Triphenyl phosphite - 98%, high purity , CAS No.101-02-0

15 Citations
  • ≥98%
Item Number
T104038
Grouped product items
SKUSizeAvailabilityPrice Qty
T104038-100g
100g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$21.90
T104038-500g
500g
In stock
$31.90

Basic Description

SynonymsTRIPHENYL PHOSPHITE | 101-02-0 | Phosphorous acid, triphenyl ester | Advance TPP | Triphenoxyphosphine | Phenyl phosphite | Sumilizer TPP-R | Stabilizer P 36 | Trifenoxyfosfin | Trifenylfosfit | Phosclere T 36 | EFED | Mellite 310 | Tris(phenoxy)phosphine | P 36 (stabilizer) | Weston
Specifications & Purity≥98%
Storage TempArgon charged
Shipped InNormal
Product Description

Used to convert alcohols to alkyl halides, as a peptide coupling agent, and, in combination with ozone, as a low-temperature source of singlet oxygen, and ligand for metal-catalyzed reactions.


application:

Triphenyl phosphite can be used:

As a source of phosphorus and as a ligand for the synthesis of transition metal phosphide nanoparticles via heating-up process.

To convert alcohols to alkyl halides.

As a peptide coupling agent.

As a low-temperature source of singlet oxygen after forming an adduct with ozone.

To synthesize bromotriphenoxyphosphonium bromide, a brominating agent, by reacting with bromine.

Associated Targets(Human)

AR Tclin Androgen receptor (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)
THRB Tclin Thyroid hormone receptor beta (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)
NFE2L2 Tchem Nuclear factor erythroid 2-related factor 2 (0 Activities)
Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)
AR Tclin Androgen Receptor (11781 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
THRB Tclin Thyroid hormone receptor beta-1 (7926 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Associated Targets(non-human)

Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID

Names and Identifiers

IUPAC Name triphenyl phosphite
INCHI InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChi Key HVLLSGMXQDNUAL-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
Isomeric SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
WGK Germany 2
RTECS TH1575000
PubChem CID 7540
UN Number 2811
Packing Group I
Molecular Weight 310.28
Beilstein 1079456
Reaxy-Rn 1079456

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

15 results found

Lot NumberCertificate TypeDateItem
K21111070Certificate of AnalysisAug 03, 2023 T104038
K21111072Certificate of AnalysisAug 03, 2023 T104038
I2111026Certificate of AnalysisJun 13, 2023 T104038
I2114004Certificate of AnalysisJun 13, 2023 T104038
I2114005Certificate of AnalysisJun 13, 2023 T104038
H2104371Certificate of AnalysisMay 10, 2023 T104038
I2308194Certificate of AnalysisJun 11, 2022 T104038
I2308196Certificate of AnalysisJun 11, 2022 T104038
I2308199Certificate of AnalysisJun 11, 2022 T104038
J2211197Certificate of AnalysisJun 11, 2022 T104038
J2211201Certificate of AnalysisJun 11, 2022 T104038
J2211202Certificate of AnalysisJun 11, 2022 T104038
J2211203Certificate of AnalysisJun 11, 2022 T104038
K2222362Certificate of AnalysisJun 11, 2022 T104038
F2129391Certificate of AnalysisJun 11, 2021 T104038

more

Chemical and Physical Properties

SolubilityInsoluble in water
SensitivityMoisture Sensitive ,air sensitive
Freezing Point(°C)20 °C
Refractive Index1.59
Flash Point(°F)410 °F
Flash Point(°C)206℃
Boil Point(°C)360°C
Melt Point(°C)22-24°C

Safety and Hazards(GHS)

Pictogram(s) GHS09,   GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H400:Very toxic to aquatic life

H410:Very toxic to aquatic life with long lasting effects

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

WGK Germany 2
RTECS TH1575000
Reaxy-Rn 1079456
Class 6.1
RIDADR UN 3077 9 / PGIII

