aulerich,David T Ramsey,Tanaka Duke. (2002-08-08) A quantitative assessment of TPP-induced delayed neuropathy in the retina and lateral geniculate nucleus of the European ferret (Mustela putorius furo).. Neurotoxicology, 23 ((1)): (33-42). [PMID:12164546]
20. C Torresani,E Zendri,V Vescovi,G De Panfilis. (2003-06-06) Contact urticaria syndrome from occupational triphenyl phosphite exposure.. Contact dermatitis, 48 ((4)): (237-238). [PMID:12786744]
21. Y Mao,W Chen,G Xia,Z Yang,L Zhang,Y Sun,S Weng,J Wu. (2003-08-27) [Influence on luminescence of Tb o-aminobenzolate complexes by second ligand].. Guang pu xue yu guang pu fen xi = Guang pu, 20 ((6)): (869-871). [PMID:12938499]
22. Catherine R Holden,Kid Wan Shum,David J Gawkrodger. (2006-05-13) Contact allergy to triphenyl phosphate: probable cross-reactivity to triphenyl phosphite present in an EN46001 System 22 clear oxygen facemask.. Contact dermatitis, 54 ((5)): (299-300). [PMID:16689819]
23. John D Meeker,Heather M Stapleton. (2010-03-03) House dust concentrations of organophosphate flame retardants in relation to hormone levels and semen quality parameters.. Environmental health perspectives, 118 ((3)): (318-323). [PMID:20194068]
24. Shadpour Mallakpour,Fatemeh Mirkarimi. (2010-03-31) Synthesis and characterization of novel, optically active polyamides derived from S-valine natural amino acid and bulky anthracenic side chain.. Amino acids, 39 ((5)): (1255-1263). [PMID:20352462]
25. Hailong Wei, Fangwei Gu, Yongsheng Wang, Jinyuan Hao, Wei Zhu, Zhongbin Zhuang. (2023) Synthesis of Pure-Phase Ni2P Nanocatalysts via Phosphorus Ligand Selection for Efficient Hydrogen Evolution Reaction. ChemElectroChem, (e202300426). [PMID:30538148]
26. Chao Zeng, ShengMing Zhang, Peng Ji, ZhiCheng Qiu, ZhiYong Li, ChaoSheng Wang, HuaPing Wang. (2023) Facile Sustainable Synthesis of Polyester-Polycarbonate and Effects of the Carbonate on Thermal, Mechanical, and Transparency Properties. ACS Sustainable Chemistry & Engineering, 11 (43): (15754–15764). [PMID:28111074]
27. Xiao Jing, Zhenyuan Hu, Jinpeng Qin, Xin Jiang, Mingyin Wang, Shikang Huo, Shuai Zhang, Jiatang Wang, Yunfeng Zhang. (2023) Highly conductive and mechanically robust single-ion conducting polymer electrolyte membranes with a high concentration of charge carriers for dendrite-proof lithium metal batteries. JOURNAL OF MEMBRANE SCIENCE, 688 (122118). [PMID:16906129]
28. Shouying Wu, Linping Zhang, Jianing Fan, Wei Wu, Bolin Ji, Xueling Feng, Bijia Wang, Yimeng Ma, Yi Zhong, Hong Xu, Zhiping Mao. (2023) Iron(III) complexes promote hydrogen peroxide activation for efficient degradation of dyeing wastewater. COLORATION TECHNOLOGY, (1): [PMID:10648423]
29. Shaokang Su, Wei Zhang, Ying Xie, Lihong Qi, Song Wang, Limin An, Kai Pan. (2023) Synthesis of Fe Atom-Doped Monodisperse Co2P Nanorods with a Dual-Ligand Strategy for Excellent Electrocatalytic Hydrogen Evolution Performance. INORGANIC CHEMISTRY, 62 (35): (14459–14468). [PMID:37615389]
30. Jia Liu, Zhengchun Cai, Yongxin Ji. (2023) Synthesis of bio-based modified amphoteric acrylate epoxy emulsion surface sizing agent via RAFT polymerization. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (39): (e54462). [PMID:]
31. Chenglong Xie, Xinxin Zhang, Haitao Yu, Ying Xie. (2023) Monodispersed bi-metallic phosphide anchoring on CNTs with enhanced stability and electrocatalytic HER performance at a wide PH range. JOURNAL OF ALLOYS AND COMPOUNDS, 965 (171256). [PMID:]
32. Enas A. Imam, Ahmed I Hashem, Ahmad A. Tolba, Mohammad G. Mahfouz, Ibrahim El-Tantawy El-Sayed, Hamada B. Hawash, Rana R. Neiber, Hamed I. Mira, Ahmed A. Galhoum, Eric Guibal. (2023) Aminophosphonate CuO nanocomposites for uranium(VI) removal: Sorption performance and mechanistic study. SEPARATION AND PURIFICATION TECHNOLOGY, 323 (124466). [PMID:]
33. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang. (2023) Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 664 (131181). [PMID:]
34. Huihui Gao, Xiankun Wu, Yaowen Hu, Mang Wu, Wei Liu, Zhongkai Wang. (2023) The conversion of woody oils into E-octadec-9-enedioic acid and multiple-shape memory polyamides. INDUSTRIAL CROPS AND PRODUCTS, 191 (115879). [PMID:]
35. Ran Yu, Chao Xu, Xiaopei Wu, Honglian Dai. (2022) Polyoxyethylene Diamine Modification of Poly(amide-imide)-polyethylene Glycol Exhibits Excellent Hydrophilicity, Degradability, and Biocompatibility. Polymers, 14 (21): (4694). [PMID:36365687]
36. Xingfeng Lei, Guo Xiong, Yuyang Xiao, Tianhao Huang, Xiangze Xin, Shuyu Xue, Qiuyu Zhang. (2022) High temperature shape memory poly(amide-imide)s with strong mechanical robustness. Polymer Chemistry, 13 (35): (5082-5093). [PMID:]
37. Shaokang Su, Chenfeng Guo, Li Li, Ying Xie, Song Wang, Kai Pan. (2022) Monodispersed nickel phosphide nanocrystals in situ grown on reduced graphene oxide matrix with excellent performance as the anode for lithium-ion batteries. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 920 (116616). [PMID:]
38. Lichao Chen, Bo Wang, Haohao Ren, Yanan Wu, Defu Lyu, Yanan Ouyang, Qiyi Zhang, Yonggang Yan. (2022) Arg−Gly−Asp peptide functionalized poly-amino acid/ poly (p-benzamide) copolymer with enhanced mechanical properties and osteogenicity. Biomaterials Advances, 133 (112627). [PMID:35527153]
39. Shikang Huo, Yang He, Zhenyuan Hu, Wei Bao, Weijie Chen, Yaying Wang, Danli Zeng, Hansong Cheng, Yunfeng Zhang. (2022) New insights into designation of single-ion conducting gel polymer electrolyte for high-performance lithium metal batteries. JOURNAL OF MEMBRANE SCIENCE, 647 (120287). [PMID:]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.