Related Documents

Citations of This Product

1. Hailong Wei, Fangwei Gu, Yongsheng Wang, Jinyuan Hao, Wei Zhu, Zhongbin Zhuang.  (2023)  Synthesis of Pure-Phase Ni2P Nanocatalysts via Phosphorus Ligand Selection for Efficient Hydrogen Evolution Reaction.  ChemElectroChem,    (e202300426).  [PMID:30538148]
2. Chao Zeng, ShengMing Zhang, Peng Ji, ZhiCheng Qiu, ZhiYong Li, ChaoSheng Wang, HuaPing Wang.  (2023)  Facile Sustainable Synthesis of Polyester-Polycarbonate and Effects of the Carbonate on Thermal, Mechanical, and Transparency Properties.  ACS Sustainable Chemistry & Engineering,  11  (43): (15754–15764).  [PMID:28111074]
3. Xiao Jing, Zhenyuan Hu, Jinpeng Qin, Xin Jiang, Mingyin Wang, Shikang Huo, Shuai Zhang, Jiatang Wang, Yunfeng Zhang.  (2023)  Highly conductive and mechanically robust single-ion conducting polymer electrolyte membranes with a high concentration of charge carriers for dendrite-proof lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  688  (122118).  [PMID:16906129]
4. Shouying Wu, Linping Zhang, Jianing Fan, Wei Wu, Bolin Ji, Xueling Feng, Bijia Wang, Yimeng Ma, Yi Zhong, Hong Xu, Zhiping Mao.  (2023)  Iron(III) complexes promote hydrogen peroxide activation for efficient degradation of dyeing wastewater.  COLORATION TECHNOLOGY,    (1):   [PMID:10648423]
5. Shaokang Su, Wei Zhang, Ying Xie, Lihong Qi, Song Wang, Limin An, Kai Pan.  (2023)  Synthesis of Fe Atom-Doped Monodisperse Co2P Nanorods with a Dual-Ligand Strategy for Excellent Electrocatalytic Hydrogen Evolution Performance.  INORGANIC CHEMISTRY,  62  (35): (14459–14468).  [PMID:37615389]
6. Jia Liu, Zhengchun Cai, Yongxin Ji.  (2023)  Synthesis of bio-based modified amphoteric acrylate epoxy emulsion surface sizing agent via RAFT polymerization.  JOURNAL OF APPLIED POLYMER SCIENCE,  140  (39): (e54462).  [PMID:]
7. Chenglong Xie, Xinxin Zhang, Haitao Yu, Ying Xie.  (2023)  Monodispersed bi-metallic phosphide anchoring on CNTs with enhanced stability and electrocatalytic HER performance at a wide PH range.  JOURNAL OF ALLOYS AND COMPOUNDS,  965  (171256).  [PMID:]
8. Enas A. Imam, Ahmed I Hashem, Ahmad A. Tolba, Mohammad G. Mahfouz, Ibrahim El-Tantawy El-Sayed, Hamada B. Hawash, Rana R. Neiber, Hamed I. Mira, Ahmed A. Galhoum, Eric Guibal.  (2023)  Aminophosphonate CuO nanocomposites for uranium(VI) removal: Sorption performance and mechanistic study.  SEPARATION AND PURIFICATION TECHNOLOGY,  323  (124466).  [PMID:]
9. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang.  (2023)  Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  664  (131181).  [PMID:]
10. Huihui Gao, Xiankun Wu, Yaowen Hu, Mang Wu, Wei Liu, Zhongkai Wang.  (2023)  The conversion of woody oils into E-octadec-9-enedioic acid and multiple-shape memory polyamides.  INDUSTRIAL CROPS AND PRODUCTS,  191  (115879).  [PMID:]
11. Ran Yu, Chao Xu, Xiaopei Wu, Honglian Dai.  (2022)  Polyoxyethylene Diamine Modification of Poly(amide-imide)-polyethylene Glycol Exhibits Excellent Hydrophilicity, Degradability, and Biocompatibility.  Polymers,  14  (21): (4694).  [PMID:36365687]
12. Xingfeng Lei, Guo Xiong, Yuyang Xiao, Tianhao Huang, Xiangze Xin, Shuyu Xue, Qiuyu Zhang.  (2022)  High temperature shape memory poly(amide-imide)s with strong mechanical robustness.  Polymer Chemistry,  13  (35): (5082-5093).  [PMID:]
13. Shaokang Su, Chenfeng Guo, Li Li, Ying Xie, Song Wang, Kai Pan.  (2022)  Monodispersed nickel phosphide nanocrystals in situ grown on reduced graphene oxide matrix with excellent performance as the anode for lithium-ion batteries.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,  920  (116616).  [PMID:]
14. Lichao Chen, Bo Wang, Haohao Ren, Yanan Wu, Defu Lyu, Yanan Ouyang, Qiyi Zhang, Yonggang Yan.  (2022)  Arg−Gly−Asp peptide functionalized poly-amino acid/ poly (p-benzamide) copolymer with enhanced mechanical properties and osteogenicity.  Biomaterials Advances,  133  (112627).  [PMID:35527153]
15. Shikang Huo, Yang He, Zhenyuan Hu, Wei Bao, Weijie Chen, Yaying Wang, Danli Zeng, Hansong Cheng, Yunfeng Zhang.  (2022)  New insights into designation of single-ion conducting gel polymer electrolyte for high-performance lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  647  (120287).  [PMID:]

References

1. Hailong Wei, Fangwei Gu, Yongsheng Wang, Jinyuan Hao, Wei Zhu, Zhongbin Zhuang.  (2023)  Synthesis of Pure-Phase Ni2P Nanocatalysts via Phosphorus Ligand Selection for Efficient Hydrogen Evolution Reaction.  ChemElectroChem,    (e202300426).  [PMID:30538148]
2. Chao Zeng, ShengMing Zhang, Peng Ji, ZhiCheng Qiu, ZhiYong Li, ChaoSheng Wang, HuaPing Wang.  (2023)  Facile Sustainable Synthesis of Polyester-Polycarbonate and Effects of the Carbonate on Thermal, Mechanical, and Transparency Properties.  ACS Sustainable Chemistry & Engineering,  11  (43): (15754–15764).  [PMID:28111074]
3. Xiao Jing, Zhenyuan Hu, Jinpeng Qin, Xin Jiang, Mingyin Wang, Shikang Huo, Shuai Zhang, Jiatang Wang, Yunfeng Zhang.  (2023)  Highly conductive and mechanically robust single-ion conducting polymer electrolyte membranes with a high concentration of charge carriers for dendrite-proof lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  688  (122118).  [PMID:16906129]
4. Shouying Wu, Linping Zhang, Jianing Fan, Wei Wu, Bolin Ji, Xueling Feng, Bijia Wang, Yimeng Ma, Yi Zhong, Hong Xu, Zhiping Mao.  (2023)  Iron(III) complexes promote hydrogen peroxide activation for efficient degradation of dyeing wastewater.  COLORATION TECHNOLOGY,    (1):   [PMID:10648423]
5. Shaokang Su, Wei Zhang, Ying Xie, Lihong Qi, Song Wang, Limin An, Kai Pan.  (2023)  Synthesis of Fe Atom-Doped Monodisperse Co2P Nanorods with a Dual-Ligand Strategy for Excellent Electrocatalytic Hydrogen Evolution Performance.  INORGANIC CHEMISTRY,  62  (35): (14459–14468).  [PMID:37615389]
6. Jia Liu, Zhengchun Cai, Yongxin Ji.  (2023)  Synthesis of bio-based modified amphoteric acrylate epoxy emulsion surface sizing agent via RAFT polymerization.  JOURNAL OF APPLIED POLYMER SCIENCE,  140  (39): (e54462).  [PMID:]
7. Chenglong Xie, Xinxin Zhang, Haitao Yu, Ying Xie.  (2023)  Monodispersed bi-metallic phosphide anchoring on CNTs with enhanced stability and electrocatalytic HER performance at a wide PH range.  JOURNAL OF ALLOYS AND COMPOUNDS,  965  (171256).  [PMID:]
8. Enas A. Imam, Ahmed I Hashem, Ahmad A. Tolba, Mohammad G. Mahfouz, Ibrahim El-Tantawy El-Sayed, Hamada B. Hawash, Rana R. Neiber, Hamed I. Mira, Ahmed A. Galhoum, Eric Guibal.  (2023)  Aminophosphonate CuO nanocomposites for uranium(VI) removal: Sorption performance and mechanistic study.  SEPARATION AND PURIFICATION TECHNOLOGY,  323  (124466).  [PMID:]
9. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang.  (2023)  Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  664  (131181).  [PMID:]
10. Huihui Gao, Xiankun Wu, Yaowen Hu, Mang Wu, Wei Liu, Zhongkai Wang.  (2023)  The conversion of woody oils into E-octadec-9-enedioic acid and multiple-shape memory polyamides.  INDUSTRIAL CROPS AND PRODUCTS,  191  (115879).  [PMID:]
11. Ran Yu, Chao Xu, Xiaopei Wu, Honglian Dai.  (2022)  Polyoxyethylene Diamine Modification of Poly(amide-imide)-polyethylene Glycol Exhibits Excellent Hydrophilicity, Degradability, and Biocompatibility.  Polymers,  14  (21): (4694).  [PMID:36365687]
12. Xingfeng Lei, Guo Xiong, Yuyang Xiao, Tianhao Huang, Xiangze Xin, Shuyu Xue, Qiuyu Zhang.  (2022)  High temperature shape memory poly(amide-imide)s with strong mechanical robustness.  Polymer Chemistry,  13  (35): (5082-5093).  [PMID:]
13. Shaokang Su, Chenfeng Guo, Li Li, Ying Xie, Song Wang, Kai Pan.  (2022)  Monodispersed nickel phosphide nanocrystals in situ grown on reduced graphene oxide matrix with excellent performance as the anode for lithium-ion batteries.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,  920  (116616).  [PMID:]
14. Lichao Chen, Bo Wang, Haohao Ren, Yanan Wu, Defu Lyu, Yanan Ouyang, Qiyi Zhang, Yonggang Yan.  (2022)  Arg−Gly−Asp peptide functionalized poly-amino acid/ poly (p-benzamide) copolymer with enhanced mechanical properties and osteogenicity.  Biomaterials Advances,  133  (112627).  [PMID:35527153]
15. Shikang Huo, Yang He, Zhenyuan Hu, Wei Bao, Weijie Chen, Yaying Wang, Danli Zeng, Hansong Cheng, Yunfeng Zhang.  (2022)  New insights into designation of single-ion conducting gel polymer electrolyte for high-performance lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,  647  (120287).  [PMID:]

Solution Calculators